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Aunnuda Lanna, Montri Suklueng, Chainuson Kasagepongsan, Sunisa Suchat, "Performance of Novel Engineered Materials from Epoxy Resin with Modified Epoxidized Natural Rubber and Nanocellulose or Nanosilica", Advances in Polymer Technology, vol. 2020, Article ID 2123836, 11 pages, 2020. https://doi.org/10.1155/2020/2123836
Performance of Novel Engineered Materials from Epoxy Resin with Modified Epoxidized Natural Rubber and Nanocellulose or Nanosilica
Performance of new engineered material from epoxy resins with modified epoxidized natural rubber (ENR) and nanofillers were investigated. ENR from renewable natural crop resources is a type of green material with potential to partially substitute or replace and toughen petrochemical-based polymers. Nanocomposites (epoxy resin/ENR/fillers nanoparticles) were characterized with Fourier transform infrared spectroscopy (FTIR), dynamic light scattering (DLS), atomic force microscope (AFM), and scanning electron microscopy (SEM). Comparison of characterized and mechanical properties of nanofiller reinforced with both nanocellulose and nanosilica were studied. The nanocomposites were characterized for their mechanical properties (e.g., impact strength, tensile strength) and thermal degradation behaviour by thermal gravimetric analysis (TGA). Mechanical property investigation results show that, the impact strength of nanocomposites, can be improved by blending in ENR 50 mixed with nanofiller, relative to the baseline nanocomposite mixers. The nanofiller loading in epoxy composite showed the highest improvement in mechanical properties at 0.75 phr (parts per hundred of resin). Effects of accelerated weathering aging were evaluated, and the observed changes were larger with nanosilica than with nanocellulose filler. Here, the accelerated aging increase in tensile properties was found to be 10% after 14 days in both nanofillers, while the other mechanical properties did not change significantly. These nanocomposites are expected to have high wear rates limiting their service life.
Nowadays, quality assurance, health protection, and environmental preservation have become interdependent and interrelated aspects and are considered to be the primary factors that respond to the concept of sustainable development. The methods used to manufacture propeller blades need to be green and environmentally friendly . An epoxy composite has a major focus for Unmanned Aerial Vehicle (UAV) blades manufacturers. In this perspective, the outcomes presented in this paper can be exploited in modern blade with the aim to develop reliable, efficient and cost-effective blades that can withstand, without adverse effects, severe static and/or dynamic loadings, to which they may be exposed during their lifetime. To enable sustainable production of nanocomposite blades coupled with green manufacturing practices, designers, and users should innovate on how to integrate health and environmental aspects into the bonding procedures. The present investigation to develop a new approach providing high performance adhesively-bonded composite blade half-shells in terms of Quality-Health-Environment related issues. Alternative solutions leading to a new generation of environmentally-friendly products can be achieved through the integration of a new green material factor into the classical bonding formulations. The blades are mostly made of nanosilica, carbon fiber, and fiber glass because these are strong but lightweight [1, 2]. However, epoxy resins are the most important component in these composites, used as the adhesive matrix with the fibers for improved strength and smooth glossy surfaces. Improving the ductility of these blades for better impact resistance is desired. The materials conventionally used in the composite are epoxy resin, fiber, and hardener [1–3]. The main component is epoxy resin which is also used in a wide range of civil engineering applications. This is because epoxy resin has excellent bonding properties, and also after curing it has good mechanical properties (high modulus, low creep, and reasonable elevated temperature performance), but it easily fails under impact because of the highly crosslinked structure [4, 5]. Elastomers materials that have been added to epoxy resin to improve its toughness include hard particulate materials [6, 7]. In addition, modified epoxidized natural rubber (ENR) elastomers have been studied . ENR was synthesized from natural rubber (NR) , which is an important renewable resource. The challenges for commercialization of biobased engineered materials are assessed. Management concerns about material of renewable resources and climate change have resulted in attempts to find green alternatives for petroleum based materials and mitigate greenhouse gas emissions. ENR particles and other soft materials such as polysiloxane, have been studied to improve the fracture toughness of brittle epoxy resin [9, 10]. Among the numerous attempts to enhance the impact strength of epoxy resin, blending in natural rubber or epoxidized natural rubber (ENR) latex has also been tested [11, 12]. In that study, comparisons of degradation of the nanocomposites were carried out in one outdoor weathering test. Environmental aging is caused by humidity, wind, and ultraviolet radiation, causing irreversible changes in the molecular structure of materials and affecting their durability [13, 14]. The tensile properties of epoxy resin composites may improve in the initial consolidation stage during aging, which is attributed to postcuring reactions . A degradation stage follows the composite properties are significantly degraded. This is attributed to deterioration and weakening of the matrix interfaces . The purpose of this study was to improve the critical mechanical properties of epoxy resin composites by adding ENR elastomer with nanofiller. The two types of nanofiller (nanosilica or nanocellulose) were tested at various filler loading levels to improve the mechanical properties for use in blades (wind turbine and UAV blade applications). Nanocomposites approaches to overcome epoxy brittleness and deal with ongoing research strategies to make tough biobased materials. The key toughening modifiers such as rubber, nanofillers are discussed. The challenges for commercialization of biobased modifiers are assessed of research and development of the tough engineered materials are explored.
