Review Article

Recent Progress on the Implementation of Renewable Biodiesel Fuel for Automotive and Power Plants: Raw Materials Perspective

Table 4

Different types of transesterification method [88].

No.Transesterification methodCharacteristics

1Homogeneous acid-catalyzed transesterification(i) Relatively insensitive to the FFA content of the raw material relatively more minor energy-intensive
(ii) Requires higher operating temperatures and
(iii) The resulting biodiesel usually has a higher amount of free glycerol (lower percentage of purity)
2Homogeneous base-catalyzed transesterification(i) Very sensitive to FFA and moisture content
(ii) Very selective in the type of raw material
(iii) The reaction is fast
(iv) The catalyst is relatively inexpensive
(v) Usually applied on an industrial scale for biodiesel production
3Heterogeneous acid-catalyzed transesterification(i) Avoids product separation problems and purification
(ii) Allows the reuse of the catalyst
(iii) Requires relatively high alcohol for oil molar ratio and a long reaction time
4Heterogeneous base-catalyzed transesterification(i) Reduces process steps and minimizes the waste that harms the environment
(ii) Easy separation and reuse of catalyst
(iii) The catalyst may be poisoned upon exposure to ambient air (not environmentally friendly)
5Lipase-catalyzed transesterification(i) Insensitive to FFA and moisture content
(ii) Carried out at low temperature and converting more amount of feedstock into biodiesel
(iii) It is expensive because enzymes are expensive and take longer to get good results
6Nanocatalyzed transesterification(i) Not sensitive to FFA
(ii) Moisture content was carried out relatively at low temperatures and took a short time
(iii) Catalysts can be reused many times at a cost
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(vi) It requires more alcohol for effective results
(vii) In some cases, preparation of the suitable catalyst is expensive
7Ionic liquids-catalyzed transesterification(i) Allows easy separation of the final product because the biphasic formation
(ii) Reduces process costs and being efficient and timesaving
(iii) Allows modulation of the desired properties of the catalysts when preparing them
(iv) The catalyst has high catalytic activity and excellent stability and can be easily separated and reused many times
(v) It requires relatively more alcohol for effective results and is usually expensive to own ionic liquid
8Supercritical transesterification(i) Not sensitive to FFA and moisture content of raw materials
(ii) Allows to use a broader range of raw materials
(iii) Usually takes less time and produces a more significant amount of fuel per mass of feedstock
(iv) It requires higher temperature and pressure and consumes more methanol
(v) It is not economically profitable because of its high operating costs