Nanotechnology for Electrooptical and Photovoltaic DevicesView this Special Issue
Research Article | Open Access
Kuo-Chin Hsu, Yaw-Shyan Fu, Pei-Ying Lin, I-Tseng Tang, Jiunn-Der Liao, "Fabrication and Characterization of CuInSe2 Thin Film Applicable for a Solar Energy Light Absorption Material via a Low Temperature Solid State Reaction", International Journal of Photoenergy, vol. 2013, Article ID 156964, 7 pages, 2013. https://doi.org/10.1155/2013/156964
Fabrication and Characterization of CuInSe2 Thin Film Applicable for a Solar Energy Light Absorption Material via a Low Temperature Solid State Reaction
The chalcopyrite CuInSe2 thin film synthesized via a low temperature solid state reaction from CuSe and InSe powders was investigated using X-ray diffractomy (XRD), scanning electron microscope (SEM), energy dispersive spectrometer (EDS), transmission electron microscopy (TEM), and UV-vis absorption spectroscopy. CuSe and InSe phases react and directly transform into CuInSe2 without the occurrence of any intermediate phase. The morphology of the newly formed CuInSe2 crystalline was close to that of the CuSe reactant particle based on the TEM results, which indicate that the solid state reaction kinetics may be dominated by the In3+ ions diffusion. The CuInSe2 thin film prepared from the solid state reaction did not use the selenide process; its band gap might reach 1.06 eV, which is competent and suitable to be used for a thin film solar cell light absorption layer.
For the new type-energy materials, the group IV quantum dot nanostructures for future generation solar cell applications  and next generation ionic conducting membranes for photochemical materials (i.e., fuels from light), batteries (i.e., electricity storage), fuel cells (i.e., electricity from fuels), and other applications  are highly promising. Successful results have been increasingly converted into products, and more and more organizations have developed novel advanced materials for renewable energy for the future. Many efforts have also been focused on photovoltaic cells. Among them, the ternary I-III-VI2 semiconductor of CuInSe2 (CIS) is one of the most important semiconductor materials used in thin film photovoltaic cells. Because of its high absorption coefficient, suitable band gap, good radiation stability, and the thickness of the absorption layers can be reduced to several micrometers .
High efficiency CIS solar cells are commonly prepared via the physical vapor deposition method [4–6]. This kind of process requires a complicated facility, thereby leading to the high fabrication cost. However, the general vacuum methods have drawbacks such as the complexity in process and high production costs and are difficult to be made on a large scale, which need to be solved before the mass production of CIS solar cells. To avoid these drawbacks, nonvacuum processes have been extensively investigated in recent years, such as ink printing method , electrodeposition process [8, 9], spray pyrolysis method , chemical deposited method , and combustion method and nonvacuum spin-coating process .
A potential nonvacuum method for CIS formation is developed in this work. In the experiment, the CuSe and InSe powders are prepared by wet chemical method, which is one of the simplest and cheapest methods. The CIS thin film is thereafter obtained by spin coating from CuSe and InSe powders on the glass and then heated at 350°C for 3 h under nitrogen gas. The structure and the optical properties of the precursors and the CIS films are investigated and discussed.
The copper (I) chloride (99.99%, Alfa Aesar, Ward Hill, MA, USA) and indium (III) chloride (99.99%, Acros, Geel, Belgium) used were analytical grade reagents. Selenium powder (99.99%, Sigma-Aldrich, St. Louis, Missouri, USA) was a high purity reagent. Oleylamine (70%, Kanto Chemical Co., Inc., Tokyo, Japan), hexane (99%, Acros, Geel, Belgium), and ethanol (95%, Acros, Geel, Belgium) were used as received, without further purification. The deionized water (DI water) used in this work was obtained from EMD Millipore Corporation-Direct-Q 3 system (Billerica, MA, USA).
2.2. Synthesis of InSe Particles
A typical synthesis of InSe particles was modified from Park et al.’s procedure ; 0.45 mmol InCl3 and 0.50 mmol Se powder were added into 10 mL of oleylamine (OLA) at room temperature. The reaction mixture was heated to 220°C and kept at that temperature under nitrogen gas with magnet stirring for 5 h. The product was then centrifuged and washed with hexane, ethanol and DI water several times and then dried at 80°C for 3 h in a vacuum oven.
2.3. Synthesis of In2Se3 Particles
The In2Se3 particles were synthesized by annealing the reaction mixture containing 0.45 mmol InCl3 and 0.70 mmol Se powder in 10 mL of OLA at 280°C under nitrogen gas for 5 h. The product was then centrifuged and washed with hexane, ethanol, and DI water several times and then dried at 80°C for 3 h in a vacuum oven.
