Research Article
Removal of Methylene Blue from Aqueous Solution Using Agricultural Residue Walnut Shell: Equilibrium, Kinetic, and Thermodynamic Studies
Table 4
Adsorption parameters of methylene blue on the walnut shell powder at different temperatures.
| Isotherm | Parameter | /K | 298 | 308 | 318 | 328 |
| Langmuir | | 0.999 | 0.979 | 0.971 | 0.987 | /mg⋅g−1 | 51.55 | 49.83 | 56.13 | 55.96 | /L⋅mg−1 | 0.419 | 0.181 | 0.163 | 0.119 |
| Freundlich | | 0.981 | 0.972 | 0.963 | 0.987 | | 18.80 | 15.86 | 13.00 | 10.50 | | 0.270 | 0.323 | 0.357 | 0.464 |
| D-R | | 0.987 | 0.998 | 0.989 | 0.995 | /kJ⋅mol−1 | 16.13 | 22.44 | 12.64 | 15.15 |
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