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The Scientific World Journal
Volume 2013 (2013), Article ID 134565, 15 pages
Research Article

Solid Phase Extraction of Inorganic Mercury Using 5-Phenylazo-8-hydroxyquinoline and Determination by Cold Vapor Atomic Fluorescence Spectroscopy in Natural Water Samples

1Université Lille 1, Equipe Chimie Analytique et Marine, UMR-CNRS 8217 Géosystèmes, Villeneuve d’Ascq Cedex, France
2Water & Environmental Sciences Laboratory (L.S.E.E), Lebanese University, Lebanon

Received 1 August 2013; Accepted 22 August 2013

Academic Editors: S. D'Ilio, T. Kaneta, S. Lee, and R. Zakrzewski

Copyright © 2013 Mirna Daye et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


8-Hydroxyquinoline (8-HQ) was chosen as a powerful ligand for Hg solid phase extraction. Among several chelating resins based on 8-HQ, 5-phenylazo-8-hydroxyquinoline (5Ph8HQ) is used for mercury extraction in which the adsorption dynamics were fully studied. It has been shown that Hg(II) is totally absorbed by 5Ph8HQ within the first 30 minutes of contact time with t1/2 5 minutes, following Langmuir adsorption model. At pH 4, the affinity of mercury is unchallenged by other metals except, for Cu(II), which have shown higher Kd value. With these latter characteristics, 5Ph8HQ was examined for the preconcentration of trace levels of Hg(II). The developed method showed quantitative recoveries of Hg(II) with LOD = 0.21 pg mL−1 and RSD = 3–6% using cold vapor atomic fluorescence spectroscopy (CV-AFS) with a preconcentration factor greater than 250.