Lattice Dynamics of Gd<sub>1−<i>x</i></sub>Y<sub><i>x</i></sub>Mn<sub>2</sub>O<sub>5</sub> Investigated by Infrared Spectroscopy

<div>The high frequency dielectric constant, <svg height="9.25202pt" id="M255" style="vertical-align:-3.29111pt" version="1.1" viewbox="-0.0498162 -5.96091 15.2854 9.25202" width="15.2854pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M401 397C401 420 368 448 302 448C245 448 169 416 122 377C62 327 23 254 23 169C23 45 83 -12 181 -12C252 -12 323 29 374 85L358 107C305 62 257 43 210 43C147 43 110 98 110 189V214L313 208L321 256L115 250C132 342 190 405 253 405C291 405 323 389 346 360C356 348 364 348 377 357C392 367 401 384 401 397Z" id="g113-227"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="424" vert-adv-y="424" xpluscharwidth="5.512"></glyph.data></g><g transform="matrix(.0091,0,0,-0.0091,5.187,3.132)"><path d="M1000 227C1000 351 905 451 780 451C658 451 590 380 530 279C465 385 388 451 261 451C168 451 38 376 38 210C38 98 121 -12 261 -12C381 -12 448 59 508 160C573 53 652 -12 780 -12C879 -12 1000 64 1000 227ZM485 199C434 109 370 25 271 25C188 25 133 117 133 241C133 355 189 414 249 414C357 414 426 302 485 199ZM903 204C903 70 852 25 790 25C681 25 611 136 552 240C603 330 669 414 768 414C855 414 903 321 903 204Z" id="g50-30"></path><glyph.data ascent="3443" descent="-2856" horiz-adv-x="1038" vert-adv-y="1038" xpluscharwidth="14.632768859999999"></glyph.data></g></svg> (closed circle), and static dielectric constant, <svg height="9.36162pt" id="M256" style="vertical-align:-3.40071pt" version="1.1" viewbox="-0.0498162 -5.96091 9.32085 9.36162" width="9.32085pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M401 397C401 420 368 448 302 448C245 448 169 416 122 377C62 327 23 254 23 169C23 45 83 -12 181 -12C252 -12 323 29 374 85L358 107C305 62 257 43 210 43C147 43 110 98 110 189V214L313 208L321 256L115 250C132 342 190 405 253 405C291 405 323 389 346 360C356 348 364 348 377 357C392 367 401 384 401 397Z" id="g113-227"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="424" vert-adv-y="424" xpluscharwidth="5.512"></glyph.data></g><g transform="matrix(.0091,0,0,-0.0091,5.187,3.132)"><path d="M339 262C339 340 273 403 193 403S48 340 48 262S113 121 193 121S339 184 339 262ZM283 262C283 210 242 168 193 168S104 210 104 262S144 356 193 356S283 314 283 262Z" id="g54-73"></path><glyph.data ascent="3443" descent="-2856" horiz-adv-x="385" vert-adv-y="385" xpluscharwidth="8.69048845"></glyph.data></g></svg> (closed square), as a function of concentration <svg height="6.1673pt" id="M257" style="vertical-align:-0.2063904pt" version="1.1" viewbox="-0.0498162 -5.96091 7.39387 6.1673" width="7.39387pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M536 404C536 423 520 448 491 448C445 448 398 404 308 283L286 338C255 416 242 448 217 448C182 448 138 402 92 341L111 321C149 368 169 378 178 378C188 378 198 363 214 320L254 212C185 117 138 65 107 65C98 65 85 69 82 75C79 82 73 86 65 86C44 86 23 60 23 39C23 7 44 -12 71 -12C119 -12 168 33 265 177L306 61C321 17 347 -12 373 -12C413 -12 465 33 507 96L491 119C459 84 432 60 413 60C395 60 378 92 358 148L321 250C341 279 369 310 389 332C417 363 439 382 456 382C466 382 475 376 481 368C486 361 492 358 496 358C513 358 536 381 536 404Z" id="g113-121"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="559" vert-adv-y="559" xpluscharwidth="7.267"></glyph.data></g></svg>.</div>

Advances in Materials Science and Engineering

fig6

Figure 6

Figure 6: Lattice Dynamics of Gd<sub>1−<i>x</i></sub>Y<sub><i>x</i></sub>Mn<sub>2</sub>O<sub>5</sub> Investigated by Infrared Spectroscopy 

Advances in Materials Science and Engineering

Lattice Dynamics of Gd1−xYxMn2O5 Investigated by Infrared Spectroscopy

Figure 6

Lattice Dynamics of Gd_1−xY_xMn₂O₅ Investigated by Infrared Spectroscopy