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The Scientific World Journal
Volume 2013, Article ID 907562, 6 pages
http://dx.doi.org/10.1155/2013/907562
Research Article

Synthesis and Use of [Cd(Detu)2(OOCCH3)2]·H2O as Single Molecule Precursor for Cds Nanoparticles

Department of Chemistry, University of Fort Hare, Private Bag X1314, Alice 5700, South Africa

Received 17 June 2013; Accepted 15 July 2013

Academic Editors: A. I. Matesanz, A. Souldozi, and W.-Y. Wong

Copyright © 2013 Peter A. Ajibade. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. J. Duque, O. Estévez-Hernández, E. Reguera, J. Ellena, and R. S. Corrêa, “Synthesis, characterization, and single crystal X-ray structure of the 1-furoyl-3-cyclohexylthiourea cadmium chloride complex, Cd[C4H3OC(O)NHC(S)NHC6H11]4Cl2,” Journal of Coordination Chemistry, vol. 62, no. 17, pp. 2804–2813, 2009. View at Publisher · View at Google Scholar · View at Scopus
  2. R. Del Campo, J. J. Criado, E. García et al., “Thiourea derivatives and their nickel(II) and platinum(II) complexes: antifungal activity,” Journal of Inorganic Biochemistry, vol. 89, no. 1-2, pp. 74–82, 2002. View at Publisher · View at Google Scholar · View at Scopus
  3. P. A. Ajibade and N. H. Zulu, “Synthesis, characterization, and antibacterial activity of metal complexes of phenylthiourea: the X-ray single crystal structure of [Zn(SC(NH2)NHC6H5)2(OOCCH3)2]·C2H5OH,” Journal of Coordination Chemistry, vol. 63, no. 18, pp. 3229–3239, 2010. View at Publisher · View at Google Scholar · View at Scopus
  4. K. S. Kumar, S. K. Singh, and S. N. Pandeya, “Synthesis and antibacterial activity of pyridyl thioureas and arylthiosemicarbazones,” Bollettino Chimico Farmaceutico, vol. 140, no. 4, pp. 238–242, 2001. View at Google Scholar · View at Scopus
  5. I. Küçükgüzel, S. G. Küçükgüzel, S. Rollas, and M. Kiraz, “Some 3-thioxo/alkylthio-1,2,4-triazoles with a substituted thiourea moiety as possible antimycobacterials,” Bioorganic and Medicinal Chemistry Letters, vol. 11, no. 13, pp. 1703–1707, 2001. View at Publisher · View at Google Scholar · View at Scopus
  6. T. K. Venkatachalam, E. A. Sudbeck, and F. M. Uckun, “Regiospecific synthesis, X-ray crystal structure and biological activities of 5-bromothiophenethyl thioureas,” Tetrahedron Letters, vol. 42, no. 38, pp. 6629–6632, 2001. View at Publisher · View at Google Scholar · View at Scopus
  7. M. J. Moloto, M. A. Malik, P. O'Brien, M. Motevalli, and G. A. Kolawole, “Synthesis and characterisation of some N-alkyl/aryl and N,N′-dialkyl/aryl thiourea cadmium(II) complexes: the single crystal X-ray structures of [CdCl2(CS(NH2)NHCH3)2]2n and [CdCl2(CS(NH2)NHCH2CH3)2],” Polyhedron, vol. 22, no. 4, pp. 595–603, 2003. View at Publisher · View at Google Scholar · View at Scopus
  8. V. Venkataramanan, M. R. Srivivasan, and H. L. Bhat, “Vibrational spectroscopic study of zinc tris(thiourea) sulfate, a new organometallic nonlinear-optical crystal,” Journal of Raman Spectroscopy, vol. 25, pp. 805–811, 1994. View at Google Scholar
  9. V. Venkataramanan, H. L. Bhat, M. R. Srinivasao, P. Ayyub, and M. S. Multani, “Vibrational spectroscopic study of the semiorganic nonlinear optical crystal bis(thiourea)cadmium chloride,” Journal of Raman Spectroscopy, vol. 28, no. 10, pp. 779–784, 1997. View at Google Scholar · View at Scopus
