Ru (III) Catalyzed Oxidation of Aliphatic Ketones by N-Bromosuccinimide in Aqueous Acetic Acid: A Kinetic Study

Table 2

Effect of variation of [Ru (III)]. 10³ [NBS] = 5.00 mol dm⁻³; 10² [H⁺] = 1.00 mol dm⁻³; [EMK] = 0.100 mol dm⁻³; 10² [Hg(OAc)₂] = 2.00 mol dm⁻³; HOAc = 10% (v/v); temp = 300 K.

10^5 [Ru (III)]	0.525	1.05	2.09	4.18	5.25
10^6 V mol dm^−3 s^−1	0.338	0.675	1.35	2.72	3.40
10^6 V/10^5 [Ru (III)]	0.644	0.595	0.646	0.650	0.648