The Scientific World Journal / 2012 / Article / Tab 1 / Research Article
Effect of Human and Bovine Serum Albumin on kinetic Chemiluminescence of Mn (III)-Tetrakis (4-Sulfonatophenyl) Porphyrin-Luminol-Hydrogen Peroxide System Table 1 CL kinetic parameters evaluated from computer fitting of the CL intensity-time for luminol-MnTSPP-H2 O2 in the presence of serum albumins.
Parameters Concentration (M)
𝑘
𝑟
(min−1 )
𝑘
𝑓
(min−1 )
𝑀
𝐽
𝐽
e
x
p
𝑇
m
a
x
(min)
𝑇
e
x
p
(min)
𝑌
0
8
0
±
4
2
.
6
±
0
.
4
4
9
3
2
±
2
646 728 0.044 0.049 358 1.5 × 10−6
6
8
±
2
2
.
4
2
±
0
.
0
8
8
4
3
±
3
547 573 0.051 0.060 348 3 × 10−6
6
4
±
3
2
.
3
6
±
0
.
2
3
6
3
0
±
2
402 433 0.053 0.066 183 HSA 4.5 × 10−6
5
8
±
5
2
.
3
1
±
0
.
0
3
4
3
8
±
6
277 313 0.058 0.070 189 6.5 × 10−5
4
7
±
1
2
.
1
8
±
0
.
6
8
3
3
5
±
3
206 225 0.068 0.082 153 9.5 × 10−6
3
9
±
4
2
.
1
±
0
.
8
1
2
7
6
±
3
168 175 0.079 0.086 131 1.5 × 10−5
3
3
±
2
1
.
9
4
±
0
.
2
2
0
4
±
2
177 133 0.091 0.103 105 1.5 × 10−6
6
3
±
7
2
.
4
9
±
1
7
7
6
±
4
523 555 0.053 0.064 311 3 × 10−6
5
3
±
5
2
.
4
2
±
0
.
3
5
5
5
1
±
2
369 375 0.061 0.073 227 BSA 4.5 × 10−6
4
1
±
5
2
.
3
2
±
0
.
7
1
3
6
6
±
2
244 271 0.074 0.08 157 6.5 × 10−5
3
6
±
4
2
±
0
.
1
1
2
9
7
±
1
174 199 0.085 0.097 148 9.5 × 10−6
2
8
.
6
±
6
1
.
9
3
±
1
.
2
2
0
8
±
2
122 157 0.101 0.110 107 1.5 × 10−5
2
2
.
4
±
6
1
.
8
5
±
0
.
2
5
1
5
7
±
3
93 115 0.121 0.132 84
