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Journal of Nanomaterials
Volume 2008, Article ID 964046, 5 pages
http://dx.doi.org/10.1155/2008/964046
Research Article

Enhanced Mechanical Properties in Organofluorosilica Thin Films

1Istituto per lo Studio dei Materiali Nanostrutturati, Consiglio Nazionale delle Ricerche (CNR), Via Ugo La Malfa 153, 90146 Palermo, Italy
2Dipartimento di Ingegneria Chimica dei Processi e dei Materiali, Università degli Studi di Palermo, Viale delle Scienze, 90128 Palermo, Italy
3Laboratoire de Métallurgie Physique, CNRS UMR 6630, Université de Poitiers, téléport 2, boulevard Marie et Pierre Curie, 86962 Futuroscope-Chasseneuil Cedex, France
4Centro de Química-Física Molecular, Complexo I, Instituto Superior Técnico, Avenida Rovisco Pais, 1049-001 Lisboa, Portugal

Received 23 May 2008; Revised 1 August 2008; Accepted 4 September 2008

Academic Editor: Müjdat Çağlar

Copyright © 2008 Mario Pagliaro et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. G. Palmisano, E. Le Bourhis, R. Ciriminna, D. Tranchida, and M. Pagliaro, “ORMOSIL thin films: tuning mechanical properties via a nanochemistry approach,” Langmuir, vol. 22, no. 26, pp. 11158–11162, 2006. View at Publisher · View at Google Scholar · View at PubMed
  2. B. D. Hatton, K. Landskron, W. Whitnall, D. D. Perovic, and G. A. Ozin, “Spin-coated periodic mesoporous organosilica thin films—towards a new generation of low-dielectric-constant materials,” Advanced Functional Materials, vol. 15, no. 5, pp. 823–829, 2005. View at Publisher · View at Google Scholar
  3. J. G. C. Veinot and T. J. Marks, “Toward the ideal organic light-emitting diode. The versatility and utility of interfacial tailoring by cross-linked siloxane interlayers,” Accounts of Chemical Research, vol. 38, no. 8, pp. 632–643, 2005. View at Publisher · View at Google Scholar · View at PubMed
  4. F. Mammeri, E. Le Bourhis, L. Rozes, and C. Sanchez, “Mechanical properties of hybrid organic-inorganic materials,” Journal of Materials Chemistry, vol. 15, no. 35-36, pp. 3787–3811, 2005. View at Publisher · View at Google Scholar
  5. W. C. Oliver and G. M. Pharr, “Improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments,” Journal of Materials Research, vol. 7, no. 6, pp. 1564–1580, 1992. View at Google Scholar
  6. M. M. Chaudhri, “A note on a common mistake in the analysis of nanoindentation data,” Journal of Materials Research, vol. 16, no. 2, pp. 336–339, 2001. View at Publisher · View at Google Scholar
  7. R. B. King, “Elastic analysis of some punch problems for a layered medium,” International Journal of Solids and Structures, vol. 23, no. 12, pp. 1657–1664, 1987. View at Google Scholar
  8. A. C. Fischer-Cripps, Nanoindentations, Springer, New York, NY, USA, 2002.
  9. R. D. Chambers, Fluorine in Organic Chemistry, Blackwell, Oxford, UK, 2004.
  10. M. A. McHugh, I.-H. Park, J. J. Reisinger, Y. Ren, T. P. Lodge, and M. A. Hillmyer, “Solubility of CF2-modified polybutadiene and polyisoprene in supercritical carbon dioxide,” Macromolecules, vol. 35, no. 12, pp. 4653–4657, 2002. View at Publisher · View at Google Scholar
  11. M. Pagliaro and R. Ciriminna, “New fluorinated functional materials,” Journal of Materials Chemistry, vol. 15, no. 47, pp. 4981–4991, 2005. View at Publisher · View at Google Scholar
  12. R. Ciriminna, S. Campestrini, and M. Pagliaro, “FluoRuGel: a versatile catalyst for aerobic alcohol oxidation in supercritical carbon dioxide,” Organic & Biomolecular Chemistry, vol. 4, no. 13, pp. 2637–2641, 2006. View at Publisher · View at Google Scholar · View at PubMed
  13. R. M. Bukowski, R. Ciriminna, M. Pagliaro, and F. V. Bright, “High-performance quenchometric oxygen sensors based on fluorinated xerogels doped with [Ru(dpp)3]2+,” Analytical Chemistry, vol. 77, no. 8, pp. 2670–2672, 2005. View at Publisher · View at Google Scholar · View at PubMed
  14. M. Pagliaro, R. Ciriminna, M. W. C. Man, and S. Campestrini, “Better chemistry through ceramics: the physical bases of the outstanding chemistry of ORMOSIL,” Journal of Physical Chemistry B, vol. 110, no. 5, pp. 1976–1988, 2006. View at Publisher · View at Google Scholar · View at PubMed