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Journal of Spectroscopy
Volume 2018, Article ID 8153941, 10 pages
https://doi.org/10.1155/2018/8153941
Research Article

Spectroscopic Characteristics of Treated-Color Natural Diamonds

1State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing, China
2Taidiam Technology (Zhengzhou) Co. Ltd., Zhengzhou, China
3National Gems & Jewelry Technology Administrative Center, Beijing, China

Correspondence should be addressed to Guanghai Shi; nc.ude.bguc@hgihs

Received 15 October 2017; Accepted 28 December 2017; Published 7 March 2018

Academic Editor: Vincenza Crupi

Copyright © 2018 Meili Wang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. G. E. Harlow, “What is diamond?” The Nature of Diamond, G. E. Harlow, Ed., Cambridge University Press, Cambridge, 1998. View at Google Scholar
  2. K. Nassau, Gemstone Enhancement History, Science and State of the Art, Butterworth-Heinemann Ltd, Oxford, 2nd edition, 1994.
  3. A. T. Collins and I. Kiflawi, “The annealing of radiation damage in type Ia diamond,” Journal of Physics: Condensed Matter, vol. 21, no. 36, article 364209, 2009. View at Publisher · View at Google Scholar · View at Scopus
  4. T. Hainschwang, A. Katrusha, and H. Vollstaedt, “HPHT treatment of different classes of type I brown diamonds,” Journal of Gemmology, vol. 29, no. 5-6, pp. 61–73, 2005. View at Google Scholar
  5. T. Hainschwang, A. Respinger, F. Notari, H. J. Hartmann, and C. Günthard, “A comparison of diamonds irradiated by high fluence neutrons or electrons, before and after annealing,” Diamond and Related Materials, vol. 18, no. 10, pp. 1223–1234, 2009. View at Publisher · View at Google Scholar · View at Scopus
  6. M. Hall and T. M. Moses, “Gem trade lab notes: diamond-blue and pink, HPHT annealed,” Gems & Gemology, vol. 36, no. 3, pp. 254–259, 2000. View at Publisher · View at Google Scholar
  7. Y. F. Meng, C. S. Yan, J. Lai et al., “Enhanced optical properties of chemical vapor deposited single crystal diamond by low-pressure/high-temperature annealing,” Proceedings of the National Academy of Sciences of the United States of America, vol. 105, no. 46, pp. 17620–17625, 2008. View at Publisher · View at Google Scholar · View at Scopus
  8. S. S. Vagarali, S. W. Webb, W. E. Jackson, W. F. Banholzer, T. R. Anthony, and G. R. Kaplan, “High pressure/high temperature production of colorless and fancy-colored diamonds,” U.S. patent 6692714, 2004.
  9. V. G. Vins, “The technique of production of fancy red diamonds,” Russian Federation patent 2237113, 2004.
  10. V. G. Vins, A. P. Yelisseyev, S. S. Lobanov, D. V. Afonin, A. Y. Maksimov, and A. Y. Blinkov, “APHT treatment of brown type Ia natural diamonds: dislocation movement or vacancy cluster destruction?” Diamond and Related Materials, vol. 19, no. 7-9, pp. 829–832, 2010. View at Publisher · View at Google Scholar · View at Scopus
  11. V. G. Vins and O. V. Kononov, “A model of HPHT color enhancement mechanism in natural gray diamonds,” Diamond and Related Materials, vol. 12, no. 3-7, pp. 542–545, 2003. View at Publisher · View at Google Scholar · View at Scopus
