Thermodynamic Study of Tl<sub>6</sub>SBr<sub>4</sub> Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides

<table class="table-group" id="tab5"><tr><td><table class="table"><tr><td class="thead-hr" colspan="7"><hr/></td></tr><tr class="thead"><td class="align_left" rowspan="2">Compound</td><td class="align_center"><span style="width: 31.2515ptpx;"><svg height="14.8871pt" id="M159" style="vertical-align:-3.2957pt" version="1.1" viewbox="-0.0498162 -11.5914 31.2515 14.8871" width="31.2515pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M600 0V24L339 665L311 657L43 24V0H600ZM497 50H107L303 539L497 50Z" id="g113-133"></path></g><g transform="matrix(.0091,0,0,-0.0091,9.958,3.132)"><path d="M442 39L431 68C420 63 406 57 394 57C377 57 359 71 359 118V301C359 353 349 393 314 424C291 443 261 451 230 451C171 438 107 401 79 381C59 366 46 355 46 340C46 316 72 295 91 295C106 295 117 303 122 319C131 350 139 371 152 384C163 397 178 404 197 404C246 404 281 365 281 293V278C260 262 186 232 124 213C69 194 41 161 41 112C41 47 92 -12 163 -12C195 -12 243 25 283 51C288 35 293 22 308 7C319 -4 339 -12 354 -12L442 39ZM281 87C262 68 226 51 199 51C169 51 129 74 129 126C129 162 151 181 190 198C211 208 259 229 281 240V87Z" id="g58-95"></path></g><g transform="matrix(.0091,0,0,-0.0091,13.88,3.132)"><path d="M303 37L293 66C280 59 256 49 231 49S173 63 173 143V396H281C294 404 298 428 287 439H173V575L158 577L92 509V439H46L17 408L22 396H92V107C92 27 128 -12 192 -12C203 -12 218 -9 237 2L303 37Z" id="g58-114"></path></g><g transform="matrix(.013,0,0,-0.013,17.243,0)"><path d="M673 297H417L411 270C517 261 522 258 506 183L487 92C476 38 428 19 360 19C207 19 123 132 123 287C123 472 243 631 441 631C557 631 617 583 617 469L647 472C650 545 655 604 658 632C625 643 554 666 467 666C201 666 23 502 23 278C23 90 156 -16 339 -16C410 -16 501 6 569 24C566 43 567 70 573 101L589 183C604 259 607 262 667 271L673 297Z" id="g113-72"></path></g><g transform="matrix(.0091,0,0,-0.0091,26.135,-5.741)"><path d="M245 635C92 635 37 457 37 312C37 149 91 -12 244 -12C395 -12 449 166 449 312C449 469 395 635 245 635ZM243 598C332 598 358 454 358 312C358 173 334 26 245 26C158 26 128 174 128 313S152 598 243 598Z" id="g50-49"></path></g></svg></span></td><td class="align_center"><span style="width: 38.0068ptpx;"><svg height="17.1204pt" id="M160" style="vertical-align:-5.528999pt" version="1.1" viewbox="-0.0498162 -11.5914 38.0068 17.1204" width="38.0068pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M535 230V280H52V230H535Z" id="g117-33"></path></g><g transform="matrix(.013,0,0,-0.013,7.631,0)"><path d="M600 0V24L339 665L311 657L43 24V0H600ZM497 50H107L303 539L497 50Z" id="g113-133"></path></g><g transform="matrix(.0091,0,0,-0.0091,17.589,3.132)"><path d="M620 667C620 684 593 710 552 710C515 710 459 687 409 634C360 582 334 506 320 433H247L215 400L220 388H310L259 80C224 -129 199 -161 185 -174C175 -183 160 -192 141 -192C123 -192 90 -181 75 -165C69 -158 64 -156 54 -164C39 -178 24 -195 24 -208C24 -231 61 -257 94 -257C124 -257 162 -243 209 -194C267 -134 303 -66 343 107C369 220 378 279 393 385L503 397L523 433H404C432 619 464 660 500 660C522 660 542 646 566 621C573 614 583 615 593 621C603 628 620 648 620 667Z" id="g50-103"></path></g><g transform="matrix(.013,0,0,-0.013,23.97,0)"><path d="M673 297H417L411 270C517 261 522 258 506 183L487 92C476 38 428 19 360 19C207 19 123 132 123 287C123 472 243 