Research Article

Ionothermal Synthesis of a Novel 3D Cobalt Coordination Polymer with a Uniquely Reported Framework: [BMI]2[Co2(BTC)2(H2O)2]

Table 2

Selected bond lengths [Å] and bond angles [deg] of [BMI]2[Co2(BTC)2(H2O)2].

Co(1)-O(2)#11.9830(13)O(2)#1-Co(1)-O(5)#391.75(6)
Co(1)-O(1)1.9904(14)O(1)-Co(1)-O(5)#393.06(6)
Co(1)-O(3)#22.0116(13)O(3)#2-Co(1)-O(5)#389.12(6)
Co(1)-O(5)#32.0524(13)O(2)#1-Co(1)-O(7)84.43(6)
Co(1)-O(7)2.1314(14)O(1)-Co(1)-O(7)92.24(6)
O(2)#1-Co(1)-O(1)138.72(6)O(3)#2-Co(1)-O(7)89.40(6)
O(2)#1-Co(1)-O(3)#2117.73(6)O(5)#3-Co(1)-O(7)174.69(6)
O(1)-Co(1)-O(3)#2103.32(6)

Symmetry transformations: #1: , , ; #2: , , ; #3: , , .