Research Article
Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of N-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions
Table 3
Values of , , and calculated from (1) for alkaline hydrolysis of 1 in the presence of
micellesa.
| ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
[1 0] = 0.1 mM, nm, °C, and the aqueous reaction mixture contained 2% v/v CH3CN. [NaOH]. with M−1 cm−1. = [C12E23]T/[NaOH].
is reaction time () where the kinetic reaction mixture was used for micellar entrapment experiment. fCalculated from the relationship: . gValue of [C12E23]T after external addition of [NaOH]. hError limits are standard deviations. iReaction mixture for kinetic run was freshly prepared, where . |