  10. M. Stoev, S. Ruseva, and B. Keremidchieva, “Preparation of CdS by thermal decomposition of double salts and saturated solutions of the systems Cd(HCOO)2-CS(NH2)2-CH3OH and Cd(CH3COO)2-CS(NH2)2-CH3OH,” Monatshefte für Chemie Chemical Monthly, vol. 125, no. 11, pp. 1215–1221, 1994. View at Publisher · View at Google Scholar · View at Scopus
  11. M. Stoev and S. Ruseva, “Preparation of cadmium sulfide from CdCl2(CdBr2, CdI2)-CS(NH2)2-CH3OH systems,” Monatshefte für Chemie, vol. 125, no. 6-7, pp. 599–606, 1994. View at Publisher · View at Google Scholar · View at Scopus
  12. M. A. Martínez, C. Guillén, and J. Herrero, “Morphological and structural studies of CBD-CdS thin films by microscopy and diffraction techniques,” Applied Surface Science, vol. 136, no. 1-2, pp. 8–16, 1998. View at Google Scholar · View at Scopus
  13. M. J. Moloto, N. Revaprasadu, P. O'Brien, and M. A. Malik, “N-alkylthioureacadmium (II) complexes as novel precursors for the synthesis of CdS nanoparticles,” Journal of Materials Science, vol. 15, no. 5, pp. 313–316, 2004. View at Publisher · View at Google Scholar · View at Scopus
  14. P. S. Nair, N. Revaprasadu, T. Radhakrishnan, and G. A. Kolawole, “Preparation of CdS nanoparticles using the cadmium(II) complex of N,N′-bis(thiocarbamoyl)hydrazine as a simple single-source precursor,” Journal of Materials Chemistry, vol. 11, no. 6, pp. 1555–1556, 2001. View at Publisher · View at Google Scholar · View at Scopus
  15. P. S. Nair, M. M. Chili, T. Radhakrishnan, N. Revaprasadu, P. Christian, and P. O'Brien, “Some effects of the nature of the ligands and temperature of decomposition on the formation of CdS nanoparticles from cadmium complexes of alkyl-substituted thioureas,” South African Journal of Science, vol. 101, no. 9-10, pp. 466–470, 2005. View at Google Scholar · View at Scopus
  16. Bruker, “SAINT. Version 6. 36a,” Bruker AXS, Madison, Wis, USA, 2002.
  17. Bruker, “SMART (Version 5. 625), SADABS (Version 2. 03a) and SHELXTL (Version 6. 12),” Bruker AXS, Madison, Wis, USA, 2001.
  18. G. M. Sheldrick, TWINABS, University of Göttingen, Germany, 2007.
  19. M. C. Burla, R. Caliandro, M. Camalli et al., “SIR2004: an improved tool for crystal structure determination and refinement,” Journal of Applied Crystallography, vol. 38, no. 2, pp. 381–388, 2005. View at Publisher · View at Google Scholar · View at Scopus
  20. A. A. Aly, E. K. Ahmed, K. M. El-Mokadem, and M. E.-A. F. Hegazy, “Update survey on aroyl substituted thioureas and their applications,” Journal of Sulfur Chemistry, vol. 28, no. 1, pp. 73–93, 2007. View at Publisher · View at Google Scholar · View at Scopus
  21. M. Merdivan, F. Karipçin, N. Kulcu, and R. S. Aygün, “Study of the thermal decompositions on N, N-dialkyl-N′-benzoylthiourea complexes of Cu(II), Ni(II), Pd(II), Pt(II), Cd(II), Ru(III) and Fe(III),” Journal of Thermal Analysis and Calorimetry, vol. 58, pp. 551–557, 1999. View at Google Scholar
  22. T. Mandal, V. Stavila, I. Rusakova, S. Ghosh, and K. H. Whitmire, “Molecular precursors for cds nanoparticles: synthesis and characterization of carboxylate-Thiourea or -Tcadmium complexes and their decomposition,” Chemistry of Materials, vol. 21, no. 23, pp. 5617–5626, 2009. View at Publisher · View at Google Scholar · View at Scopus