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International Journal of Polymer Science
Volume 2013, Article ID 156289, 10 pages
Research Article

Synthesis and Characterizations of Poly(trimethylene terephthalate)-b-poly(tetramethylene glycol) Copolymers

College of Chemistry & Environmental Science, Hebei University, Baoding 071002, China

Received 30 June 2013; Revised 1 October 2013; Accepted 1 October 2013

Academic Editor: Giridhar Madras

Copyright © 2013 Feng Liu et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


A series of poly(trimethylene terephthalate)-b-poly(tetramethylene glycol) (PTT-PTMEG) copolymers were synthesized by two-step melt-polycondensation. The copolymers were characterized by using Fourier transform infrared spectroscopy (FTIR), 1H NMR spectroscopy, rheometer, differential scanning calorimetry (DSC), polarized optical microscopy (POM), thermal gravimetric analysis (TGA), and mechanical properties. The results suggest that by increasing the flexible PTMEG contents from 0% to 60 wt%, the copolymers show decreased glass transition temperatures, melting points, melt-crystallization temperatures, hardness, tensile strength, thermostability, and smaller spherulites dimensions; however it has much increased impact strength and elongation at breaking point. Compared with commercial poly(butylene terephthalate) (PBT)-type TPEE with 25 mol% flexible segments, PTT-type TPEE having 25 mol% flexible segments has a lower glass transition temperature, melting point, crystallization temperature, and much lower tensile strength although it has a much higher impact strength than that of PBT-type TPEE, and it is not suitably used as a commercial TPEE.