Research Article | Open Access
Shang-Chou Chang, "In-Line Sputtered Gallium and Aluminum Codoped Zinc Oxide Films for Organic Solar Cells", International Journal of Photoenergy, vol. 2014, Article ID 916189, 6 pages, 2014. https://doi.org/10.1155/2014/916189
In-Line Sputtered Gallium and Aluminum Codoped Zinc Oxide Films for Organic Solar Cells
Gallium and aluminum codoped zinc oxide (GAZO) films were deposited at different temperatures by in-line sputtering. Aluminum is thermally unstable compared to other elements in GAZO films. The grains of GAZO films increase with deposition temperature. Coalescence between grains was observed for GAZO films deposited at 250°C. The deposition temperature exhibits positive influence on crystallinity, and electrical and optical properties of GAZO films. The carrier concentration and mobility of GAZO films increase, while the electrical resistivity of GAZO films decreases with deposition temperature. The average optical transmittance of GAZO films rises with deposition temperature. In-line sputtering demonstrates a potential method with simplicity, mass production, and large-area deposition to produce GAZO films with good electrical and optical quality. The electrical resistivity of 4.3 10−4 Ω cm and the average optical transmittance in the visible range from 400 to 800 nm of 92% can be obtained for GAZO films deposited at 250°C. The hybrid organic solar cells (OSC) were fabricated on GAZO-coated glass substrates. Blended poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C61 butyric acid methyl ester (PCBM) were the photoactive materials in OSC. The power conversion efficiency of OSC is 0.65% for the OSC with the 250°C deposited GAZO electrode.
Transparent conductive oxides (TCO) are widely used in fabricating transparent electrodes of solar cells, touch panel displays, organic light emitting devices, and transparent thin films transistors [1, 2]. Tin doped indium oxide (ITO) is the commonly used materials of TCO nowadays due to its excellent electrical and optical properties. However, there are demerits for ITO. Indium in ITO is expensive and indium oxide is easily reduced in hydrogen plasma [3, 4]. Impurity doped ZnO has been developed as alternative to ITO for several advantages: lower cost, lower synthesis temperature, higher etch ability, and higher resistance to hydrogen plasma reduction. The aluminum doped zinc oxide (AZO) and gallium doped zinc oxide (GZO) have been most widely used in impurity doped ZnO . Good electrical and optical properties of AZO were reported. The AZO has better resistance over ITO in hydrogen plasma reduction. The hydrogen plasma is often encountered in fabricating transparent electrodes of amorphous silicon [6, 7]. Gallium is less reactive and more resistant to oxidation compared to Al [8, 9]. The diffusivity of Ga is smaller than that of Al such that Ga causes less diffusion-related problems .
Ionic and covalent radii of Ga are 0.62 and 1.26 Å, respectively, close to those of Zn (0.74 and 1.31 Å), compared with those of Al (0.50 and 1.26 Å) . The covalent bond length of Ga–O (1.92 Å) is almost the same as that of Zn–O (1.97 Å) . Less deformation of ZnO lattice is expected when Ga atoms substitute Zn sites in ZnO crystal lattice . Gallium and aluminum codoped zinc oxide (GAZO) films were fabricated and expected to obtain the benefits of both AZO and GZO films. The GAZO films have been prepared by several deposition methods such as pulsed laser deposition, cosputtering, and facing targets sputtering [2, 10, 13–15]. In-line sputtering technique is widely used in mass-production system for large-sized substrates. The substrates pass linearly along one or more sputter cathodes to acquire thin film coating. This work applied in-line sputtering techniques to fabricate GAZO films with various deposition temperatures. Structural, electrical, and optical characteristics of in-line sputtered GAZO films were explored. Organic solar cells (OSC) with ZnO based electrode have been reported in recent years [16–21]. Few or no reports were found for using GAZO films as the electrode of OSC. The GAZO films found with good electrical and optical properties were used as the electrode to replace ITO in fabricating hybrid OSC. The process flow of fabricating OSC was similar to the hybrid OSC with ITO electrode used in our group [22, 23].