  12. V. G. Vins, “Technique of production of fancy red diamonds,” US Patent 2007/0053823A1, 2007.
  13. I. M. Reinitz, P. R. Buerki, J. E. Shigley, S. F. McClure, and T. M. Moses, “Identification of HPHT-treated yellow to green diamonds,” Gems & Gemology, vol. 36, no. 2, pp. 128–137, 2000. View at Publisher · View at Google Scholar · View at Scopus
  14. J. E. Shigley, “High-pressure-high-temperature treatment of gem diamonds,” Elements, vol. 1, no. 2, pp. 101–104, 2005. View at Publisher · View at Google Scholar
  15. W. Wang, C. P. Smith, M. S. Hall, C. M. Breeding, and T. M. Moses, “Treated-color pink-to-red diamonds from Lucent Diamonds Inc,” Gems & Gemology, vol. 41, no. 1, pp. 6–19, 2005. View at Publisher · View at Google Scholar · View at Scopus
  16. C. M. Welbourn, M. Cooper, and P. M. Spear, “De beers natural versus synthetic diamond verification instruments,” Gems & Gemology, vol. 32, no. 3, pp. 156–169, 1996. View at Publisher · View at Google Scholar
  17. S. Liggins, M. E. Newton, J. P. Goss, P. R. Briddon, and D. Fisher, “Identification of the dinitrogen <001> split interstitial H1a in diamond,” Physical Review B, vol. 81, no. 8, article 0852145, 2010. View at Publisher · View at Google Scholar · View at Scopus
  18. C. D. Clark, R. W. Ditchburn, and H. B. Dyer, “Absorption spectra of natural and irradiated diamonds,” Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, vol. 234, no. 1198, pp. 363–381, 1956. View at Publisher · View at Google Scholar
  19. G. S. Woods, “Platelets and the infrared absorption of type Ia diamonds,” Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, vol. 407, no. 1832, pp. 219–238, 1986. View at Publisher · View at Google Scholar
  20. F. S. Gentile, S. Salustro, M. Causa, A. Erba, P. Carbonniere, and R. Dovesi, “The VN3H defect in diamond: a quantum-mechanical characterization,” Physical Chemistry Chemical Physics, vol. 19, no. 33, pp. 22221–22229, 2017. View at Publisher · View at Google Scholar · View at Scopus
  21. A. Mainwood, “Nitrogen and nitrogen-vacancy complexes and their formation in diamond,” Physical Review B, vol. 49, no. 12, pp. 7934–7940, 1994. View at Publisher · View at Google Scholar · View at Scopus
  22. A. M. Zaitsev, Optical Properties of Diamond: A Data Handbook, Springer-Verlag, Berlin, 2001. View at Publisher · View at Google Scholar
  23. D. Fisher, “Brown diamonds and high pressure high temperature treatment,” Lithos, vol. 112, pp. 619–624, 2009. View at Publisher · View at Google Scholar · View at Scopus
  24. W. Wang, P. Doering, J. L. R. Tower et al., “Strongly colored pink CVD lab-grown diamonds,” Gems & Gemology, vol. 46, no. 1, pp. 4–17, 2010. View at Publisher · View at Google Scholar · View at Scopus
  25. L. Tretiakova, “Spectroscopic methods for the identification of natural yellow gem-quality diamonds,” European Journal of Mineralogy, vol. 21, no. 1, pp. 43–50, 2009. View at Publisher · View at Google Scholar · View at Scopus
  26. I. A. Dobrinets, V. G. Vins, and A. M. Zaitsev, HPHT-Treated Diamonds, Springer Series in Material Science, Berlin, 2013.