2.4. Synthesis of CuSe Particles
The CuSe particles were synthesized by annealing the reaction mixture containing 0.50 mmol Se powder and 10 mL of OLA (OLA/Se) firstly mixed at room temperature, and the resulting solution was heated to 180°C. 0.46 mmol CuCl and was then quickly added into the hot OLA/Se solution; the reaction mixture was annealed at 220°C for 2 h under nitrogen gas. The product was then centrifuged and washed with hexane, ethanol, and DI water several times and then dried at 80°C for 3 h in a vacuum oven.
2.5. Synthesis of Cu2Se Particles
The Cu2Se particles were synthesized by annealing the reaction mixture containing 0.91 mmol CuCl and 0.50 mmol Se powder in 10 mL of OLA at 220°C for 2 h under nitrogen gas. All the products were then centrifuged and washed with hexane, ethanol, and DI water several times and then dried at 80°C for 3 h in a vacuum oven.
2.6. Synthesis of CuInSe2 Films
The CuInSe2 films were prepared using the as-prepared metal Se compounds as precursors in two reaction paths. In the reaction path A, the as-prepared InSe (0.25 mmol) and CuSe (0.25 mmol) were dispersed in ethanol and spin-coated on the glass with 500 rev. min−1 for 20 s in air, then dried at 100°C for 1 h to remove residual solvent. The glass was transferred into closed graphite box and heated at 350°C for 3 h under nitrogen gas. In the reaction path B, the as-prepared In2Se3 (0.25 mmol) and Cu2Se (0.25 mmol) were also dispersed in ethanol and spin-coated on the glass with 500 rev. min−1 for 20 s in air, then dried at 100°C for 1 h to remove residual solvent. The glass was transferred into closed graphite box and heated at 350°C for 3 h under nitrogen gas. The experimental parameters were summarized in Table 1.
|Samples no. 1~4 were reaction via wet chemical process using OLA as solvent.|
bThe precursors were prepared by samples no. 1~4 and reaction through low temperature solid state reaction.
2.7. Material Characterization
The X-ray powder diffraction (XRD, operating at 8 kV) patterns of the as-prepared samples were recorded on Shimadzu XRD-6000 X-ray diffractometer (Kyoto, Japan) with Cu K radiation ( nm). The morphologies and micro-/nanostructure were investigated by Hitachi 4200A (Tokyo, Japan) scanning electron microscope (SEM, operating at 10 kV) and JEOL JEM-2000EX (Tokyo, Japan) transmission electron microscope (TEM, operating at 160 kV). The measurements using energy dispersive spectrometer (EDS) were performed on Horiba EX220 (Kyoto, Japan), which was attached to TEM for compositional analyses. Thermal analysis was carried out with Perkin Elmer Pyris Diamond TG/DTA thermal analyzer (Boston, MA, USA) in nitrogen atmosphere at a heating rate of 20°C/min. UV-vis absorption spectra were recorded by Hitachi U-3010 spectrophotometer (Tokyo, Japan).
3. Results and Discussion
The phase and crystallographic structure of the as-prepared metal Se compounds were determined by XRD. Figure 1 showed XRD patterns of the as-prepared (a) InSe, (b) In2Se3, (c) CuSe, and (d) Cu2Se particles, which corresponded to the cubic phase, consistent with the literature , the hexagonal structure (JCPDS no. 89-0658) , the klockmannite structure (JCPDS no. 49-1457) , and the cubic structure (JCPDS no. 88-2044) , respectively. Figure 2 showed XRD patterns of the CIS films synthesized from (a) the as-prepared metal Se compounds: InSe and CuSe, and (b) the as-prepared metal Se compounds: In2Se3 and Cu2Se, respectively. The chemical composition of the as-prepared metal Se compounds and other products was analyzed with EDS and given in Table 1.
Figure 2(a) showed XRD pattern obtained from the annealed thin film made by CuSe and InSe, which exhibited a single crystalline structure composed of CIS that corresponds to the peaks at (112), (211), (204)/(220), (116)/(312), (008)/(400), (316)/(332), and (228)/(424). The chalcopyrite phase of CIS (JCPDS no. 40-1487) was then synthesized. Figure 2(b) showed XRD pattern obtained from the annealed thin film made by Cu2Se and In2Se3, which exhibited a multicrystalline structure composed of CuInSe2 and In2Se3 that corresponds to the chalcopyrite CIS and the hexagonal In2Se3.
