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International Journal of Photoenergy
Volume 2008 (2008), Article ID 504945, 6 pages
http://dx.doi.org/10.1155/2008/504945
Research Article

A Rapid Method of Assessing the Photocatalytic Activity of Thin Films Using an Ink Based on the Redox Dye 2,6-Dichloroindophenol

WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow G1 1XL, Scotland

Received 24 July 2007; Accepted 1 November 2007

Academic Editor: Russell Howe

Copyright © 2008 Andrew Mills et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

An indicator ink based on the redox dye 2,6-dichloroindophenol (DCIP) is described, which allows the rapid assessment of the activity of thin, commercial photocatalytic films, such as Activ. The ink works via a photoreductive mechanism, DCIP being reduced to dihydro-DCIP within ca. 7.5 minutes exposure to UVA irradiation of moderate intensity (ca. 4.8 mW ). The kinetics of photoreduction are found to be independent of the level of dye present in the ink formulation, but are highly sensitive to the level of glycerol. This latter observation may be associated with a solvatochromic effect, whereby the microenvironment in which the dye finds itself and, as a consequence, its reactivity is altered significantly by small changes in the glycerol content. The kinetics of photoreduction also appear linearly dependent on the UVA light intensity with an observed quantum efficiency of ca. .