Review Article

Edible Oil Parameters during Deterioration Processes

Table 1

Advantages and disadvantages of the basic characterization methods of fat and oils.

NamePrinciple to useInstrumentationAdvantagesDisadvantagesRef.

Acid valueAcid base reactionTitration using buretteReproducible, low cost, reliable resultsDepends on human vision, based on only one fatty acid[6, 15]
Iodine valueOxide reduction reactionTitration using buretteReproducible, low cost, reliable resultsExcess titration, indirect procedure[6, 22]
Saponification valueSaponification reactionTitration using buretteReproducible, low cost, reliable resultsDependent on temperature and human vision[6, 19]
Thiobarbituric acid indexFormation of the alkylidentiobarbituric acidsSpectrophotometerGood correlation with other chemical methods and sensory evaluationTime consuming[23, 24]
Total polar compounds (TPC)AdsorptionColumn chromatographyThis method is accurate and reproducible. Oils with similar PUFA good correlation between TPC and degradation products. Kinetics parametersTime consuming, weak correlation between TPC and oils with a high content of diacylglycerols[25, 26]