Kinetic Analysis of the Thermal Decomposition of Polymer-Bonded Explosive Based on PETN: Model-Fitting Method and Isoconversional Method

Table 4

Kinetic parameters of PETN and PBXs by the modified KAS method.

φ	PETN			PBX-PN-85			PBX-PP-85
	Eφ (kJ⋅mol^−1)	ln A, (min^−1)	R^2	Eφ (kJ⋅mol^−1)	ln A, (min^−1)	R^2	Eφ (kJ⋅mol^−1)	ln A, (min^−1)	R^2
0.1	133.8	24.7	0.9955	124.5	21.3	0.9835	139.3	27.8	0.9880
0.2	138.3	26.3	0.9915	136.3	25.4	0.9905	150.4	32.5	0.9950
0.3	141.3	27.2	0.9850	136.5	24.9	0.9945	152.6	33.2	0.9915
0.4	145.2	28.4	0.9884	138.6	26.8	0.9964	152.1	32.4	0.9835
0.5	145.3	28.6	0.9935	137.9	24.8	0.9924	155.5	34.1	0.9980
0.6	147.1	29.9	0.9828	136.6	24.6	0.9920	153.2	32.2	0.9909
0.7	145.8	28.9	0.9845	135.8	24.7	0.9960	148.5	31.3	0.9945
0.8	141.4	27.5	0.9899	137.9	26.4	0.9949	147.6	29.8	0.9952
0.9	141.8	27.7	0.9854	127.2	22.6	0.9935	146.7	27.8	0.9960
Mean	144.9	28.6		137.1	25.2		152.4	32.6