Research Article

Comparative Catalytic Evaluation of Nano-ZrOx Promoted Manganese Catalysts: Kinetic Study and the Effect of Dopant on the Aerobic Oxidation of Secondary Alcohols

Table 3

Effect of reaction temperature on the catalytic performance.

EntryReaction temp. (°C)Conv. (%)Sp. activity (mmol·g−1·h−1)Sel. (%)

12044.828.96>99
24060.0512.01>99
36074.5314.91>99
48087.9617.59>99
510010020.0>99

Reaction conditions: 2 mmol of 1-phenylethanol, 300 mg of catalyst, calcination temperature at 300°C, oxygen with rate 20 mL min−1, 10 mL of toluene, and 20 min of reaction time.