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Advances in Materials Science and Engineering
Volume 2018 (2018), Article ID 2940601, 5 pages
Research Article

Mesoporous Silica Loaded with Molybdenum Phosphide Nanoparticles for Hydrogen Evolution

Guangdong Polytechnic of Environmental Protection Engineering, Foshan 528216, China

Correspondence should be addressed to Keliang Wang; moc.361@21kwgnail

Received 4 July 2017; Accepted 19 October 2017; Published 21 January 2018

Academic Editor: Wei Zhou

Copyright © 2018 Keliang Wang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


A mesoporous silica loaded with molybdenum phosphide nanoparticles (MoP@MSN) was synthesized using Pluronic F-127 as a hard template. Using the method of XRD and HRTEM, the crystallinity, the phase structure, and the morphologies of the MoP@MSN were investigated. The results showed that the MoP@MSN were composed of nanoflakes with approximately 100 nm. Through the linear sweep voltammetry (LSV), the Tafel slopes of 100 and 341 mV were yielded for MoP@MSN and pure MoP, respectively, meaning that the composite of MSN can significantly improve the conductivity of the products. Meanwhile, the mesoporous MoP@MSN presented excellent electrochemical activity and stability toward hydrogen evolution compared with those of bulk MoP nanoparticles, showing a promising prospect in hydrogen production.