Comparative Catalytic Evaluation of Nano-ZrO_x Promoted Manganese Catalysts: Kinetic Study and the Effect of Dopant on the Aerobic Oxidation of Secondary Alcohols

Table 5

Comparison between our work and earlier publications for the selective oxidation of 1-phenylethanol into acetophenone.

Catalyst	Conv. (%)	Sel. (%)	T (°C)	Time (h)	Sp. activity (mmol·g^−1·h^−1)	Ref.
1% ZrOx–MnCO3	100	>99	100	0.1	40.0	This work
NbP–S2	72	100	90	24	2.74	[3]
VOPO4	38.5	89	80	6	8.02	[8]
Pd/GC	18.9	>99.9	110	6	0.50	[15]
Ru/Mg–LaO	96	>99	80	4	2.4	[9]
FeAPO	56.2	100	70	6	7.45	[67]
CoAl2O4	63.45	83.25	80	8	0.79	[36]
POM/ZrO2	88	>99	RT	3	11.73	[68]
Fe(NO3)3·9H2O	92	>99	RT	48	1.92	[69]
Ru/CaO–ZrO2	>99	>98	40	6	1.67	[70]
CuZnO	>99	>99	RT	3	33.33	[50]
NG900	1.8	>98	70	3	0.02	[51]
Oxo–V SB/G	89	>99	65	0.33	13.35	[71]
Cu(II)–Zn(II)	78	>99	100	14	16.39	[52]
Fe3O4	76	>99	80	18	1.4	[72]
UiO–66–Sal–CuCl2	45	99	60	24	4.34	[73]
Co(II)/ZnO	95	100	70	13	1.45	[74]
CeCrO3	100	100	90	6	15.15	[75]
Co(acac)2	94	100	40	7	6.1	[76]
Na/CoCl3	99	100	RT	46	0.43	[77]
Au/HT	99	99	RT	6	416	[78]
Au/CeO2	>99	>99	100	5	173	[79]
Pd/HAP	>99	>99	90	1	208	[80]