2. Materials and Methods
2.1.1. Modified Epoxidized Natural Rubber (ENR)
The ENR was synthesized from natural rubber (NR) latex, obtained from Muang Mai Guthrie Co., Ltd. Thailand. NR contained spherical particles with an average diameter around 1 µm, and its solid content was about 60 wt%. The density of NR was 0.92 gcm−3 and it contained more than 98% cis-1,4 polyisoprene. The ENR 50 was prepared via in situ epoxidation to 50 mol% epoxide content with performic acid epoxidation of natural rubber latex using 0.5 M hydrogen peroxide, polyalcohol ethylene oxide condensate (Terric 16A-16) (3 wt%) and 0.75 M reagent grade formic acid. The reaction was allowed to proceed at 50°C for 8 h .
2.1.2. Epoxy Resin (EP)
The epoxy resin was used as bisphenol-A type epoxy resin, the chemical structure show in Figure 1(a) bisphenol-A diglycidyl ether (Epotec YD 535 LV: Epicholrohydrin-bisphenol A), average molecular weight less than 700 g/mol. The specific gravity of EP was 1.10, and viscosity 1,200 cps, and purchased from Aditya Birla Chemical Industry Co., Ltd., Thailand.
2.1.3. Curing Agent
A polyamine (TH 7255) was curing agent, the chemical structure show in Figure 1(b), the reacts with bisphenol-A type epoxy resin to cure at room temperature with heat generation. The specific gravity of TH 7255 was 1.04, and viscosity 100 cps. The TH 7255 curing agent was supplied by Aditya Birla Chemical Industry Co., Ltd., Thailand.
The fillers nanoscale obtaining nanocomposites were separate into two types, one based on nanocellulose compare with nanosilica, and more detail as;
Nanocellulose. The white nanocellulose powder was a commercial product prepared from wood pulp. Weight average molecular weight of the nanocellulose was 14,700–27,850 g/mol, with specific surface area of 400 m2/g. The nanocellulose was provided by CelluForce, Canada.
Nanosilica. The nanosilica colloidal from white nanosilica powder was surface-modified with methyl triethoxy silane . Weight average molecular weight of the nanosilica was 60 g/mol, with specific surface area of 135 m2/g. The 40 wt% nanosilica colloidal was kindly suspension in H2O, provided by Bossofticl Co., Ltd., Thailand.
2.2. Nanocomposite Samples Preparation
The nanocomposites were prepared as follows.
First, the epoxy resin 100 phr (phr: parts per hundred parts of epoxy resin) was blended with 5 phr of 50 mol% epoxide content of epoxidized natural rubber (ENR 50) and with desired nanofiller loading, stirring in the reactor (AM120Z-H Laboratory electric mixer/Stirring machine) for 15 min at 50 rpm, and at room temperature (30°C). As the second step, the TH 7255 hardener or curing agent was stirred in at the same stirrer speed for 5 min. Finally, the nanocomposites specimens were formed into rubber molds at room temperature for 24 h, and the specimens formed with a computer molded numerical control (CNC) machine to samples prepared for mechanical properties tested.
2.3. Characterization and Analysis
The characterization of nanocomposites samples from epoxy resin blended with ENR 50 and nanofiller were done as follows.
