Research Article
Effect of Rare Earth Metals, Sr, and Ti Addition on the Microstructural Characterization of A413.1 Alloy
(a) Silicon particle characteristics of A413.1 alloys (no Sr), graphite mold |
| Alloy code | Composition | Silicon particle characteristics | Eutectic temp (°C) | Aimed | Actual | Area (µm2) | Length (µm) | Aspect ratio | Density (number/mm2) | La (wt%) | Ce (wt%) | La (wt%) | Ce (wt%) | Average | SD | Average | SD |
| TE | 0 | 0 | 0 | 0 | 31.88 | 73.21 | 11.62 | 16.56 | 2.77 | 2662 | 574 | TE10 | 0.2 | 0 | 0.187 | 0 | 17.67 | 28.56 | 8.27 | 9.36 | 2.55 | 3695 | 571 | TE1 | 0.5 | 0 | 0.284 | 0 | 37.74 | 77.81 | 12.48 | 16.34 | 2.69 | 2224 | 572 | TE2 | 1 | 0 | 0.717 | 0 | 33.48 | 78.40 | 10.77 | 14.55 | 2.47 | 2129 | 571 | TE3 | 1.5 | 0 | 0.940 | 0 | 39.89 | 99.13 | 11.06 | 16.15 | 2.34 | 2365 | 570 | TE11 | 0 | 0.2 | 0.022 | 0.083 | 20.00 | 31.48 | 9.28 | 10.43 | 2.78 | 3200 | 567 | TE4 | 0 | 0.5 | 0.237 | 0.308 | 36.76 | 82.67 | 11.14 | 16.07 | 2.41 | 1965 | 571 | TE5 | 0 | 1 | 0.067 | 0.300 | 42.22 | 94.57 | 12.33 | 17.83 | 2.47 | 1899 | 571 | TE6 | 0 | 1.5 | 0.078 | 0.634 | 39.55 | 90.24 | 11.90 | 17.26 | 2.52 | 2394 | 571 | TE7 | 0.5 | 0.5 | 0.321 | 0.163 | 31.06 | 73.44 | 10.20 | 14.80 | 2.46 | 2544 | 571 | TE8 | 1 | 1 | 0.511 | 0.387 | 38.12 | 72.24 | 13.57 | 14.09 | 2.39 | 1850 | 572 | TE9 | 1.5 | 1.5 | 0.840 | 0.497 | 46.62 | 98.33 | 15.48 | 15.67 | 2.38 | 1318 | 571 |
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Note. Mold temperature: 600°C. SD: standard deviation.
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(b) Silicon particle characteristics of A413.1 alloys (with Sr), graphite mold |
| Alloy code | Composition | Silicon particle characteristics | Eutectic temp (°C) | Aimed | Actual | Area (μm2) | Length (μm) | Aspect ratio | Density (number/mm2) | Sr (ppm) | La (wt%) | Ce (wt%) | Sr (ppm) | La (wt%) | Ce (wt%) | Average | SD | Average | SD |
| TES | 100 | 0 | 0 | 0.0088 | 0 | 0 | 2.35 | 1.25 | 0.95 | 0.12 | 1.35 | 45435 | 568 | TE10S | 100 | 0.2 | 0 | 78 | 0.187 | 0 | 3.248 | 4.687 | 2.772 | 3.920 | 1.921 | 41495 | 571 | TE1S | 100 | 0.5 | 0 | 87 | 0.284 | 0 | 6.981 | 8.023 | 5.584 | 6.586 | 2.188 | 5376 | 567 | TE2S | 100 | 1 | 0 | 65 | 0.717 | 0 | 6.785 | 8.011 | 5.079 | 6.574 | 2.104 | 15613 | 569 | TE3S | 100 | 1.5 | 0 | 79 | 0.94 | 0 | 11.700 | 26.650 | 7.287 | 8.096 | 2.164 | 4402 | 568 | TE11S | 100 | 0 | 0.2 | 193 | 0.022 | 0.083 | 3.556 | 4.983 | 2.890 | 3.836 | 2.019 | 26520 | 570 | TE4S | 100 | 0 | 0.5 | 123 | 0.237 | 0.308 | 3.110 | 4.426 | 2.806 | 2.812 | 1.968 | 44959 | 570 | TE5S | 100 | 0 | 1 | 81 | 0.067 | 0.300 | 5.914 | 10.290 | 4.193 | 4.316 | 2.071 | 4165 | 567 | TE6S | 100 | 0 | 1.5 | 80 | 0.078 | 0.634 | 7.839 | 14.970 | 4.648 | 5.280 | 2.020 | 18047 | 569 | TE7S | 100 | 0.5 | 0.5 | 79 | 0.321 | 0.163 | 4.884 | 6.043 | 3.679 | 4.948 | 2.233 | 15065 | 568 | TE8S | 100 | 1 | 1 | 84 | 0.511 | 0.387 | 9.330 | 11.650 | 5.682 | 8.138 | 2.274 | 4557 | 568 | TE9S | 100 | 1.5 | 1.5 | 81 | 0.84 | 0.497 | 16.876 | 7.541 | 7.237 | 9.321 | 2.086 | 4912 | 572 |
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Note. Mold temperature: 600°C. SD: standard deviation.
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