Figure 3 showed various images of the as-prepared CIS thin film from path A: (a) cross-sectioned SEM image for the as-synthesized CIS before annealing and (b) that after annealing, (c) LR-TEM, and (d) HR-TEM and SAED (the insert) images for the as-prepared CIS. In Figure 3(a), the upper layer was identified as InSe particles with irregular shapes. The lower layer was identified as CuSe particles with a regular hexagonal shape of around 2 μm in diameter. In Figure 3(b), the CIS thin film exhibited a regular shape of hexagonal chalcopyrite particles. The insert image was the dispersed CIS particles from its film. Figure 3(c) showed the LR-TEM image of CIS particle. Its morphology and particle size were consistent with those observed by SEM. Figure 3(d) showed the HR-TEM and inserted SAED image of CIS particle. The spacing of the crystal lattice was measured around 3.3 Å, which is consistent with the crystal lattice plane of CIS under (112). The EDS analysis expected an average composition of Cu1.0In0.79Se1.86, which estimated an element ratio for copper, indium, and selenium of 1.27 : 1.00 : 2.36. The CIS structure prepared through the solid state reaction showed a Cu- and Se-rich structure, but roughly correlated with the composition of CuInSe2.
Hsiang et al.  investigated that the CIS crystalline reaction from Cu2Se and In2Se3 was close to that from the Cu2Se reactant particle, based on the TEM result. It indicates that the solid state reaction kinetics may be dominated by the In3+ ions diffusion. The same situation also occurred in the experiment of path A. From TEM images, the solid state reaction kinetics of path A was most probably dominated by the In3+ ions diffusion. On the other hand, the reaction kinetics using solid state reaction from CuSe and InSe precursors was lower than that from Cu2Se and In2Se3 precursors [16, 17]. Figure 4 showed TGA curves of (a) CuSe, (b) InSe, (c) Cu2Se, (d) In2Se3, and (e) CIS particles prepared by the reaction path A or B via solid state reaction. The figures showed the total percentage of weight loss as the increasing temperatures till 800°C. According to Figures 4(a)–4(d), only InSe had 7% weight loss, whereas almost no weight loss measured till 350°C for CuSe, Cu2Se, and In2Se3 was found. Figure 4(e) showed that the weight loss of path A was about 1.5% at 600°C. The result indicated that CIS particles prepared by solid state reaction exhibited good thermal stability. In addition, the weight loss of path B was about 0.1% at 350°C and about 2.5% at 600°C, which indicated that the path B might require higher reaction temperature to form CIS phase. As a result, the path B for synthesizing CIS phase was relatively difficult at 350°C, while the solid state reaction kinetics of path A was presumably dominated by In3+ ions diffusion .
Furthermore, Figure 5(a) showed the UV-vis absorption spectrum of CIS particles prepared by reaction path A. The sample was dispersed in absolute ethanol under intense sonication for 20 min, while ethanol was used as a reference. The band gap of CIS particles was calculated using the direct band gap method from its optical absorption spectrum ; the value was determined as 1.06 eV, which is consistent with the reported value of 1.04 eV for the bulk CIS . Figure 5(b) showed Raman spectrum of CIS thin films synthesized from the reaction path A. The main peak at around 177 cm−1 could be identified as the A1 vibrational mode from chalcopyrite ordered CIS. A relatively small peak at around 240 cm−1 was related to the characteristic mode from the elemental Se [19, 20]; however, scarcely Se could not be found in the form of CIS thin film. The Cu and Se binary phase were difficult to be identified in the measured spectral range: the peak at 259 cm−1 was the most intense one observed on Raman spectrum of CuSe .
In this work, CIS thin film is successfully fabricated by using CuSe and InSe binary precursors via a low temperature solid state reaction. The XRD results indicate that CIS thin film has a chalcopyrite structure with good crystallinity, which exhibits (112) prefer orientation. Particularly, CIS thin film can be preferably obtained by path A with the reaction of CuSe + InSe → CuInSe2 at relatively low temperature (350°C) and short preparation time (3 h). Besides, the weight loss indicated by TGA pattern is only 1.5% at 600°C. The value of band gap for the as-prepared CIS is calculated to be 1.06 eV, which demonstrates that this material is suitable to be used for a thin film solar cell light absorption material. Its good absorption in the visible light region also suggests that such photovoltaic material is promising for sustainable energy related applications.
The authors thank the National Sciences Council of Taiwan for the financial support, Grant nos. NSC 102-2113-M-024-001 and 101-2321-B-006-01.
- G. Conibeer, M. Green, E.-C. Cho et al., “Silicon quantum dot nanostructures for tandem photovoltaic cells,” Thin Solid Films, vol. 516, no. 20, pp. 6748–6756, 2008.
- B. Levy, “Photochemistry of nanostructured materials for energy applications,” Journal of Electroceramics, vol. 1, pp. 239–272, 1997.
- D. Cahen, J.-M. Gilet, C. Schmitz, L. Chernyak, K. Gartsman, and A. Jakubowicz, “Room-temperature, electric field-induced creation of stable devices in CuInSe2 crystals,” Science, vol. 258, no. 5080, pp. 271–274, 1992.