2.3.1. Fourier Transform Infrared Spectroscopy (FTIR)
Approximately 15 mg sample of the composite was subjected to Fourier transform infrared spectroscopy. To assess the functional groups in raw materials, each of samples were similarly studied by FTIR. The FTIR spectra were recorded using a Vertex 70, (Bruker, Karlsruhe, Germany), which was equipped with a germanium ATR crystal probe and allows direct recording of the spectra without sample preparation. The recorded spectra were averages of 32 scans over the wave number range 4000–400 cm−1 at 4 cm−1 resolution. A background scan of the clean crystal was recorded before scanning the samples.
2.3.2. Dynamic Light Scattering (DLS)
Dynamic light scattering is a technique measuring the intensity of light, also known as photon correlation spectroscopy (PCS), that can estimate particle sizes in nanometer range: within 0.005–5 micrometers. The measurements were done at room temperature in suspension mode using Annalys 22 Nanotech, Germany.
2.3.3. Atomic Force Microscope (AFM)
An atomic force microscope was used to characterize the particle sizes of nanofillers. AFM images were captured at room temperature in semicontact mode using Nanosurf Easyscan 2 AFM (Nanosurf AG, Liestal, Switzerland).
2.4. Mechanical Properties
Key mechanical properties of the nanocomposites (epoxy resin blend with ENR 50 and nanofiller) for propeller blade applications were determined. The tensile strength according to ASTM D638, the impact strength was measured according to ASTM D256, and the hardness (Shore D) according to ASTM D2240.
2.4.1. Tensile Strength
The tensile strength of nanocomposites (epoxy resin with ENR 50 and nanofiller) were measured by Universal Testing Machine, Zwick Roll, Germany (Z010) according to ASTM D638. The testing machine was equipped with a 10 kN load cell, and the extension speed used was 50 mm/min. The specimen’s type I were prepared to 50 mm and 3 mm working and gauge lengths. The tensile strength is the maximal force per unit area acting on a plane transverse to the applied load, and is a fundamental measure of the internal cohesive forces within a sample.
2.4.2. Impact Strength
The Izod impact strengths of cured un-notched samples of nanocomposites (epoxy resin with ENR 50 and nanofiller) were measured. The energy absorbed in breaking the specimen can be expressed in SI units and was determined by the impact tester machine (Dynisco Polymer Test 50J, Japan). The Izod pendulum impact test records the energy to break standard test composite specimens of specified size under conditions stipulated by ASTM D256. The specimen dimensions were 63.5 mm × 12.7 mm × 3.0 mm [1, 3]. The sample is held in a cantilevered beam configuration (opposed to a three-point bending configuration).
The hardness of nanocomposite was measured with digital hardness durometer Shore D meter. Specimens were at least 6.0 mm (0.25 inches) thick, and one specimen of each type was measured three times replicates. The measuring the initial hardness, or the indentation hardness after a given period of time. The test requires applying mechanical force in a consistent manner.
2.5. Morphological Typology
Scanning electron microscope (SEM) is one of the common methods for imaging the morphology of the materials. SEM imaging was done in the vicinity of a razor notch, to reflect uniform failure mode. And also, SEM was to assess the phase compatibility in the nanocomposite. In SEM, an electron beam with low energy is radiated to the material and scans the surface of the sample. The SEM specimens were sputter coated (5–8 kV in a vacuum) with thin gold/palladium layer and were imaged with Cambridge Stereoscan 200 (FEI-Quanta 400, Jeol Ltd., Tokyo, Japan).
2.6. Thermal Properties
2.6.1. Thermogravimetric Analysis (TGA)
Thermal properties were assessed with TGA (STA 6000, Perkin Elmer Inc., Connecticut, USA) over the temperature range from 30°C to 600°C with N2 and 600°C to 900°C with O2 flushing, with a heating rate of 10°C min−1 and flow rate of 100 ml/min, using about 10 mg samples.
2.6.2. Accelerated Aging
The weathering with UVA exposure was performed following ASTM G154 cycle I, using a QUV-accelerated weathering tester (QUV test LU-0819, Q-panel lab products, USA). The conditions of QUV-accelerated weathering test include UVA radiation at 340 nm and 0.77 W/m2 intensity, at 60°C for 8 h, water-condensation at 50°C for 4 h, and water sprayed on the specimen for 15 min. The aging cycles were repeated for up to 168 h and 336 h.
2.7. Statistical Analyses
The XLSTAT software of ANOVA was used to measure significance of factors on the mechanical properties.
