Research Article

Comparative Catalytic Evaluation of Nano-ZrOx Promoted Manganese Catalysts: Kinetic Study and the Effect of Dopant on the Aerobic Oxidation of Secondary Alcohols

Table 4

Effect of catalyst amount in oxidation of 1-phenylethanol.

EntryCatalyst amount (mg)Conv. (%)Sp. activity (mmol·g−1·h−1)Sel. (%)

110041.8183.62>99
220057.6657.66>99
330072.4348.29>99
440086.7543.38>99
550010040.0>99

Reaction conditions: 2 mmol of 1-phenylethanol, calcination temperature at 300°C, oxygen with rate 20 mL min−1, reaction temperature at 100°C, 10 mL of toluene, and 6 min of reaction time.