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The Scientific World Journal
Volume 2012, Article ID 856948, 7 pages
http://dx.doi.org/10.1100/2012/856948
Research Article

Development of a Reliable Analytical Method for Liquid Anion-Exchange Extraction and Separation of Neodymium(III)

1Department of Chemistry, Raje Ramrao Mahavidyalaya, Jath, Sangli 416 404, India
2Analytical Chemistry Laboratory, Department of Chemistry, Shivaji University, Kolhapur 416 004, India
3Analytical Chemistry Laboratory, PG Department of Chemistry, Jaysingpur College, Jaysingpur, Kolhapur 416 116, India

Received 24 October 2011; Accepted 1 December 2011

Academic Editor: Wan Kuen Jo

Copyright © 2012 Balasaheb N. Kokare et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. J. D. Lee, Concise Inorganic Chemistry, ELBS Chapman and Hall, London, UK, 4th edition, 1991.
  2. R. C. Vickary, Chemistry of Lanthanons, Butterworth’s, 1953.
  3. C. R. Hammond, “The elements,” in Handbook of Chemistry and Physics, CRC Press, 81th edition, 2000. View at Google Scholar
  4. Y. Wei and X. Zhou, “The effect of neodymium (Nd+3) on some physiological activities in oilseed rape during calcium (Ca+2) starvation,” in Proceedings of the 10th International Rapeseed Congress, Canberra, Australia, 1999.
  5. I. L. Dukov and M. Atanassova, “Effect of the diluents on the synergistic solvent extraction of some lanthanides with thenoyltrifluoroacetone and quaternary ammonium salt,” Hydrometallurgy, vol. 68, no. 1–3, pp. 89–96, 2003. View at Publisher · View at Google Scholar · View at Scopus
  6. M. Atanassova and I. L. Dukov, “Synergistic solvent extraction and separation of trivalent lanthanide metals with mixtures of 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one and aliquat 336,” Separation and Purification Technology, vol. 40, no. 2, pp. 171–176, 2004. View at Publisher · View at Google Scholar · View at Scopus
  7. M. Atanassova, “Synergistic solvent extraction and separation of lanthanide(III) Ions with 4-Benzoyl-3-Phenyl-5-Isoxazolone and the quaternary ammonium salt,” Solvent Extraction and Ion Exchange, vol. 27, no. 2, pp. 159–171, 2009. View at Publisher · View at Google Scholar · View at Scopus
  8. M. L. P. Reddy, J. R. Bosco Bharathi, S. Peter, and T. R. Ramamohan, “Synergistic extraction of rare earths with bis(2,4,4-trimethyl pentyl) dithiophosphinic acid and trialkyl phosphine oxide,” Talanta, vol. 50, no. 1, pp. 79–85, 1999. View at Publisher · View at Google Scholar · View at Scopus
  9. E. A. Mowafy and H. F. Aly, “Extraction behaviours of Nd(III), Eu(III), La(III), Am(III), and U(VI) with some substituted malonamides from nitrate medium,” Solvent Extraction and Ion Exchange, vol. 20, no. 2, pp. 177–194, 2002. View at Publisher · View at Google Scholar · View at Scopus
  10. E. A. Mowafy and H. F. Aly, “Extraction behaviors of trivalent lanthanides from nitrate medium by selected substituted malonamides,” Solvent Extraction and Ion Exchange, vol. 24, no. 5, pp. 677–692, 2006. View at Publisher · View at Google Scholar · View at Scopus
  11. Y. Koma, T. Koyama, and Y. Tanaka, “Enhancement of the mutual separation of lanthanide elements in the solvent extraction based on the CMPO-TBP mixed solvent by using a DTPA-nitrate solution,” Journal of Nuclear Science and Technology, vol. 36, no. 10, pp. 934–939, 1999. View at Google Scholar · View at Scopus
  12. W. He, W. Liao, C. Niu, and D. Li, “Synergistic extraction of rare earths using acid-base coupling extractants of calyx[4]arene carboxyl derivative and primary amine N1923,” Separation and Purification Technology, vol. 62, pp. 674–680, 2008. View at Google Scholar
  13. M. Atanassova, V. M. Jordanov, and I. L. Dukov, “Effect of the quaternary ammonium salt Aliquat 336 on the solvent extraction of lanthanoid (III) ions with thenoyltrifluoroacetone,” Hydrometallurgy, vol. 63, no. 1, pp. 41–47, 2002. View at Publisher · View at Google Scholar · View at Scopus
  14. I. L. Dukov and M. Atanassova, “Effect of the diluents on the synergistic solvent extraction of some lanthanides with thenoyltrifluoroacetone and quaternary ammonium salt,” Hydrometallurgy, vol. 68, no. 1-3, pp. 89–96, 2003. View at Publisher · View at Google Scholar · View at Scopus
  15. Q. Jia, Z. Li, W. Zhou, and H. Li, “Studies on the solvent extraction of rare earths from nitrate media with a combination of di(2-etylhexyl) phosphoric acid and sec-octylphenoxyacetic acid,” Journal of Chemical Technology & Biotechnology, vol. 84, pp. 565–569, 2009. View at Google Scholar
  16. M. S. Lee, J. Y. Lee, J. S. Kim, and G. S. Lee, “Solvent extraction of neodymium ions from hydrochloric acid solution using PC88A and saponified PC88A,” Separation and Purification Technology, vol. 46, pp. 72–78, 2005. View at Google Scholar
  17. A. Hino, S. Nishihama, T. Hirai, and I. Komasawa, “Practical study of liquid-liquid extraction process for separation of rare earth elements with bis(2-ethylhexyl) phosphinic acid,” Journal of Chemical Engineering of Japan, vol. 30, no. 6, pp. 1040–1046, 1997. View at Google Scholar · View at Scopus
  18. M. S. Milyukova, N. S. Varezhkina, and B. F. Myasoedov, “Extraction of rare earth elements by high molecular weight amines from nitric acid solutions,” Journal of Radioanalytical and Nuclear Chemistry Letters, vol. 105, no. 4, pp. 249–256, 1986. View at Publisher · View at Google Scholar · View at Scopus
  19. D. D. Desai and V. M. Shinde, “Liquid anion-exchange extraction and separation of yttrium, neodymium and samarium,” Analytica Chimica Acta, vol. 167, pp. 413–417, 1985. View at Google Scholar · View at Scopus
  20. E. B. Sandell, Colorimetric Determination of Traces of Metals, Interscience, New York, NY, USA, 3rd edition, 1965.
  21. Z. H. Gardlund, R. J. Curtis, and G. W. Smith, “Influence of molecular structural changes on the mesomorphic behavior of benzylideneanilines,” Liquid Crystals Ordered Fluids, vol. 2, pp. 541–545, 1973. View at Google Scholar
  22. K. N. Munshi, “Spectrophotometric determination of rare earth metals with 4-(2-pyridylazo)resorcinol,” Analytical Chemistry, vol. 36, no. 10, pp. 2003–2004, 1964. View at Google Scholar · View at Scopus
  23. H. A. Flaschka and A. J. Barnard Jr., Chelates in Analytical Chemistry, vol. 4, Marcel Dekker, New York, NY, USA, 1972.
  24. Z. Marckzenko, Spectrophotometric Determination of Elements, Ellis Horwood Limited, Chichester, UK, 1st edition, 1976.
  25. S. Shibata, F. Takeuchi, and T. Matsumae, “Spectrophotometric determination of lanthanum with neo-thorone,” Analytica Chimica Acta, vol. 21, pp. 177–181, 1959. View at Google Scholar · View at Scopus