631 441 631C557 631 617 583 617 469L647 472C650 545 655 604 658 632C625 643 554 666 467 666C201 666 23 502 23 278C23 90 156 -16 339 -16C410 -16 501 6 569 24C566 43 567 70 573 101L589 183C604 259 607 262 667 271L673 297Z" id="g113-72"></path></g><g transform="matrix(.0091,0,0,-0.0091,32.862,-5.741)"><path d="M245 635C92 635 37 457 37 312C37 149 91 -12 244 -12C395 -12 449 166 449 312C449 469 395 635 245 635ZM243 598C332 598 358 454 358 312C358 173 334 26 245 26C158 26 128 174 128 313S152 598 243 598Z" id="g50-49"></path></g></svg></span></td><td class="align_center"><svg height="17.1204pt" id="M161" style="vertical-align:-5.528999pt" version="1.1" viewbox="-0.0498162 -11.5914 38.0068 17.1204" width="38.0068pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M535 230V280H52V230H535Z" id="g117-33"></path></g><g transform="matrix(.013,0,0,-0.013,7.631,0)"><path d="M600 0V24L339 665L311 657L43 24V0H600ZM497 50H107L303 539L497 50Z" id="g113-133"></path></g><g transform="matrix(.0091,0,0,-0.0091,17.589,3.132)"><path d="M620 667C620 684 593 710 552 710C515 710 459 687 409 634C360 582 334 506 320 433H247L215 400L220 388H310L259 80C224 -129 199 -161 185 -174C175 -183 160 -192 141 -192C123 -192 90 -181 75 -165C69 -158 64 -156 54 -164C39 -178 24 -195 24 -208C24 -231 61 -257 94 -257C124 -257 162 -243 209 -194C267 -134 303 -66 343 107C369 220 378 279 393 385L503 397L523 433H404C432 619 464 660 500 660C522 660 542 646 566 621C573 614 583 615 593 621C603 628 620 648 620 667Z" id="g50-103"></path></g><g transform="matrix(.013,0,0,-0.013,23.97,0)"><path d="M673 297H417L411 270C517 261 522 258 506 183L487 92C476 38 428 19 360 19C207 19 123 132 123 287C123 472 243 631 441 631C557 631 617 583 617 469L647 472C650 545 655 604 658 632C625 643 554 666 467 666C201 666 23 502 23 278C23 90 156 -16 339 -16C410 -16 501 6 569 24C566 43 567 70 573 101L589 183C604 259 607 262 667 271L673 297Z" id="g113-72"></path></g><g transform="matrix(.0091,0,0,-0.0091,32.862,-5.741)"><path d="M245 635C92 635 37 457 37 312C37 149 91 -12 244 -12C395 -12 449 166 449 312C449 469 395 635 245 635ZM243 598C332 598 358 454 358 312C358 173 334 26 245 26C158 26 128 174 128 313S152 598 243 598Z" id="g50-49"></path></g></svg> (b.c) </td><td class="align_center"><span style="width: 33.2871ptpx;"><svg height="14.8871pt" id="M162" style="vertical-align:-3.2957pt" version="1.1" viewbox="-0.0498162 -11.5914 33.2871 14.8871" width="33.2871pt" xmlns="http://www.w3.org/2000/svg" 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192 -12C203 -12 218 -9 237 2L303 37Z" id="g58-114"></path></g><g transform="matrix(.013,0,0,-0.013,17.243,0)"><path d="M828 650H570L564 622C646 614 650 609 634 524L604 366H253L281 524C296 608 308 615 382 622L388 650H132L126 622C211 615 214 609 198 524L121 122C106 42 102 35 23 28L17 0H276L282 28C196 35 191 40 206 122L243 324H597L559 123C544 42 537 35 452 28L446 0H710L716 28C632 35 628 43 643 122L719 524C735 610 741 615 822 622L828 650Z" id="g113-73"></path></g><g transform="matrix(.0091,0,0,-0.0091,28.166,-5.741)"><path d="M245 635C92 635 37 457 37 312C37 149 91 -12 244 -12C395 -12 449 166 449 312C449 469 395 635 245 635ZM243 598C332 598 358 454 358 312C358 173 334 26 245 26C158 26 128 174 128 313S152 598 243 598Z" id="g50-49"></path></g></svg></span></td><td class="align_center"><span style="width: 40.0425ptpx;"><svg