2. Experimental Procedure
Borosilicate glass was applied as the substrate that GAZO films were deposited on. The borosilicate glass was treated with ultrasonic cleaning using purified water and acetone in sequence to remove grease and debris. The glass was then cleaned with purified water and dried with nitrogen. One in-line sputtering tool was used to deposit GAZO films. The DC power of sputtering cathode was 6 kW. The ceramic GAZO target was with Zn : O : Ga : Al = 44 : 53 : 2 : 1 at% in composition and 950 × 125 mm2 in size. The sputtering power density was 2.53 W/cm2. The process chamber was pumped down to 1 × 10−3 Pa as base pressure. The process pressure was kept at 3 × 10−1 Pa with feeding argon in flow rate of 300 sccm. The substrate was moved linearly along the sputtering cathode with speed of 6 mm/sec during sputtering. The deposition temperature was varied from room temperature (RT) to 250°C. The film thickness of deposited GAZO films was 500 nm.
The crystalline structure, films composition, and surface morphology of GAZO films deposited at various substrate temperatures were probed with an X-ray diffract meter (model D/MAX-2500V, Rigaku), energy dispersive spectrometer (EDS), and field emission scanning electron microscope (FESEM) (model JSM-6700F, JEOL), respectively. The carrier concentration, mobility, and electrical resistivity of GAZO films were explored by a Hall measurement with van der Pauw method (model HMS-3000, Ecopia). The optical transmittance of GAZO films was measured by an UV-VIS spectrophotometer (model U-2800A, Hitachi). Structural, electrical, and optical characteristics of GAZO films deposited at various temperatures were compared.
The produced GAZO films found with good electrical and optical characteristics were used as the electrode to produce hybrid OSC. The GAZO glass substrates were oxygen plasma cleaned by an inductively coupled plasma system to make the surface of GAZO films hydrophilic. A layer of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS, Baytron P 4083) about 40 nm thick was spin-coated on the GAZO substrate and baked at 120°C for 30 min. The photoactive layer was made of poly(3-hexylthiophene) (P3HT) (FEM. Inc.) and -phenyl C61 butyric acid methyl ester (PCBM) (Nano-C) dissolved in 1,2-dichlorobenzene. The P3HT and PCBM were 10 : 8 wt% in proportion. The photoactive materials were spin-coated with a rotation speed of 800 rpm in a glove box, and the resulting film was about 300 nm thick. The P3HT:PCBM blend film was then annealed at 120°C for 10 min to reduce contact resistance of electrodes. Finally, a 120 nm thick Ca/Al electrode was deposited onto the P3HT:PCBM blend film through a shadow mask by thermal evaporation. The current density voltage measurements were obtained by using a source meter (Keithley, 2410) and a solar simulator (TELTEC) with an AM 1.5 illumination and intensity of 100 mW/cm2.
3. Results and Discussion
3.1. Structural Properties
All the GAZO films deposited at various temperatures have only (002) preferential direction obtained from the spectra of X-ray diffraction (XRD). The (002) peak in XRD spectra of the GAZO films deposited at RT, 100°C, 200°C, and 250°C is shown in Figure 1. The intensity of (002) peak increases, while the corresponding full width at half maximum decreases with deposition temperature. It indicates that the crystallinity of GAZO films improves with thermal energy provided by heating substrate during sputtering. The (002) peak shifts to a higher angle with rising deposition temperature, which means that the adjacent (002) interplanar distance of GAZO films decreases with deposition temperature of GAZO films. This phenomenon could be related to more Ga and Al atoms substitution for Zn in ZnO crystal lattice when GAZO films were deposited at high temperatures, since the ionic and covalent radii of Ga and Al are smaller than those of Zn .
The atomic percent in films composition of the GAZO films deposited at RT, 100°C, 200°C, and 250°C is listed in Table 1. The impurities, both Ga and Al, were found for all GAZO films deposited at different temperatures. The atomic percent of Al decreases while that of Ga increases with deposition temperature. The Al in AZO films is thermally unstable which is found from our previous work . The intensity of thermal desorption for Al is highest among Zn, O, and Al in AZO films. The Al in GAZO films may be thermally desorbed easier than other elements during films formation at high deposition temperature. This explains why the atomic percent of Al in GAZO films decreases with deposition temperature. Figures 2(a), 2(b), 2(c), and 2(d) show SEM micrographs of the GAZO films deposited at RT, 100°C, 200°C, and 250°C. Grains of the GAZO films grow with deposition temperature observed from Figures 2(a) to 2(d). Coalescence between grains for GAZO films deposited at 250°C can be seen from Figure 2(d). The phenomena of grain growth and coalescence can result from solid reaction induced by thermal energy during sputtering.
