Phenolic Composition and Antioxidant and Antiproliferative Activities of the Extracts of Twelve Common Bean (Phaseolus vulgaris L.) Endemic Ecotypes of Southern Italy before and after Cooking

Table 4

Chromatographic profile of the polyphenols extracts. They were identified based on the retention times of the corresponding standards.

(a)

	(1a) (BA)	(1a) (BAc)	(1b) (DM)	(1b) (DMc)	(1c) (V)	(1c) (Vc)
Gallic acid	64.563	64.827	53.168	116.329	49.236	58.734
Caftaric acid	14.247	7.002			7.907	4.021
Chlorogenic acid	104.362	96.367	64.453	83.111	65.225	29.6
Epigallocatechin		4.087
Cichoric acid	11.022
Catechin	10.002				9.411	6.068
Caffeic acid				0.539
Epicatechin	2.603	2.093		0.824	1.807	1.16
Sinigrin				1.779	1.939
Coumaric acid	1.777	1.587
Hyperoside	8.83	9.08	4.532	3.453	2.536	20.823
Spiraeoside	3.643
Formononetin	26.208	66.753	6.989	1.253	2.682	4.172

(b)

	(2a) (CR)	(2a) (CRc)	(2b) (OR)	(2b) (ORc)	(2c) (Z)	(2c) (Zc)
Gallic acid	67.565	60.985	259.764	56.526	618.536	555.525
Caftaric acid	15.55	6.848		6.559	49.795	33.45
Chlorogenic acid	76.245	35.456	308.9	67.963	132.459	82.863
Epigallocatechin						35.165
Cicoric acid		21.73	160.473	35.504	117.773
Catechin	22.772
Vanillic acid	11.855	5.87	38.845	6.959
Epicatechin	3.27	4.4	35.573	5.926	13.191	3.373
Quercetin 3,4 diglucoside				1.941	17.595
1-3 dicaffeoylquinic acid				17.311
Sinigrin	5.312				16.668	1.193
Siringaldeid	15.045
Hyperoside		24.541	205.9	27.281	28.773	4.323
Taxifolin	2.48		43.945
Indole3 carboxilic a.				0.526		0.27
Spiraeosid			295.418	10.019
Miricetin						0.218
Genistein	2.09	3.651
Kampherol					6.723	6.045
Formononentin	38.648	32.289	25.736	24.985	4.986	4.063

(c)

	(3a) (P)	(3a) (Pc)	(3b) (S)	(3b) (Sc)	(3c) (Si)	(3c) (Sic)
Gallic acid	301.135	416.078	521.645	292.937		428.594
Caftaric acid	203.988	76.12	145.791	49.122	87.6	39.629
Chlorogenic acid	141.223	86.658	325.264	103.334	237.473	73.644
Epigallocatechin	27.028			12.285
Cicoric acid	137.253	67.065	156.018	79.144	288.118	47.206
Catechin			59.173
Vanillic acid	62.34		38.509		63.736
Caffeic acid						2.488
Epicatechin	21.388	9.815	34.427	8.717	56
Quercetin 3,4 diglucoside			34.809		57.5	4.91
1-3 dicaffeoylquinic acid	82.608
Sinigrin	47.455	12.978		12.793	154.191
Hyperoside	60.343	21.27	32.073	22.749	146.036	6.567
Rosmarinic acid	36.758				56.964	2.502
Taxifolin		14.038	9.127
Spiraeosid	113.72			39.507
Miricetin					3.355
Dadzein	5.67				8.218
Luteolin				3.095
Quercetin	8.595
Genistein		3.732
Naringenin				0.622
Kampherol	1.98				5.727	5.219
Formononentin	54.108	53.785	21.373	12.951	4.527	3.642

(d)

	(4c) (NC)	(4c) (NCc)	(4b) (NF)	(4b) (NFc)	(4a) (NA)	(4a) (NAc)
Gallic acid	38.359	176.217	74.851	79.488	186.945	83.053
Caftaric acid	90.605	38.329	74.017	26.932		41.02
Chlorogenic acid	334.545	122.52	178.263	94.236	752.809	166.8
Cicoric acid			153.017			54.333
Catechin				7.38
Vanillic acid					29.8
Siringic acid		0.951		1.296		1.887
Epicatechin	14.986	0.871	10.9	1.488	34.482
Quercetin 3,4 diglucoside	45.691	5.526	11.229
Sinigrin				1.936
Coumaric acid	6.177		4.377		14.791	3.047
Ellagic acid			18.083
Siringaldeid	30.8	4.311			113.891	17.72
Hyperoside			34.506	6.68
Taxifolin	13.659				21.782
Indole 3 carboxiladeid					5.245	1.18
Miricetin	1.986
Genistein						9.467
Formononentin	35.941	28.137	39.72	5.096	163.336	65.62
Biochanin-A						4.12