- I. Repins, M. A. Contreras, B. Egaas et al., “19.9%-efficient ZnO/CdS/CuInGaSe2 solar cell with 81.2% fill factor,” Progress in Photovoltaics, vol. 16, no. 3, pp. 235–239, 2008.
- W. Liu, Y. Sun, W. Li, C.-J. Li, F.-Y. Li, and J.-G. Tian, “Influence of different precursor surface layers on Cu()Se2 thin film solar cells,” Applied Physics A, vol. 88, no. 4, pp. 653–656, 2007.
- F. Kurdesau, M. Kaelin, V. B. Zalesski, and V. I. Kovalewsky, “In situ resistivity measurements of Cu-In thin films during their selenization,” Journal of Alloys and Compounds, vol. 378, no. 1-2, pp. 298–301, 2004.
- Q. Guo, S. J. Kim, M. Kar et al., “Development of CulnSe2 nanocrystal and nanoring inks for low-cost solar cells,” Nano Letters, vol. 8, no. 9, pp. 2982–2987, 2008.
- L. Kaupmees, M. Altosaar, O. Volubujeva, and E. Mellikov, “Study of composition reproducibility of electrochemically co-deposited CuInSe2 films onto ITO,” Thin Solid Films, vol. 515, no. 15, pp. 5891–5894, 2007.
- F. Kang, J. Ao, G. Sun, Q. He, and Y. Sun, “Structure and photovoltaic characteristics of CuInSe2 thin films prepared by pulse-reverse electrodeposition and selenization process,” Journal of Alloys and Compounds, vol. 478, no. 1-2, pp. L25–L27, 2009.
- S. L. Castro, S. G. Bailey, R. P. Raffaelle, K. K. Banger, and A. F. Hepp, “Nanocrystalline chalcopyrite materials (CuInS2 and CuInSe2) via low-temperature pyrolysis of molecular single-source precursors,” Chemistry of Materials, vol. 15, no. 16, pp. 3142–3147, 2003.
- R. H. Bari, L. A. Patil, P. S. Sonawane, M. D. Mahanubhav, V. R. Patil, and P. K. Khanna, “Studies on chemically deposited CuInSe2 thin films,” Materials Letters, vol. 61, no. 10, pp. 2058–2061, 2007.
- P. F. Luo, R. Z. Zuo, and L.T. Chen, “The preparation of CuInSe2 films by combustion method and non-vacuum spin-coating process,” Solar Energy Materials and Solar Cells, vol. 94, no. 6, pp. 1146–1151, 2010.
- K. H. Park, K. Jang, S. Kim, J. K. Hae, and U. S. Seung, “Phase-controlled one-dimensional shape evolution of InSe nanocrystals,” Journal of the American Chemical Society, vol. 128, no. 46, pp. 14780–14781, 2006.
- P.-Y. Lin and Y.-S. Fu, “Fabrication of CuInSe2 light absorption materials from binary precursors via wet chemical process,” Materials Letters, vol. 75, pp. 65–67, 2012.
- H.-I. Hsiang, L.-H. Lu, Y.-L. Chang, D. Ray, and F.-S. Yen, “CuInSe2 nano-crystallite reaction kinetics using solid state reaction from Cu2Se and In2Se3 powders,” Journal of Alloys and Compounds, vol. 509, no. 24, pp. 6950–6954, 2011.
- S. Kim, W. K. Kim, R. M. Kaczynski et al., “Reaction kinetics of CuInSe2 thin films grown from bilayer InSe/CuSe precursors,” Journal of Vacuum Science and Technology A, vol. 23, no. 2, pp. 310–315, 2005.
- J. S. Park, Z. Dong, S. Kim, and J. H. Perepezko, “CulnSe2 phase formation during Cu2Se/In2Se3 interdiffusion reaction,” Journal of Applied Physics, vol. 87, no. 8, pp. 3683–3690, 2000.
- H. S. Soliman, M. M. El-Nahas, O. Jamjoum, and K. A. Mady, “Optical properties of CulnSe2 thin films,” Journal of Materials Science, vol. 23, no. 11, pp. 4071–4075, 1988.
- V. V. Poborchii, A. V. Kolobov, and K. Tanaka, “An in situ Raman study of polarization-dependent photocrystallization in amorphous selenium films,” Applied Physics Letters, vol. 72, no. 10, pp. 1167–1169, 1998.
- P. Nagels, E. Sleeckx, R. Callaerts, and L. Tichy, “Structural and optical properties of amorphous selenium prepared by plasma-enhanced CVD,” Solid State Communications, vol. 94, no. 1, pp. 49–52, 1995.
- M. Ishii, K. Shibata, and H. Nozaki, “Anion distributions and phase transitions in (x = 0 − 1) studied by raman spectroscopy,” Journal of Solid State Chemistry, vol. 105, no. 2, pp. 504–511, 1993.
Copyright © 2013 Kuo-Chin Hsu et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.