3. Results and Discussion
3.1. Characterization of Materials
The first step in assessing of nanocomposites materials is to chemically identify and characterize materials.
3.1.1. Particle Size of Nanofiller
The particle size distributions are shown in Figure 2(a) (for nanocellulose), and Figure 2(b) (for nanosilica). Dynamic light scattering provides quick, precise and repeatable nanoparticle size data and it is an essential tool for the nanoparticle technologist. The z-average diameters obtained with the SZ-100 are listed. The size distribution of nanocellulose is bimodal with two peaks (Figure 2(a)). There is nanocellulose diameter of particles at which exactly 90% of particle volume is larger than 20.3 nm, and 10% of particles smaller than about 1.4 nm. Figure 2(b) show that the particle size distribution of nanosilica is unimodal with nominal particle size around 20 nm and average diameter around 50 nm.
The particle size of nanofiller can be confirmed by an atomic force microscope (AFM) in Figures 2(a)(1)–2(a)(3) for nanocellulose, and Figures 2(b)(1)–2(b)(3) for nanosilica show topographies with nanofiller in 2-D and 3-D images, and these clearly allow distinguishing nanoparticles.
The average particle sizes were estimated as 20.34 nm for nanocellulose and 52.8 nm for nanosilica, by image analysis.
3.1.2. Fourier Transform Infrared Spectroscopy (FTIR) Analysis
The FTIR spectra in the range 4000–400 cm−1 are summarized in Table 1 and shown in Figure 3. The first line (Epoxy resin line) at 915 cm−1 is attributed to C–O deformations in the oxirane group [8, 18]. The peak at approximately 3050 cm−1 is attributed to C–H stretching in the methylene group of epoxy ring. This peak is polymerization degree epoxy monomers it can be used as a qualitative indicator of the presence of epoxy groups. The FTIR spectrum of NR (NR lines) shows strong peaks of unsaturated C = C stretching at 1660 cm−1. Peaks at 2935 cm−1, 2864 cm−1, and 2840 cm−1 attributed to C–H stretching and the peak at 837 cm−1 indicating C–H bending attached to unsaturated carbon [19, 20]. For the ENR 50 line appeared peaks at 870 cm−1 indicate the epoxy ring and C–H bending attached to the oxyrane ring, the intensities at 838 cm−1 which are observed in ENR 50 reduced after epoxidation increased, which might be due to the epoxy ring has also occurred at the C = C double bond . The absorption band approximately 1730 cm−1 in the nanocellulose spectrum (Nanocellulose line) is due to -C = O stretching in carboxylic acid or ester groups, seen in Figure 3. The peak at 897 cm−1 was assigned to C–O–C glycosidic linkages between glucose units in cellulose, while absorption at 3440 cm−1 was assigned to H–O–H stretching. At 1506 cm−1 the absorption band is due to stretching of special types of unsaturation in the benzene ring. The absorption at 1246 cm−1 is related to (C–O) stretching. The FTIR results confirm the three main characteristic peaks of nanosilica (Nanosilica lines) from Si–O–Si asymmetric bond (Si–O) at 1093 cm−1, Si–O–Si asymmetric bond (Si–OH) at 788 cm−1 and Si–O–Si bond bending vibrations (Si–O–Si, siloxane) at 466 cm−1; these are attributed to asymmetric and symmetric stretching, and bending modes of silica, respectively. The absorption bands at 3440 cm−1 and 1645 cm−1 were assigned to H–O–H stretching and bending modes of adsorbed water, respectively, related to the silanol-OH groups and water bound to silica surfaces . These spectra for the composites (EP + ENR 50, EP + ENR 50 + CNC, and EP + ENR 50 + Nanosilica) had absorption at 915 cm−1, which is attributed to C–O deformations in oxirane group, and at 3050 cm−1 that is attributed to C–H stretching in methylene group of the epoxide rings.
FTIR has been used to identify the level of 50 mol% epoxidation in ENR [1, 8]. The ENR 50 usually has high elasticity, and resilience strain crystallization, but low oil resistance in the latex stage. Accordingly, this ENR was labelled ENR 50 as in prior work.
3.2. Morphology of Nanocomposite
3.2.1. Morphology of the Epoxy without and with ENR 50
Morphology was assessed from SEM micrographs of notched Izod impact fracture surfaces (Figure 4(a)) for the neat epoxy resin matrix and the related composites. The structural investigation of the fracture surfaces were showed the formation of new phases on the surfaces of ENR 50 particles (Figure 4(b)).
