Research Article
Effect of Catalytic Pyrolysis Conditions Using Pulse Current Heating Method on Pyrolysis Products of Wood Biomass
Table 2
GC-MS semiquantitative analysis of pyrolysis oil components obtained from Japanese cedar wood meal/catalyst (1 : 1 w/w) mixtures pyrolyzed at 800°C.
| Retention time | Pyrolysis oil | Pyrolysis oil | Pyrolysis oil | Pyrolysis oil | Japanese cedar wood meal [10] | Mixture with Fe3O4 | Mixture with TiO2 | Mixture with ZSM-5 | (min) | Area/I. S. area | Area/I. S. area | Area/I. S. area | Area/I. S. area |
| 6.21 Benzene | 0.63 | 0.21 | 0.25 | 0.04 | 8.85 Toluene | 0.18 | 0.03 | 0.01 | 0.06 | 10.14 Furfural | — | — | — | — | 10.97 Ethynylbenzene | 0.26 | — | 0.02 | — | 11.25 Styrene | 0.24 | 0.03 | 0.01 | — | 12.48 Phenol | 0.12 | 0.14 | — | 0.28 | 13.62 o-Cresol | — | 0.03 | — | 0.14 | 13.74 1-Propynylbenzene | 0.50 | — | — | — | 13.90 p-Cresol | — | 0.07 | — | 0.22 | 14.19 Guaiacol | — | 0.07 | — | 0.19 | 15.40 Catechol | — | — | — | 0.18 | 15.57 m-Cresol | — | — | — | — | 15.77 Naphthalene | 0.95 | 1.15 | 0.61 | 0.47 | 17.07 Methylnaphthalene | 0.12 | 0.04 | 0.02 | 0.27 | 17.45 Eugenol | — | 0.03 | — | — | 17.95 Biphenyl | 0.10 | — | 0.01 | 0.09 | 18.00 Vanillin | — | 0.07 | — | — | 18.49 Isoeugenol | — | 0.11 | — | — | 18.89 Acenaphthylene | 0.59 | 0.65 | 0.41 | 0.36 | 20.22 o-Biphenylenemethane | 0.24 | — | — | — | 21.84 Phenanthrene | 0.37 | 0.24 | 0.12 | 0.05 | 21.91 Anthracene | 0.14 | 0.05 | — | 0.14 | 24.05 Pyrene | 0.29 | 0.19 | 0.24 | — | 25.00 Internal standard (tetracosane) | 1.00 | 1.00 | 1.00 | 1.00 |
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