Effects of Aluminum on Hydrogen Solubility and Diffusion in Deformed Fe-Mn Alloys

<table class="table-group" id="tab2"><tr><td><table class="table"><tr><td class="thead-hr" colspan="4"><hr/></td></tr><tr class="thead"><td class="align_left">System</td><td class="align_center"><svg height="11.927pt" id="M76" style="vertical-align:-3.291101pt" version="1.1" viewbox="-0.0498162 -8.6359 13.0189 11.927" width="13.0189pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M593 650H142L136 622C219 616 224 611 209 531L130 120C114 39 108 34 23 28L17 0H501C518 32 557 130 568 158L540 169C519 132 495 93 469 70C439 43 409 35 332 35C272 35 241 37 225 50C211 61 211 89 222 149L253 320H350C441 320 443 312 441 239H471L510 434H481C455 366 448 358 360 358H260L303 572C311 613 312 615 348 615H431C509 615 522 603 532 581C544 555 546 531 545 491L574 493C583 555 592 631 593 650Z" id="g113-70"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="616" vert-adv-y="616"></glyph.data></g><g transform="matrix(.0091,0,0,-0.0091,7.943,3.132)"><path d="M245 635C92 635 37 457 37 312C37 149 91 -12 244 -12C395 -12 449 166 449 312C449 469 395 635 245 635ZM243 598C332 598 358 454 358 312C358 173 334 26 245 26C158 26 128 174 128 313S152 598 243 598Z" id="g50-49"></path><glyph.data ascent="3443" descent="-2856" horiz-adv-x="487" vert-adv-y="487"></glyph.data></g></svg> (eV)</td><td class="align_center"><svg height="11.927pt" id="M77" style="vertical-align:-3.291101pt" version="1.1" viewbox="-0.0498162 -8.6359 12.8231 11.927" width="12.8231pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M578 512C578 619 494 650 387 650H140L134 622C219 615 223 609 210 542L127 119C112 40 104 34 23 28L17 0H235C317 0 387 7 444 33C515 65 564 122 564 195C564 289 495 335 412 352V354C505 373 578 422 578 512ZM486 510C486 422 423 367 314 367H257L294 565C299 591 305 602 315 608C324 614 339 617 362 617C421 617 486 595 486 510ZM466 200C466 100 393 35 296 35C222 35 198 51 212 127L250 333H303C388 333 466 303 466 200Z" id="g113-67"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="601" vert-adv-y="601"></glyph.data></g><g transform="matrix(.0091,0,0,-0.0091,7.748,3.132)"><path d="M245 635C92 635 37 457 37 312C37 149 91 -12 244 -12C395 -12 449 166 449 312C449 469 395 635 245 635ZM243 598C332 598 358 454 358 312C358 173 334 26 245 26C158 26 128 174 128 313S152 598 243 598Z" id="g50-49"></path><glyph.data ascent="3443" descent="-2856" horiz-adv-x="487" vert-adv-y="487"></glyph.data></g></svg> (GPa)</td><td class="align_center"><span style="width: 33.7392ptpx;"><svg height="11.439pt" id="M78" style="vertical-align:-2.15067pt" version="1.1" viewbox="-0.0498162 -9.28833 33.7392 11.439" width="33.7392pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M471 379C471 433 467 511 427 578C379 658 305 712 208 712C154 712 98 699 70 684C70 668 95 634 111 634C141 651 180 665 234 665C306 665 350 627 372 575C391 530 393 480 393 442V415C371 436 344 448 313 448C280 448 227 437 176 411C100 372 23 279 23 148C23 67 64 -12 180 -12C293 -12 360 46 407 129C450 205 471 310 471 379ZM382 335C382 142 289 50 238 35C226 31 213 28 200 28C139 28 110 91 110 164C110 310 191 382 223 395C245 404 259 409 280 409C305 409 332 404 359 388C379 376 382 362 382 335Z" id="g113-222"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="494" vert-adv-y="494"></glyph.data></g><g transform="matrix(.013,0,0,-0.013,6.163,0)"><path d="M578 512C578 619 494 650 387 650H140L134 622C219 615 223 609 210 542L127 119C112 40 104 34 23 28L17 0H235C317 0 387 7 444 33C515 65 564 122 564 195C564 289 495 335 412 352V354C505 373 578 422 578 512ZM486 510C486 422 423 367 314 367H257L294 565C299 591 305 602 315 608C324 614 339 617 362 617C421 617 486 595 486 