Research Article

A Simple Approach for Measuring Emission Patterns of Vapor Phase Mercury under Temperature-Controlled Conditions from Soil

Table 2

Summary of experiments using three soil samples with a total weight of 50 ga.
(a) Hg concentration exiting the chamber (ng m−3)

TempC(S1)bC(S2)C(S3-1)C(S3-2)C(S3-3)

25 7.065 3.046 6.568 NMNM
30 10.412 2.607 4.206 DLDL
40 21.194 6.159 3.941 DLDL
50 32.524 4.160 1.822 DLDL
60 13.024 6.565 1.386 0.064 1.025
70 NM4.217 0.883 0.372 3.745

(b) Hg emission flux (ng m−2 h−1)

TempF(S1)F(S2)F(S3-1)F(S3-2)F(S3-3)

25 70.2 30.3 65.3
30 103.5 25.9 41.8
40 210.6 61.2 39.2
50 323.2 41.3 18.1
60 129.4 65.2 13.8 0.6 10.2
70  41.9 8.8 3.7 37.2

(c) Relationship between 1/ 𝑇 versus ln(emission flux)

1 / 𝑇 (abs)ln(F(S1))ln(F(S2))ln(F(S3-1)) ln(F(S3-2))ln(F(S3-3))

0.0034 4.2514 3.4100 4.1785
0.0033 4.6392 3.2546 3.7329
0.0032 5.3500 4.1142 3.6677
0.0031 5.7782 3.7219 2.8961
0.0030 4.8630 4.1780 2.6226 −0.4466 2.3207
0.0029  3.7354 2.1721 1.3071 3.6167

aThree soil samples are named as S1, S2, and S3, and the number of repetition is given after the hyphen.
bInitiation dates for each experiment: S1 (22 December 2009), S2 (30 December 2009), S3-1 (26 January 2010), S3-2 (2 February 2010), and S3-3 (11 February 2010).