Air Monitoring: New Advances in Sampling and Detection

Table 5

Analytical conditions.

TD conditions	GC conditions	TOF MS conditions
Configuration: CIA-Advantage automated canister analysis system (Markes International Ltd); Sampling: 10 mL/min for 1 min (MFC); Flow path temperature: 150°C; Cold trap: air toxics analyser type trap; Trapping temperature: 25°C; Cold trap desorption: 300°C for 3 min (splitless); Trap heating rate: 40°C/s	Column: 60 m × 0.32 mm × 1.8 μm, 624 type phase; Oven: 40°C (5 min), 5°C/min to 230°C (0 min); Constant pressure: 10 psi	Configuration: BenchTOF-dx (ALMSCO International Ltd, UK); Ion source heating: 240°C; Transfer line temperature: 240°C; Acquisition rate: 2 data points/s, (5000 spectra/data point); Mass range: m/z 35–500