height="17.1204pt" id="M163" style="vertical-align:-5.528999pt" version="1.1" viewbox="-0.0498162 -11.5914 40.0425 17.1204" width="40.0425pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M535 230V280H52V230H535Z" id="g117-33"></path></g><g transform="matrix(.013,0,0,-0.013,7.631,0)"><path d="M600 0V24L339 665L311 657L43 24V0H600ZM497 50H107L303 539L497 50Z" id="g113-133"></path></g><g transform="matrix(.0091,0,0,-0.0091,17.589,3.132)"><path d="M620 667C620 684 593 710 552 710C515 710 459 687 409 634C360 582 334 506 320 433H247L215 400L220 388H310L259 80C224 -129 199 -161 185 -174C175 -183 160 -192 141 -192C123 -192 90 -181 75 -165C69 -158 64 -156 54 -164C39 -178 24 -195 24 -208C24 -231 61 -257 94 -257C124 -257 162 -243 209 -194C267 -134 303 -66 343 107C369 220 378 279 393 385L503 397L523 433H404C432 619 464 660 500 660C522 660 542 646 566 621C573 614 583 615 593 621C603 628 620 648 620 667Z" id="g50-103"></path></g><g transform="matrix(.013,0,0,-0.013,23.97,0)"><path d="M828 650H570L564 622C646 614 650 609 634 524L604 366H253L281 524C296 608 308 615 382 622L388 650H132L126 622C211 615 214 609 198 524L121 122C106 42 102 35 23 28L17 0H276L282 28C196 35 191 40 206 122L243 324H597L559 123C544 42 537 35 452 28L446 0H710L716 28C632 35 628 43 643 122L719 524C735 610 741 615 822 622L828 650Z" id="g113-73"></path></g><g transform="matrix(.0091,0,0,-0.0091,34.893,-5.741)"><path d="M245 635C92 635 37 457 37 312C37 149 91 -12 244 -12C395 -12 449 166 449 312C449 469 395 635 245 635ZM243 598C332 598 358 454 358 312C358 173 334 26 245 26C158 26 128 174 128 313S152 598 243 598Z" id="g50-49"></path></g></svg></span></td><td class="align_center"><svg height="17.1204pt" id="M164" style="vertical-align:-5.528999pt" version="1.1" viewbox="-0.0498162 -11.5914 40.0425 17.1204" width="40.0425pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M535 230V280H52V230H535Z" id="g117-33"></path></g><g transform="matrix(.013,0,0,-0.013,7.631,0)"><path d="M600 0V24L339 665L311 657L43 24V0H600ZM497 50H107L303 539L497 50Z" id="g113-133"></path></g><g transform="matrix(.0091,0,0,-0.0091,17.589,3.132)"><path d="M620 667C620 684 593 710 552 710C515 710 459 687 409 634C360 582 334 506 320 433H247L215 400L220 388H310L259 80C224 -129 199 -161 185 -174C175 -183 160 -192 141 -192C123 -192 90 -181 75 -165C69 -158 64 -156 54 -164C39 -178 24 -195 24 -208C24 -231 61 -257 94 -257C124 -257 162 -243 209 -194C267 -134 303 -66 343 107C369 220 378 279 393 385L503 397L523 433H404C432 619 464 660 500 660C522 660 542 646 566 621C573 614 583 615 593 621C603 628 620 648 620 667Z" id="g50-103"></path></g><g transform="matrix(.013,0,0,-0.013,23.97,0)"><path d="M828 650H570L564 622C646 614 650 609 634 524L604 366H253L281 524C296 608 308 615 382 622L388 650H132L126 622C211 615 214 609 198 524L121 122C106 42 102 35 23 28L17 0H276L282 28C196 35 191 40 206 122L243 324H597L559 123C544 42 537 35 452 28L446 0H710L716 28C632 35 628 43 643 122L719 524C735 610 741 615 822 622L828 650Z" id="g113-73"></path></g><g transform="matrix(.0091,0,0,-0.0091,34.893,-5.741)"><path d="M245 635C92 635 37 457 37 312C37 149 91 -12 244 -12C395 -12 449 166 449 312C449 469 395 635 245 635ZM243 598C332 598 358 454 358 312C358 173 334 26 245 26C158 26 128 174 128 313S152 598 243 598Z" id="g50-49"></path></g></svg> (b.c) </td></tr><tr class="thead"><td class="align_center" colspan="6">kJ⋅mol<sup>−1</sup></td></tr><tr><td class="thead-hr" colspan="7"><hr/></td></tr><tr><td