Alternative to Water Based Fabric Cleaner in Textile and Detergent Processes
Table 1
Physicochemical properties of different chemical reactants in EHOs detergent formulations [22–24].
CR (MF)
Two-dimensional structure
MW (g mol−1)
MP (˚C)
BP (˚C)
RB
HD
HA
pKa
Potassium hydroxide (KOH)
56.1
380
1327
0
1
1
16
Ethanol (C2H6O)
46.1
78.3
0
1
1
15.5
Sodium hydroxide (NaOH)#
40.0
323
1388
0
1
1
14.8
Water (H2O)
18.0
0
100
0
1
1
14
Hydrogen peroxide (H2O2)
34.0
152
0
2
2
11.6
Citric acid (C6H8O7)
192.1
153
—
5
4
7
pKa1 = 3.1 pKa2 = 4.8 pKa3 = 6.4
Note: represents the possible replacement of KOH in EHOs detergent formulations. values are listed using water solvent at 25˚C. CR: chemical reagent; MF: molecular formula; MW: molecular weight; MP: melting point; BP: boiling point; RB: rotatable bond count; HD: hydrogen bond donor count; HA: hydrogen bond acceptor count.