Research Article
Synthesis and Use of [Cd(Detu)2(OOCCH3)2]·H2O as Single Molecule Precursor for Cds Nanoparticles
Table 2
Selected bond length and angles for [Cd(detu)2(CH3COO)2]·H2O.
| | Bond length (Å) | Bond angles (°) |
| | Cd(1)–O(4) | 2.3077(18) | S(1)–Cd(1)–S(2) | 102.83(3) | | Cd(1)–O(2) | 2.3714(18) | O(2)–Cd(1)–O(1) | 54.51(6) | | Cd(1)–O(1) | 2.4200(18) | O(4)–Cd(1)–O(3) | 54.20(6) | | Cd(1)–O(3) | 2.4753(17) | O(2)–Cd(1)–O(3) | 79.28(6) | | Cd(1)–S(1) | 2.5587(8) | C(2)–S(1)–Cd(1) | 108.82(8) | | Cd(1)–S(2) | 2.5656(9) | C(6)–S(2)–Cd(1) | 115.59(8) | | Cd(1)–C(13) | 2.745(2) | O(4)–Cd(1)–S(1) | 114.64 | | Cd(1)–C(11) | 2.748(2) | O(2)–Cd(1)–S(1) | 145.57(4) | | O(1)–C(11) | 1.271(3) | O(1)–Cd(1)–S(1) | 95.20(4) | | O(1)–C(13) | 1.249(3) | O(3)–Cd(1)–S(1) | 93.72(5) | | O(1)–C(13) | 1.252(3) | O(4)–Cd(1)–S(2) | 97.49(4) | | O(1)–C(13) | 1.259(3) | O(2)–Cd(1)–S(2) | 98.55(5) | | S(1)–C(1) | 1.727(2) | O(1)–Cd(1)–S(2) | 99.43(4) | | S(2)–C(6) | 1.730(2) | O(3)–Cd(1)–S(2) | 151.48(4) | | N(1)–C(1) | 1.327(3) | N(2)–C(1)–N(1) | 119.1(2) | | N(1)–C(2) | 1.459(3) | N(4)–C(6)–N(3) | 119.8(2) | | N(2)–C(1) | 1.324(3) | N(2)–C(1)–S(1) | 120.10(17) | | N(2)–C(4) | 1.458(3) | N(1)–C(1)–S(1) | 120.81(17) | | | | N(4)–C(6)–S(2) | 121.62(17) | | | | N(3)–C(6)–S(2) | 118.51(17) |
|
|
