Kinetic Analysis for Macrocyclizations Involving Anionic Template at the Transition State

Figure 1

Concentration of the reactants, products, and reaction intermediate versus time for kinetic model 1. [A]₀=[B]₀=0.005 M, 𝑘₁=10 M⁻¹ min⁻¹ and (a) 𝑘₂=0.5 min⁻¹, (b) 𝑘₂=0.05 min⁻¹.

(a)

(b)