Research Article

Subzero Temperature Dip-Coating of Sol-Gel Vanadium Pentoxide: Effect of the Deposition Temperature on the Film Structure, Morphology, and Electrochromic Properties

Table 3

Position of the Raman bands in the spectra corresponding to the subzero and room-temperature dip-coating.

 Position of Raman bands (cm−1)Assignment
RTLT (cm−1)

997.49997.96+0.47ν (terminal O)
708.44711.26+2.82ν (V2-O)
528.15532.16+4.01ν (V3-O)
484.75486.71+1.96δ (V-O-V)
406.06408.03+1.97δ (V=O)
303.32303.66+0.34
283.97286.95+2.98δ (V=O)

Room-temperature dip-coated and annealed at 500°C.
Low-temperature dip-coated and annealed at 500°C
LT-RT.