Research Article
Ionothermal Synthesis of a Novel 3D Cobalt Coordination Polymer with a Uniquely Reported Framework: [BMI]2[Co2(BTC)2(H2O)2]
Table 1
Crystallographic data for Co-BTC metal organic frameworks synthesized with [RMI]Br ionic liquids (RMI = EMI, PMI, BMI).
| | | [EMI]2[Co3(BTC)2(OAc)2] | [PMI]2[Co2(BTC)2(H2O)2] | [BMI]2[Co2(BTC)2(H2O)2] |
| | Empirical formula | C22H12Co3O16 | C16H18CoN2O7 | C17H20CoN2O7 | | Fw | 709.11 | 409.26 | 423.28 | | Space group | Pbca | P2(1)/n | P2(1)/n | | Crystal system | Orthorhombic | Monoclinic | Monoclinic | | (Å) | 14.2616(4) | 11.279(10) | 11.1946(5) | | (Å) | 16.1525(5) | 10.679(10) | 10.7911(5) | | (Å) | 16.4867(5) | 15.428(14) | 15.3026(8) | | α (deg) | 90.00 | 90.00 | 90.00 | | β (deg) | 90.00 | 95.276(14) | 95.3550(10) | | γ (deg) | 90.00 | 90.00 | 90.00 | | Cell volume | 3797.9(2) | 1850.406 | 1840.52(15) | | 4 | 4 | 4 | | (K) | 90(2) | 273 | 173(2) | | factor | 0.0323 | 0.0522 | 0.0183 | | Reference | [27] | [26] | This work |
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The reference in the article.
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