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Advances in Meteorology
Volume 2012, Article ID 140932, 18 pages
http://dx.doi.org/10.1155/2012/140932
Research Article

Examining the Impact of Nitrous Acid Chemistry on Ozone and PM over the Pearl River Delta Region

1Department of Mathematics, The Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong
2Atmospheric Modeling and Analysis Division, National Exposure Research Laboratory, Office of Research and Development, US Environmental Protection Agency, RTP, NC 27711, USA
3Division of Environment, The Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong
4College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China

Received 16 February 2012; Accepted 3 April 2012

Academic Editor: Tareq Hussein

Copyright © 2012 Rui Zhang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The impact of nitrous acid (HONO) chemistry on regional ozone and particulate matter in Pearl River Delta region was investigated using the community multiscale air quality (CMAQ) modeling system and the CB05 mechanism. Model simulations were conducted for a ten-day period in October 2004. Compared with available observed data, the model performance for NOx, SO2, PM10, and sulfate is reasonably good; however, predictions of HONO are an order of magnitude lower than observed data. The CB05 mechanism contains several homogenous reactions related to HONO. To improve the model performance for HONO, direct emissions, two heterogeneous reactions, and two surface photolysis reactions were incorporated into the model. The inclusion of the additional formation pathways significantly improved simulated HONO compared with observed data. The addition of HONO sources enhances daily maximum 8-hour ozone by up to 6 ppbV (8%) and daily mean PM2.5 by up to 17 ug/m3 (12%). They also affected ozone control strategy in Pearl River Delta region.