510ZM466 200C466 100 393 35 296 35C222 35 198 51 212 127L250 333H303C388 333 466 303 466 200Z" id="g113-67"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="601" vert-adv-y="601"></glyph.data></g><g transform="matrix(.013,0,0,-0.013,13.976,0)"><path d="M368 703H309L44 -163H104L368 703Z" id="g113-48"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="412" vert-adv-y="412"></glyph.data></g><g transform="matrix(.013,0,0,-0.013,19.338,0)"><path d="M471 379C471 433 467 511 427 578C379 658 305 712 208 712C154 712 98 699 70 684C70 668 95 634 111 634C141 651 180 665 234 665C306 665 350 627 372 575C391 530 393 480 393 442V415C371 436 344 448 313 448C280 448 227 437 176 411C100 372 23 279 23 148C23 67 64 -12 180 -12C293 -12 360 46 407 129C450 205 471 310 471 379ZM382 335C382 142 289 50 238 35C226 31 213 28 200 28C139 28 110 91 110 164C110 310 191 382 223 395C245 404 259 409 280 409C305 409 332 404 359 388C379 376 382 362 382 335Z" id="g113-222"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="494" vert-adv-y="494"></glyph.data></g><g transform="matrix(.013,0,0,-0.013,25.501,0)"><path d="M600 480C600 590 528 650 384 650H143L137 622C222 614 225 607 210 531L130 127C113 41 106 36 23 28L17 0H294L300 28C204 36 195 42 212 127L243 284L314 263C327 263 339 263 352 264C465 271 600 337 600 480ZM508 481C508 351 402 304 329 304C289 304 265 311 250 317L295 559C302 594 310 606 323 611C335 616 350 619 367 619C455 619 508 573 508 481Z" id="g113-81"></path><glyph.data ascent="3473" descent="-2876" horiz-adv-x="617" vert-adv-y="617"></glyph.data></g></svg></span></td></tr><tr><td class="thead-hr" colspan="4"><hr/></td></tr><tr><td class="align_left">Fe<sub>24</sub>Mn<sub>8</sub></td><td class="align_center">−265.581</td><td class="align_center">176.6</td><td class="align_center">4.78</td></tr><tr><td class="align_left">Fe<sub>24</sub>Mn<svg height="6.00939pt" id="M79" style="vertical-align:-3.29111pt" version="1.1" viewbox="-0.0498162 -2.71828 5.04606 6.00939" width="5.04606pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.0091,0,0,-0.0091,0,3.132)"><path d="M253 635C142 635 71 555 71 471C71 401 113 353 178 316C144 294 106 267 91 252C70 231 46 202 46 157C46 51 132 -12 241 -12C328 -12 442 52 442 168C442 257 379 305 311 343C354 373 380 398 388 407C406 428 417 458 417 487C417 568 348 635 253 635ZM240 600C288 600 340 563 340 481C340 423 313 387 279 360C207 394 148 427 148 499C148 549 182 600 240 600ZM252 23C188 23 129 73 129 163C129 217 162 266 211 298C289 260 360 217 360 144C360 69 312 23 252 23Z" id="g50-57"></path><glyph.data ascent="3443" descent="-2856" horiz-adv-x="487" vert-adv-y="487"></glyph.data></g></svg>H</td><td class="align_center">−268.922</td><td class="align_center">175.6</td><td class="align_center">4.70</td></tr><tr><td class="align_left">Fe<sub>23</sub>Mn<sub>8</sub>Al</td><td class="align_center">−261.717</td><td class="align_center">168.5</td><td class="align_center">4.847</td></tr><tr><td class="align_left">Fe<sub>23</sub>Mn<sub>8</sub>AlH (oc1)</td><td class="align_center">−264.992</td><td class="align_center">168.3</td><td class="align_center">4.763</td></tr><tr><td class="align_left">Fe<sub>23</sub>Mn<sub>8</sub>AlH (oc2)</td><td class="align_center">−265.141</td><td class="align_center">167.4</td><td class="align_center">4.910</td></tr><tr class="table-tr"><td colspan="4"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

Energies at equilibrium volume, bulk modulus, and its derivative with respect to pressure as obtained from Murnaghan fits of the <i>ab initio</i> data.

Advances in Materials Science and Engineering

tab2

Table 2

Table 2: Effects of Aluminum on Hydrogen Solubility and Diffusion in Deformed Fe-Mn Alloys 