Research Article
Effect of Catalytic Pyrolysis Conditions Using Pulse Current Heating Method on Pyrolysis Products of Wood Biomass
Table 1
GC-MS semiquantitative analysis of pyrolysis oil components obtained from Japanese cedar wood meal/catalyst (1 : 1 w/w) mixtures pyrolyzed at 500°C.
| Retention time | Pyrolysis oil | Pyrolysis oil | Pyrolysis oil | Pyrolysis oil | Japanese cedar wood meal [10] | Mixture with Fe3O4 | Mixture with TiO2 | Mixture with ZSM-5 | (min) | Area/I. S. area | Area/I. S. area | Area/I. S. area | Area/I. S. area |
| 6.21 Benzene | — | 0.32 | 0.27 | — | 8.85 Toluene | — | 0.24 | 0.16 | — | 10.14 Furfural | 0.12 | 0.11 | 0.07 | 0.04 | 10.97 Ethynylbenzene | — | 0.03 | — | — | 11.25 Styrene | — | 0.18 | 0.13 | — | 12.48 Phenol | — | 0.73 | 0.64 | 0.28 | 13.62 o-Cresol | — | 0.29 | 0.30 | 0.14 | 13.74 1-Propynylbenzene | — | — | — | — | 13.90 p-Cresol | — | 0.57 | 0.48 | 0.26 | 14.19 Guaiacol | 0.11 | 0.04 | — | — | 15.40 Catechol | 0.09 | 0.20 | 0.17 | 0.17 | 15.57 m-Cresol | 0.16 | 0.04 | — | — | 15.77 Naphthalene | — | 0.51 | 0.82 | 0.17 | 17.07 Methylnaphthalene | — | 0.18 | 0.19 | — | 17.45 Eugenol | 0.04 | 0.07 | — | — | 17.95 Biphenyl | — | — | 0.06 | — | 18.00 Vanillin | 0.08 | 0.04 | — | — | 18.49 Isoeugenol | 0.12 | 0.05 | 0.04 | — | 18.89 Acenaphthylene | — | 0.12 | 0.30 | — | 20.22 o-Biphenylenemethane | — | — | — | — | 21.84 Phenanthrene | — | 0.05 | 0.16 | — | 21.91 Anthracene | — | — | — | — | 24.05 Pyrene | — | — | — | — | 25.00 Internal standard (tetracosane) | 1.00 | 1.00 | 1.00 | 1.00 |
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