3.2. Electrical Properties
The electrical properties, carrier concentration, mobility, and electrical resistivity of the GAZO films deposited at RT, 100°C, 200°C, and 250°C, are shown in Figures 3(a) and 3(b). The carrier concentration and mobility increase, while the electrical resistivity decreases with deposition temperature observed from Figures 3(a) and 3(b). The electrical resistivity of the GAZO films decreases from 1.5 × 10−3 Ω cm when films were deposited at RT and then decreases to 4.3 × 10−4 Ω cm when deposited at 250°C. Thermal energy supplied by heating substrate during sputtering results in more substitution from Zn to Al or Ga atoms in ZnO crystal lattice so as to increase the carrier concentration. Comparison of the lowest electric resistivity for GAZO films reported recently was shown in Table 2. The lowest electric resistivity reported in this work demonstrates the lowest one for GAZO films deposited by sputtering listed in Table 2. In addition, this work uses one target with GAZO in composition instead of two targets of GZO and AZO to produce GAZO films. Comparing deposition methods in Table 2, in-line sputtering used in this work is simple, with high throughput, and ready for large-area deposition.
3.3. Optical Properties
Figure 4 presents the optical transmittance spectra of the GAZO films deposited at RT, 100°C, 200°C, and 250°C. Blue shift of the optical transmittance spectra with rising deposition temperature is clearly observed in inset of Figure 4, which can be attributed to Burstein-Moss effect [25, 26]. The increase of the carrier concentration of the GAZO films with deposition temperature is mentioned in Section 3.2. The increase of carrier concentration widens the optical band gap of GAZO films. The average optical transmittance in the visible range from 400 to 800 nm of the GAZO films deposited at RT, 100°C, 200°C, and 250°C was calculated and listed in Table 3. The average optical transmittance of the GAZO films increases with deposition temperature. The average optical transmittance of the GAZO films increases from 75% to 92% when the deposition temperature of films was increased from RT to 250°C. This phenomenon is caused by the reduction of materials defects at high deposition temperature. The thermal energy was provided by heating substrate during sputtering. The grains of GAZO films grow and crystallinity of GAZO films improves with deposition temperature observed from the results of SEM and XRD mentioned in Section 3.1, suggesting the number of materials defects in GAZO films decreases with deposition temperature. The average optical transmittance of GAZO films is therefore increased due to the reduction of materials defects in GAZO films. Comparison of the highest average optical transmittance in visible wavelength region for GAZO films reported recently was also collected in Table 2. The highest average optical transmittance in the visible region reported in this work demonstrates the highest one in Table 2.
3.4. Device Fabrication of Organic Solar Cells
The GAZO films deposited at 250°C possess good electrical and optical properties: the electrical resistivity of 4.3 × 10−4 Ω cm and the average optical transmittance in visible region of 92%. The hybrid OSC were fabricated on GAZO-coated glass substrates on which the GAZO films were deposited at 250°C. The device structure of the produced OSC is shown in Figure 5. Calcium was inserted to improve the fill factor and the open-circuit voltage . The organic layer of anhydrous molecular residues must be cared for because calcium oxidizes if it is exposed to oxygen and moisture . The current density-voltage characteristics of the fabricated OSC with the 250°C deposited GAZO electrode were measured under an illumination intensity of 100 W/cm2 as shown in Figure 6. The power conversion efficiency of the fabricated OSC with the GAZO electrode is 0.65%. The power conversion efficiency of OSC with the 250°C deposited GAZO electrode may improve with inverse structure in OSC where GAZO was used as the electron-collecting cathode [16, 20, 21].
The GAZO films were deposited by in-line sputtering. Structural, electrical, and optical properties of the GAZO films deposited at RT, 100°C, 200°C, and 250°C were investigated. The deposition temperature shows positive influence on crystallinity and electrical and optical properties. The electric resistivity and average optical transmittance in the visible range from 400 to 800 nm are 1.3 × 10−3 Ω cm and 75%, respectively, for the GAZO films deposited at RT. They can improve to 4.3 × 10−4 Ω cm and 92%, respectively, for the GAZO films deposited at 250°C. In-line sputtering presents a simple, mass-production, and large-area deposition method to produce both good electrical and optical properties of GAZO films reported recently. The P3HT:PCBM based OSC with the 250°C deposited GAZO electrode were fabricated. The power conversion efficiency of the produced OSC is 0.65%.
Conflict of Interests
The author declares that there is no conflict of interests regarding the publication of this paper.
The author would like to thank the National Science Council of Taiwan for partial financial support (NSC 102-2221-E-168-037-), Bay Zu Precision Corporation for providing in-line sputtering tool, and Kuang-Jung Wu for carrying out part of measurements.
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