The globular rubber nodules were improved impact strength and tensile strength. The epoxy resin and ENR 50 composite had better interactions at phase boundaries in the case of ENR 50, which gave higher impact strength than the neat epoxy resin matrix.
The rubber is present as the component, large globular domains dispersed in the thermoplastic are observed. The loading with 5 phr of ENR 50 is an appropriate choice to improve impact strength. Amorphous ENR 50 was chosen for the model matrix to investigate the effects of the nanoparticles on mechanical properties of nanocomposites.
3.2.2. Morphology of Nanocomposites
Morphology of nanocomposites with epoxy resin, ENR 50 and nanofiller are shown in Figures 4(c) and 4(d), in SEM micrographs of notched Izod impact fracture surfaces. The micrograph of epoxy nanocomposite has smooth and glossy exterior with numerous wavy or stream-like cracks, shown by arrows. There is a gradual increase in the yield strength of the rubber and nanofiller filled nanocomposite. Figure 4(c)(1–4) shows the nanocomposites blends of epoxy resin (EP)/ENR 50/nanocellulose (CNC) with superior interactions at phase boundaries in the case of CNC at 0.75 phr, which gave the highest impact strength. The blend EP/ENR 50/nanosilica in Figure 4(d)(1–4) had improved interactions at the phase boundaries of nanosilica, so the mechanical properties improved with nanofiller loading. The trends with nanosilica were similar to those with nanocellulose. The well dispersed nanocellulose and nanosilica in epoxy composite improved the mechanical properties. Increasing the nanofiller loading level continuously improved strength and fracture toughness. Overall, nanofillers are a promising approach to modify the properties of aerospace epoxy resin nanocomposites. It can be concluded that 0.75 phr nanocellulose in the mixture was the best choice, with good compatibility and high strength without significant negative effects. It should be noted that adding more than 0.75 phr can worsen the mechanical properties.
3.3. The Mechanical Properties of Nanocomposites
To evaluate the mechanical properties of epoxy resin nanocomposites containing ENR 50 (ENR 50 at 5 phr loading improved the impact strength), and nanofiller. The nanofiller loading was varied up to 1 phr relative to the neat epoxy resin matrix, and results for the nanocomposites are collected in Table 2, showing that the nanofiller loading level affected the mechanical properties. In this investigation, we studied the effects of filler types and amounts for nanocellulose and nanosilica in composites. The impact strengths of the nanocomposites with 0.25, 0.5, 0.75, and 1 phr nanofiller loading levels were determined. The impact strength with 0.75 phr was higher than with 0.25, 0.5, and 1 phr. This is due to the small particle size of nanocellulose along with its good compatibility and dispersion in the epoxy matrix. The uniform dispersion and high aspect ratio of the nanocellulose contributed to good results with it, according to prior research [22, 23]. The nanofillers were compatible with epoxy resin due to similar polarization levels, which improved stiffness of the nanocomposites.
a, b, c, dDifferent superscripts indicate statistically significant differences at 95% confidence by Duncan’s method. Mean ± SD: mean and standard deviation based on triplicate samples.
Comparison of the types of nanofiller (nanocellulose and nanosilica) was done for finding the best mechanical properties of nanocomposites. Table 2 summarizes the mechanical properties, such as impact strength, tensile strength, and hardness that improved with nanofiller loading. Regarding tensile strength, nanocellulose increased it more than nanosilica, because the C-C bonds with nanocellulose inhibit crystallization of rubber more than nanosilica. Also the impact strength with nanocellulose was higher than with nanosilica, possibly because the fibers improved resistance against crack propagation. There were no significant changes in the toughness, although it appeared higher for epoxy resin blends with nanosilica than with nanocellulose. The SiO2 bonded stronger than C-C bonds, formerly hardness of nanosilica increased it more than nanocellulose. It was also found that regardless of the mixing approach, the strength of a nanocomposite having nanosilica or nanocellulose was higher than that of neat epoxy resin composite. Comparing the mechanical properties such as impact strength and tensile strength between filler loadings, it seems that the composite with 0.75 phr nanocellulose would be the best choice with highest strength. However, nanocellulose as reinforcing filler gave even better mechanical properties than nanosilica. And the mechanical properties of nanocomposites were further improved by post cure during accelerated aging.