  27. J. E. Shigley, E. Fritsch, J. I. Koivula, N. V. Sobolev, I. Y. Malinovsky, and Y. N. Pal'yanov, “The gemological properties of Russian gem-quality synthetic yellow diamonds,” Gems & Gemology, vol. 29, no. 4, pp. 228–248, 1993. View at Publisher · View at Google Scholar
  28. A. T. Collins, “Optical centres produced in diamond by radiation damage,” New Diamond and Frontier Carbon Technology, vol. 17, no. 2, p. 47, 2007. View at Google Scholar
  29. A. T. Collins, A. Connor, C. Ly, A. Shareef, and P. M. Spear, “High-temperature annealing of optical centers in type-I diamond,” Journal of Applied Physics, vol. 97, no. 8, article 083517, 2005. View at Google Scholar
  30. V. G. Vins and A. P. Yelisseyev, “Effect of high pressure, high temperature annealing on impurity-defect structure of natural diamonds,” Perspectives Materials, vol. 1, pp. 49–57, 2010, (in Russian). View at Google Scholar
  31. E. J. Brookes, A. T. Collins, and G. S. Woods, “Cathodoluminescence at indentations in diamonds,” Journal of Hazardous Materials, vol. 4, pp. 98–105, 1993. View at Google Scholar
  32. F. De Weerdt, R. Galloway, and A. Anthonis, “Defect aggregation and dissociation in brown type-Ia diamonds by annealing at high pressure and high temperature (HPHT),” In Defect and Diffusion Forum, vol. 226, pp. 49–60, 2004. View at Google Scholar
  33. A. T. Collins, “Colour centers in diamond,” Journal of Gemmology, vol. 18, no. 1, pp. 37–75, 1982. View at Google Scholar
  34. A. T. Collins, “The detection of colour-enhanced and synthetic gem diamonds by optical spectroscopy,” Diamond and Related Materials, vol. 12, no. 10-11, pp. 1976–1983, 2003. View at Publisher · View at Google Scholar · View at Scopus
  35. A. T. Collins, H. Kanda, and H. Kitawaki, “Colour changes produced in natural brown diamonds by high-pressure, high-temperature treatment,” Diamond and Related Materials, vol. 9, no. 2, pp. 113–122, 2000. View at Publisher · View at Google Scholar
  36. F. De Weerdt and J. Van Royen, “Defects in coloured natural diamonds,” Diamond and Related Materials, vol. 10, no. 3-7, pp. 474–479, 2001. View at Publisher · View at Google Scholar · View at Scopus
  37. A. T. Collins, “Investigating artificially colored diamond,” Nature, vol. 273, no. 5664, pp. 654-655, 1978. View at Publisher · View at Google Scholar · View at Scopus
  38. V. G. Vins and A. P. Eliseev, “Effect of annealing at high pressures and temperatures on the defect-admixture structure of natural diamonds,” Inorganic Materials: Applied Research, vol. 1, no. 4, pp. 303–310, 2010. View at Publisher · View at Google Scholar · View at Scopus
  39. V. G. Vins and A. P. Yelisseyev, “Physical fundamentals behind modern techniques of natural diamond enhancement,” Australian Gemmologist, vol. 24, pp. 219–221, 2008. View at Google Scholar
  40. V. G. Vins, A. P. Yelisseyev, and V. Sarin, “Physics behind the modern methods of enhancement of natural diamonds,” Precision Metals Precision Stones, vol. 12, no. 180, pp. 155–163, 2008. View at Google Scholar
  41. D. Fisher, D. J. F. Evans, C. Glover, C. J. Kelly, M. J. Sheehy, and G. C. Summerton, “The vacancy as a probe of the strain in type IIa diamonds,” Diamond and Related Materials, vol. 15, no. 10, pp. 1636–1642, 2006. View at Publisher · View at Google Scholar · View at Scopus
  42. H. Lim, S. Park, H. Cheong, H. M. Choi, and Y. C. Kim, “Discrimination between natural and HPHT-treated type IIa diamonds using photoluminescence spectroscopy,” Diamond and Related Materials, vol. 19, no. 10, pp. 1254–1258, 2010. View at Publisher · View at Google Scholar · View at Scopus
