| Key characteristics | LC | GC |
| Targeted compound | Relative molecular mass is large (1000–2000), high boiling point, and difficult to volatilize | Relatively small molecular mass (<1000), low boiling point, and volatile [60] | Columns | Tens to hundreds of millimeters [61] | A few meters to tens of meters and different capillary columns [62] | Mobile phase | Liquids, single or mixed water, acetonitrile, and methanol | Gases, such as H2, N2, Ar, He, and CO2 [63] | Flow rate | ≤1.0 mL/min, normally [64] | 20–100 mL/min, normally [64] | Detection time | HPLC > UPLC | A few to tens of minutes | Detector | Ultraviolet detector (UV-detector), mass spectrometry (MS), diode array detector (DAD), fluorescence detector (FLD), and refractive index detector (RID) [65] | Flame ionization detector (FID), thermal conductivity detector (TCD), electron capture detector (ECD), flame photometric detector (FPD), nitrogen phosphorus detector (NPD), and MS [63, 66] | Others | Room temperature detection, using a flat-headed injection needle | In the gasification chamber gasification, higher detection temperature, using a pointed injection needle |
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