3.4. Thermal Properties of Nanocomposites
3.4.1. Thermogravimetric Analysis (TGA)
It was used to study the thermal stability of the epoxy nanocomposites, Figures 5(a) and 5(b). The TGA thermograms show that the thermal stability of epoxy matrix steadily increased significantly with nanofiller loadings among 0.25, 0.5, 0.75, and 1 phr. It is noted that, the TGA was performed under nitrogen atmosphere in the temperature range from 30 to 600°C, and under oxygen atmosphere in the temperature range from 600 to 900°C. Figure 5, two decomposition steps are clearly observed. The first step is for degradation under nitrogen atmosphere, and the second step is for decomposition under oxygen atmosphere. It is observed that while the thermal stability of nanocellulose (CNC)-nanocomposite in Figure 5(a) significantly improved, the maximum degradation temperature (Td) was around 370°C for all cases. However, the case with 0.75 phr CNC had the best thermal stability. Figure 5(b), it is observed that the thermal stability of nanosilica- nanocomposite significantly increased with nanosilica loading, but the maximum degradation temperature was 380°C for all cases. At the final 600°C temperature, the fillers (nanocellulose and nanosilica) in the composites might be partly decomposed in the second step and some residue still remained, and its amount tended to increase with filler. However, the overall stability of the nanocomposites depends greatly on the nature of crosslinks and nanofillers will have profound effects on the mechanical properties. In this study, the degree of crosslinking in the epoxy system was not evaluated, and it will be subjected to further investigation in the future.
3.4.2. The Accelerated Aging
The mechanical properties before and after accelerated aging of the optimal nanocomposites (100 phr epoxy resin, 5 phr ENR 50 and 0.75 phr nanofiller) are shown in Figure 6. The results show that the accelerated aging (UV-A for 68, 168, and 336 h) reduced the impact strength in Figure 6(a), according to the Izod impact test. However, after accelerated aging the samples had increased hardness, and the surfaces of samples exhibited a distinct change in colour from colourless to dark yellow. Conversely, nanocellulose gave a higher impact strength than nanosilica. In Figure 6(b), show the accelerated aging improved tensile strength according previous researches , while the other mechanical properties did not change significantly. Effects of accelerated aging with UV-A were evaluated, and the observed changes were larger with nanosilica than with nanocellulose nanofiller. The nanocomposites had good strength properties after accelerated aging, and the best case was UV-A treatment for 168 h. This is due to the small particle sizes of nanofiller and of ENR 50 that both had good compatibility and dispersion in the epoxy nanocomposites. When we compare between the types of nanofiller, nanocellulose gave higher tensile strength property than nanosilica. The high aspect ratio of nanocellulose fibers may help prevent crack propagation. Nanocomposites approach to engineered biobased epoxy resins with ENR and nanofillers fits the search for nonpetroleum-based structural materials, like bio-nanocomposites that are biodegradable, high performance and lightweight.
In this study, epoxidized natural rubber to 50 mol percent level at 5 phr loading improved the impact strength of epoxy nanocomposite. Comparison of two types of nanofiller were applied and their effects on the mechanical properties before and after accelerated aging were assessed. Also morphology and thermal properties of the nanocomposites were examined. The optimum loading of nanosilica or nanocellulose for best overall performance was 0.75 phr. However, nanocellulose as reinforcing filler gave even better mechanical properties than nanosilica. Thermal stability improved with nanofiller loading. The nanocomposites had good strength properties also after accelerated aging. ENR 50 level at 5 phr and nanocellulose at 0.75 phr is a good choice of blend proportions to improve the impact resistance of epoxy resin nanocomposite, for use in blades propeller. Performance of new renewable materials from nanocomposites and agro-industrial is approaches to engineer tough biobased epoxy resin.
The data used to support the findings of this study are available from the corresponding author upon request.
Conflicts of Interest
The authors declare that they have no conflicts of interest.
This work was supported by the government budget of Prince of Songkla University with The Natural Rubber Innovation Research Institute of Prince of Songkla University with the funding number “SIT601019S” for financial support, the authors gratefully acknowledge the Research and Researcher for Industry Program with the funding number “MSD60I0087”, Prince of Songkla University for financial support and the experiment station.
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