  43. I. Kiflawi, A. T. Collins, K. Iakoubovskii, and D. Fisher, “Electron irradiation and the formation of vacancy-interstitial pairs in diamond,” Journal of Physics: Condensed Matter, vol. 19, no. 4, article 046216, 2007. View at Publisher · View at Google Scholar · View at Scopus
  44. G. Davies, “Charge states of the vacancy in diamond,” Nature, vol. 269, no. 5628, pp. 498–500, 1977. View at Publisher · View at Google Scholar · View at Scopus
  45. F. De Weerdt and A. T. Collins, “HPHT annealing of natural diamond,” New Diamond and Frontier Carbon Technology, vol. 17, no. 2, 2007. View at Google Scholar
  46. J. P. Goss, P. R. Briddon, V. Hill, R. Jones, and M. J. Rayson, “Identification of the structure of the 3107 cm−1 H-related defect in diamond,” Journal of Physics: Condensed Matter, vol. 26, no. 14, article 145801, 2014. View at Publisher · View at Google Scholar · View at Scopus
  47. V. G. Vins, “Changing diamond colour,” Best Gemology, vol. 1, no. 3, pp. 19–30, 2001. View at Google Scholar
  48. F. De Weerdt and I. N. Kupriyanov, “Report on the influence of HPHT annealing on the 3107 cm−1 hydrogen related absorption peak in natural type Ia diamonds,” Diamond and Related Materials, vol. 11, no. 3-6, pp. 714-715, 2002. View at Publisher · View at Google Scholar · View at Scopus
  49. A. T. Collins, “Colour of diamond and how it may be changed,” Journal of Gemmology, vol. 27, no. 6, pp. 341–359, 2001. View at Google Scholar
  50. A. T. Collins and P. M. Spear, “Optically active nickel in synthetic diamond,” Journal of Physics D: Applied Physics, vol. 15, no. 12, pp. L183–L187, 1982. View at Publisher · View at Google Scholar · View at Scopus
  51. S. C. Lawson, H. Kanda, and M. Sekita, “New nickel-related optical absorption in high-pressure synthetic diamond,” Philosophical Magazine B, vol. 68, no. 1, pp. 39–46, 1993. View at Publisher · View at Google Scholar · View at Scopus
  52. J. Darley and J. M. King, “Natural color hydrogen-rich blue-gray diamond,” Gems & Gemology, vol. 43, no. 2, pp. 155-156, 2007. View at Google Scholar
  53. E. Fritsch and K. Scarratt, “Natural-color nonconductive gray-to-blue diamonds,” Gems & Gemology, vol. 28, no. 1, pp. 35–42, 1992. View at Publisher · View at Google Scholar
  54. H. Kitawaki, “Gem diamonds: causes of colors,” New Diamond and Frontier Carbon Technology, vol. 17, no. 3, pp. 119–126, 2007. View at Google Scholar
  55. Y. C. Kim and H. M. Choi, “A study on the HPHT-processed NOUV diamonds by means of their gemological and spectroscopic properties,” Journal of the Korean Crystal Growth and Crystal Technology, vol. 15, no. 3, pp. 114–119, 2005. View at Google Scholar
  56. W. Wang and M. Hall, “HPHT-treated type Ia diamond with a green component caused by the H2 defect,” Gems & Gemology, vol. 43, no. 2, pp. 156–158, 2007. View at Google Scholar
  57. M. E. Newton, “Treated diamond: a physicist’s perspective,” Gems & Gemology, vol. 42, no. 3, pp. 84-85, 2006. View at Google Scholar
  58. F. De Weerdt and J. Van Royen, “Investigation of seven diamonds, HPHT treated by NovaDiamond,” Journal of Gemmology, vol. 27, no. 4, pp. 201–208, 2000. View at Publisher · View at Google Scholar
  59. J. P. Chalain, E. Fritsch, and H. A. Haenni, “Diamants de type IIa et traitement HPHT: Identificatio,” Revue de Gemmologie, vol. 141, pp. 50–53, 2001. View at Google Scholar
  60. L. Tretiakova and Y. Tretyakova, “In significance of spectroscopic methods for the identification defects in diamond,” in 9th International Kimberlite Conference, Extended Abstract No. 9IKC-A-00042, 2008.