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Journal of Spectroscopy
Volume 2018, Article ID 6924758, 6 pages
Research Article

Surface-Enhanced Raman Scattering of MEH-PPV on Gold and Silver Nanoparticles

Laboratório de Nanoestruturas Plasmônicas, Departamento de Química, Universidade Federal de Juiz de Fora, 36036-330 Juiz de Fora, MG, Brazil

Correspondence should be addressed to Celly M. S. Izumi; rb.ude.fjfu@imuzi.yllec

Received 18 December 2017; Accepted 13 February 2018; Published 13 March 2018

Academic Editor: Anatoly Frenkel

Copyright © 2018 Beatriz R. Moraes et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


The interaction of poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) with Au or Ag nanospheres, Au nanostars, and Ag nanoprisms was investigated using surface-enhanced Raman scattering (SERS). The SERS investigation showed that adsorption of MEH-PPV strongly depends on the nature of the nanoparticle surface. On gold nanostars that present a thick layer of capping polymer, SERS spectrum is only observed in relatively concentrated MEH-PPV solution (1 mmol L−1). On the other hand, Au and Ag nanospheres present SERS spectra down to 10−6 mol L−1 and no chemical interaction of MEH-PPV and metal surface is observed. The spectra of MEH-PPV on Ag nanoprisms with PVP as stabilizing agent suggest that the capping polymer induces a planar conformation of MEH-PPV and consequently an increase of conjugation length. These results give support for the application of MEH-PPV on optoelectronics in which interfacial effects are critical in the device efficiency and stability.