class="align_left">Tl<sub>5</sub>Se<sub>2</sub>Cl</td><td class="align_center">1564</td><td class="align_center">392,8</td><td class="align_center">17,0</td><td class="align_center">1858</td><td class="align_center">421,6</td><td class="align_center">28,1</td></tr><tr><td class="align_left">Tl<sub>5</sub>Se<sub>2</sub>Br</td><td class="align_center">1531</td><td class="align_center">374,3</td><td class="align_center">16,1</td><td class="align_center">1816</td><td class="align_center">384,3</td><td class="align_center">26,4</td></tr><tr><td class="align_left">Tl<sub>5</sub>Se<sub>2</sub>I</td><td class="align_center">1488</td><td class="align_center">334,0</td><td class="align_center">17,9</td><td class="align_center">1775</td><td class="align_center">324,0</td><td class="align_center">15,1</td></tr><tr><td class="align_left">Tl<sub>5</sub>Te<sub>2</sub>Cl</td><td class="align_center">1480</td><td class="align_center">355,9</td><td class="align_center">12,5</td><td class="align_center">1766</td><td class="align_center">377,1</td><td class="align_center">7,8</td></tr><tr><td class="align_left">Tl<sub>5</sub>Te<sub>2</sub>Br</td><td class="align_center">1442</td><td class="align_center">340,1</td><td class="align_center">14,3</td><td class="align_center">1728</td><td class="align_center">343,9</td><td class="align_center">10,2</td></tr><tr><td class="align_left">Tl<sub>5</sub>Te<sub>2</sub>I</td><td class="align_center">1389</td><td class="align_center">296,5</td><td class="align_center">12,8</td><td class="align_center">1669</td><td class="align_center">286,8</td><td class="align_center">12,1</td></tr><tr><td class="align_left">Tl<sub>6</sub>SCl<sub>4</sub></td><td class="align_center">2142</td><td class="align_center">833,5</td><td class="align_center">2,8</td><td class="align_center">2534</td><td class="align_center">928,1</td><td class="align_center">3,6</td></tr><tr><td class="align_left">Tl<sub>6</sub>SBr<sub>4</sub></td><td class="align_center">1987</td><td class="align_center">787,2</td><td class="align_center">6,6</td><td class="align_center">2377</td><td class="align_center">791,3</td><td class="align_center">8,2</td></tr><tr><td class="align_left">Tl<sub>6</sub>SI<sub>4</sub></td><td class="align_center">1784</td><td class="align_center">601,7</td><td class="align_center">9,7</td><td class="align_center">2172</td><td class="align_center">595,1</td><td class="align_center">9,0</td></tr><tr><td class="align_left">Tl<sub>6</sub>SeI<sub>4</sub></td><td class="align_center">1754</td><td class="align_center">613,1</td><td class="align_center">16,6</td><td class="align_center">2145</td><td class="align_center">609,7</td><td class="align_center">22,3</td></tr><tr class="table-tr"><td colspan="7"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

Comparison of thermodynamic functions of atomization, formation from elemental components, and formation from binary compounds of thallium chalcogen-halides.

Advances in Materials Science and Engineering

tab5

Table 5

Table 5: Thermodynamic Study of Tl<sub>6</sub>SBr<sub>4</sub> Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides 

Advances in Materials Science and Engineering

Thermodynamic Study of Tl6SBr4 Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides

Table 5

Thermodynamic Study of Tl₆SBr₄ Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides