Research Article
Determination of Free Amino Acids in Three Species of Duckweed (Lemnaceae)
Table 5
Contents of 24 free amino acids, total amino acids, total proteins (μg/g), and ratio of free to total amino acids (%) in three species of duckweed.
| Sample | Tyr | Ala | Glu | Phe | His | Ile | Asp | Lys | Gly | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio |
| SP1 | 3.16 | 6259.48 | 0.0505 | 6.95 | 10680.18 | 0.0651 | 25.27 | 16774.31 | 0.1506 | 0.44 | 9597.56 | 0.0046 | 1.52 | 4255.26 | 0.0357 | 0.38 | 8532.07 | 0.0045 | 9.31 | 11169.49 | 0.0834 | 11.95 | 7164.09 | 0.1668 | 3.33 | 8764.89 | 0.0380 | SP2 | 6.73 | 6161.25 | 0.1092 | 65.17 | 10089.59 | 0.6459 | 54.61 | 25366.04 | 0.2153 | 0.95 | 10729.73 | 0.0089 | 4.43 | 3888.26 | 0.1139 | 1.35 | 10094.12 | 0.0134 | 56.68 | 15862.58 | 0.3573 | 21.28 | 10090.45 | 0.2109 | 8.38 | 8695.46 | 0.0964 | SP3 | 39.72 | 6115.87 | 0.6495 | 173.11 | 9881.22 | 1.7519 | 96.43 | 15463.41 | 0.6236 | 7.97 | 8667.06 | 0.0920 | 22.26 | 3824.22 | 0.5821 | 11.90 | 7226.86 | 0.1647 | 69.12 | 12387.34 | 0.5580 | 112.90 | 8153.11 | 1.3847 | 128.27 | 6293.65 | 2.0381 | SP4 | 29.21 | 6251.45 | 0.4673 | 157.69 | 12424.62 | 1.2692 | 49.52 | 22986.51 | 0.2154 | 5.01 | 10467.29 | 0.0479 | 32.80 | 3569.79 | 0.9188 | 11.14 | 8392.28 | 0.1327 | 170.28 | 17175.49 | 0.9914 | 137.48 | 10225.20 | 1.3445 | 78.17 | 9626.14 | 0.8121 | SP5 | 5.58 | 6257.00 | 0.0892 | 29.04 | 13866.45 | 0.2094 | 34.93 | 23518.46 | 0.1485 | 0.86 | 11427.08 | 0.0075 | 6.41 | 4312.95 | 0.1486 | 0.96 | 9753.24 | 0.0098 | 16.39 | 18654.70 | 0.0879 | 21.25 | 11094.76 | 0.1915 | 5.53 | 10174.01 | 0.0544 | SP6 | 27.42 | 6245.68 | 0.4390 | 273.35 | 12005.84 | 2.2768 | 49.09 | 18787.83 | 0.2613 | 2.55 | 10284.72 | 0.0248 | 45.46 | 3424.75 | 1.3274 | 13.55 | 8465.53 | 0.1601 | 132.84 | 15752.94 | 0.8433 | 139.27 | 8608.52 | 1.6178 | 77.36 | 7010.22 | 1.1035 | SP7 | 39.61 | 5884.11 | 0.6732 | 229.20 | 12123.87 | 1.8905 | 71.86 | 18146.81 | 0.3960 | 4.90 | 8585.01 | 0.0571 | 46.17 | 4088.80 | 1.1292 | 11.22 | 7231.96 | 0.1551 | 94.84 | 14833.85 | 0.6393 | 230.52 | 7636.34 | 3.0187 | 65.35 | 5417.04 | 1.2064 | SP8 | 5.71 | 6124.81 | 0.0932 | 38.00 | 9734.57 | 0.3904 | 53.14 | 17640.33 | 0.3012 | 1.17 | 8527.84 | 0.0137 | 4.56 | 3751.52 | 0.1216 | 1.40 | 7266.84 | 0.0193 | 42.82 | 14315.75 | 0.2991 | 22.77 | 7392.06 | 0.3080 | 5.63 | 7832.50 | 0.0719 | SP9 | 13.90 | 6054.66 | 0.2296 | 120.58 | 9953.18 | 1.2115 | 70.75 | 16620.79 | 0.4257 | 3.68 | 8384.54 | 0.0439 | 18.01 | 3496.99 | 0.5150 | 5.25 | 6745.54 | 0.0778 | 94.10 | 11606.55 | 0.8107 | 73.99 | 6323.41 | 1.1701 | 21.63 | 7899.86 | 0.2738 | SP10 | 16.70 | 6097.17 | 0.2739 | 118.61 | 13272.16 | 0.8937 | 74.72 | 25451.33 | 0.2936 | 3.72 | 11056.99 | 0.0336 | 28.19 | 4110.01 | 0.6859 | 4.41 | 9671.14 | 0.0456 | 36.11 | 17757.11 | 0.2034 | 70.81 | 8546.75 | 0.8285 | 25.55 | 7505.72 | 0.3404 | SP11 | 23.10 | 6004.10 | 0.3847 | 205.08 | 11155.38 | 1.8384 | 67.31 | 26088.53 | 0.2580 | 10.26 | 9883.88 | 0.1038 | 61.35 | 3238.60 | 1.8943 | 14.23 | 8891.25 | 0.1600 | 56.14 | 15601.46 | 0.3598 | 133.66 | 8386.70 | 1.5937 | 87.43 | 9088.41 | 0.9620 | SP12 | 9.38 | 6127.68 | 0.1531 | 93.06 | 9760.92 | 0.9534 | 51.58 | 26516.14 | 0.1945 | 7.60 | 7997.37 | 0.0950 | 31.87 | 3300.60 | 0.9656 | 4.09 | 9260.26 | 0.0442 | 225.20 | 12413.46 | 1.8142 | 74.86 | 5684.24 | 1.3170 | 24.76 | 6908.86 | 0.3584 | SP13 | 93.61 | 6130.06 | 1.5271 | 195.69 | 8956.55 | 2.1849 | 52.85 | 16377.44 | 0.3227 | 23.33 | 7668.17 | 0.3042 | 46.78 | 2889.26 | 1.6191 | 14.85 | 7650.07 | 0.1941 | 4.76 | 10136.24 | 0.0470 | 135.91 | 6635.82 | 2.0481 | 73.19 | 5663.18 | 1.2924 | SP14 | 19.98 | 6120.49 | 0.3264 | 161.86 | 13337.15 | 1.2136 | 96.09 | 15114.77 | 0.6357 | 5.94 | 10678.41 | 0.0556 | 26.03 | 4189.64 | 0.6213 | 6.56 | 9933.71 | 0.0660 | 29.20 | 13225.32 | 0.2208 | 102.55 | 11141.92 | 0.9204 | 34.50 | 7778.37 | 0.4435 | SP15 | 1.13 | 6057.44 | 0.0187 | 19.99 | 13617.28 | 0.1468 | 17.01 | 21045.25 | 0.0808 | 0.62 | 11056.19 | 0.0056 | 9.77 | 4213.32 | 0.2319 | 0.30 | 8452.34 | 0.0035 | 0.95 | 12630.34 | 0.0075 | 17.70 | 8018.34 | 0.2207 | 6.64 | 6872.17 | 0.0966 | SP16 | 61.29 | 5884.22 | 1.0416 | 280.92 | 12551.36 | 2.2382 | 46.82 | 20775.77 | 0.2254 | 19.27 | 10311.88 | 0.1869 | 54.60 | 3881.89 | 1.4065 | 20.18 | 9290.92 | 0.2172 | 112.81 | 13791.37 | 0.8180 | 158.24 | 7293.79 | 2.1695 | 52.41 | 8307.13 | 0.6309 | SP17 | 0.89 | 5938.26 | 0.0150 | 23.96 | 10170.30 | 0.2356 | 46.90 | 15656.17 | 0.2996 | 0.42 | 10562.87 | 0.0040 | 2.49 | 5358.17 | 0.0465 | 1.11 | 10201.54 | 0.0109 | 2.95 | 12263.36 | 0.0241 | 13.08 | 8069.24 | 0.1621 | 4.44 | 5669.36 | 0.0783 | SP18 | 12.28 | 5985.32 | 0.2052 | 157.75 | 13673.70 | 1.1537 | 81.27 | 15272.53 | 0.5321 | 15.58 | 10449.06 | 0.1491 | 28.93 | 4949.42 | 0.5845 | 10.04 | 9948.89 | 0.1009 | 85.38 | 20641.51 | 0.4136 | 79.39 | 11463.15 | 0.6926 | 29.19 | 6848.95 | 0.4262 | SP19 | 45.66 | 5897.55 | 0.7742 | 182.98 | 12217.80 | 1.4977 | 87.43 | 20888.93 | 0.4185 | 28.84 | 10128.19 | 0.2847 | 48.02 | 4231.77 | 1.1347 | 20.85 | 9161.44 | 0.2276 | 10.22 | 14574.99 | 0.0701 | 83.12 | 9060.52 | 0.9174 | 34.17 | 6664.53 | 0.5127 | SP20 | 28.03 | 5860.01 | 0.4783 | 241.91 | 9302.34 | 2.6005 | 46.17 | 14837.19 | 0.3112 | 23.18 | 7603.97 | 0.3048 | 64.10 | 3206.91 | 1.9988 | 14.80 | 6774.94 | 0.2185 | 109.03 | 11544.71 | 0.9444 | 164.87 | 6737.28 | 2.4471 | 73.15 | 6715.81 | 1.0892 | SP21 | 2.75 | 6264.80 | 0.0439 | 55.55 | 10989.25 | 0.5055 | 91.79 | 22493.65 | 0.4081 | 0.84 | 9615.10 | 0.0087 | 23.80 | 4257.07 | 0.5591 | 1.00 | 8364.75 | 0.0120 | — | 11442.81 | — | 31.30 | 6932.76 | 0.4515 | 9.46 | 6910.06 | 0.1369 | SP22 | 7.95 | 5839.15 | 0.1361 | 29.20 | 10343.17 | 0.2823 | 22.86 | 16692.99 | 0.1369 | 1.07 | 8957.29 | 0.0119 | 5.17 | 3585.28 | 0.1442 | 1.06 | 8011.79 | 0.0132 | 0.91 | 13590.39 | 0.0067 | 15.15 | 6361.56 | 0.2381 | 11.21 | 7059.65 | 0.1588 | SP23 | 6.86 | 6265.35 | 0.1095 | 68.62 | 11510.74 | 0.5961 | 100.28 | 20064.52 | 0.4998 | 2.53 | 9584.25 | 0.0264 | 32.22 | 3573.51 | 0.9016 | 1.84 | 7753.50 | 0.0237 | 33.31 | 15126.56 | 0.2202 | 42.69 | 7622.22 | 0.5601 | 11.21 | 8763.05 | 0.1279 | SP24 | 2.86 | 6318.22 | 0.0453 | 121.06 | 11508.52 | 1.0519 | 133.69 | 16946.16 | 0.7889 | 1.99 | 9477.13 | 0.0210 | 25.81 | 4474.44 | 0.5768 | 2.27 | 7926.91 | 0.0286 | 47.91 | 15776.45 | 0.3037 | 30.02 | 7939.55 | 0.3781 | 10.04 | 8867.42 | 0.1132 | SP25 | 43.24 | 5967.19 | 0.7246 | 261.74 | 11024.75 | 2.3741 | 53.23 | 21609.69 | 0.2463 | 16.89 | 9293.80 | 0.1817 | 64.22 | 4222.87 | 1.5208 | 20.92 | 9560.51 | 0.2188 | 162.59 | 18624.39 | 0.8730 | 209.44 | 7299.84 | 2.8691 | 63.50 | 7917.96 | 0.8020 | LP1 | 15.93 | 5971.26 | 0.2668 | 66.50 | 12151.90 | 0.5472 | 30.75 | 24958.79 | 0.1232 | 11.80 | 10826.10 | 0.1090 | 35.08 | 4061.19 | 0.8638 | 4.88 | 9319.60 | 0.0524 | 108.30 | 14896.35 | 0.7270 | 47.16 | 8613.79 | 0.5475 | 14.76 | 9583.97 | 0.1540 | LP2 | 38.97 | 5921.55 | 0.6581 | 140.81 | 11584.07 | 1.2155 | 63.83 | 21969.13 | 0.2905 | 15.15 | 9814.43 | 0.1544 | 30.41 | 4647.49 | 0.6543 | 2.61 | 8750.97 | 0.0298 | 59.96 | 16728.80 | 0.3584 | 134.72 | 7842.84 | 1.7177 | 30.64 | 6109.14 | 0.5015 | LP3 | 10.25 | 6287.19 | 0.1630 | 65.63 | 11013.29 | 0.5959 | 55.16 | 18366.66 | 0.3003 | 2.58 | 10992.07 | 0.0235 | 16.14 | 3302.54 | 0.4887 | 0.65 | 8567.75 | 0.0076 | 28.45 | 14101.74 | 0.2017 | 40.15 | 6593.31 | 0.6090 | 7.10 | 4632.59 | 0.1533 | LP4 | 47.76 | 6004.07 | 0.7955 | 180.48 | 11148.05 | 1.6189 | 83.06 | 18093.89 | 0.4590 | 7.65 | 9312.27 | 0.0821 | 48.49 | 3515.42 | 1.3794 | 9.18 | 8187.52 | 0.1121 | 103.28 | 15513.40 | 0.6657 | 94.68 | 8007.43 | 1.1824 | 74.60 | 8640.35 | 0.8634 | LP5 | 74.45 | 6011.02 | 1.2386 | 318.14 | 9785.11 | 3.2513 | 50.05 | 16830.48 | 0.2974 | 17.43 | 8490.88 | 0.2053 | 38.14 | 3571.09 | 1.0680 | 11.66 | 7900.11 | 0.1476 | 218.70 | 13106.01 | 1.6687 | 129.60 | 8308.91 | 1.5598 | 44.93 | 5574.15 | 0.8060 | LP6 | 22.44 | 6404.35 | 0.3504 | 187.93 | 9320.51 | 2.0163 | 51.11 | 19093.97 | 0.2677 | 10.76 | 10746.47 | 0.1001 | 17.66 | 4145.39 | 0.4260 | 4.29 | 8189.38 | 0.0524 | 137.49 | 13879.01 | 0.9906 | 57.61 | 6486.39 | 0.8882 | 13.94 | 6180.53 | 0.2255 | LP7 | 17.40 | 6413.54 | 0.2713 | 167.19 | 10950.61 | 1.5268 | 73.42 | 20616.00 | 0.3561 | 10.75 | 9606.73 | 0.1119 | 20.94 | 3464.43 | 0.6044 | 2.23 | 8717.93 | 0.0256 | 207.21 | 15567.27 | 1.3311 | 51.72 | 8761.56 | 0.5903 | 14.60 | 6213.59 | 0.2350 | LP8 | 35.02 | 6285.44 | 0.5572 | 139.27 | 11569.10 | 1.2038 | 72.38 | 18381.09 | 0.3938 | 18.51 | 10138.80 | 0.1826 | 28.90 | 4434.85 | 0.6517 | 7.46 | 9558.72 | 0.0780 | 73.30 | 15357.08 | 0.4773 | 78.65 | 7886.32 | 0.9973 | 24.80 | 8792.99 | 0.2820 | LP9 | 41.17 | 5951.60 | 0.6917 | 149.55 | 11075.37 | 1.3503 | 48.55 | 22021.01 | 0.2205 | 9.10 | 11619.61 | 0.0783 | 52.62 | 3058.17 | 1.7206 | 12.36 | 8587.29 | 0.1439 | 182.44 | 15444.00 | 1.1813 | 202.10 | 10583.78 | 1.9095 | 176.76 | 6207.16 | 2.8477 | LP10 | 23.74 | 6012.91 | 0.3948 | 187.15 | 10077.16 | 1.8572 | 57.20 | 22847.31 | 0.2504 | 3.20 | 10674.83 | 0.0300 | 11.62 | 3881.87 | 0.2993 | 6.47 | 10514.94 | 0.0615 | 48.04 | 19845.70 | 0.2421 | 111.09 | 8283.89 | 1.3410 | 107.73 | 7557.95 | 1.4254 | LP11 | 14.86 | 6110.90 | 0.2432 | 94.14 | 9256.17 | 1.0171 | 16.70 | 26967.52 | 0.0619 | 5.60 | 7780.40 | 0.0720 | 7.52 | 3541.02 | 0.2124 | 3.81 | 7300.09 | 0.0522 | 6.45 | 13678.56 | 0.0472 | 75.66 | 7596.11 | 0.9960 | 46.74 | 6276.56 | 0.7447 | LP12 | 8.06 | 6259.52 | 0.1288 | 25.80 | 10729.35 | 0.2405 | 11.61 | 28848.73 | 0.0402 | 1.45 | 9609.21 | 0.0151 | 4.31 | 4095.51 | 0.1052 | 0.93 | 8635.84 | 0.0108 | 2.44 | 11847.35 | 0.0206 | 29.23 | 8736.23 | 0.3346 | 7.00 | 7434.59 | 0.0942 | LP13 | 33.36 | 6270.49 | 0.5320 | 274.21 | 10059.65 | 2.7258 | 85.36 | 26195.21 | 0.3259 | 5.22 | 11114.42 | 0.0470 | 44.10 | 3500.71 | 1.2597 | 8.74 | 9771.06 | 0.0894 | 78.86 | 17064.92 | 0.4621 | 148.06 | 8026.46 | 1.8446 | 92.39 | 7807.71 | 1.1833 | LP14 | 29.35 | 6070.40 | 0.4835 | 160.58 | 13818.32 | 1.1621 | 57.00 | 27399.97 | 0.2080 | 5.18 | 12682.81 | 0.0408 | 38.41 | 5535.27 | 0.6939 | 9.59 | 11826.29 | 0.0811 | 139.52 | 14718.19 | 0.9479 | 158.90 | 7779.67 | 2.0425 | 85.79 | 7101.48 | 1.2081 | LP15 | 14.08 | 6310.67 | 0.2231 | 108.54 | 12226.01 | 0.8878 | 11.43 | 20415.24 | 0.0560 | 4.29 | 10235.21 | 0.0419 | 6.83 | 4786.65 | 0.1427 | 3.49 | 10163.51 | 0.0343 | 4.42 | 16813.25 | 0.0263 | 70.82 | 8454.76 | 0.8376 | 57.87 | 8826.59 | 0.6556 | LP16 | 38.10 | 6308.99 | 0.6039 | 224.42 | 10920.13 | 2.0551 | 58.19 | 18915.27 | 0.3076 | 12.98 | 9252.57 | 0.1403 | 25.58 | 3501.54 | 0.7305 | 6.06 | 8361.97 | 0.0725 | 187.80 | 14243.86 | 1.3185 | 79.64 | 8381.28 | 0.9502 | 24.49 | 7349.44 | 0.3332 | LA1 | 39.53 | 5844.15 | 0.6764 | 153.40 | 11080.16 | 1.3845 | 53.94 | 17900.19 | 0.3013 | 5.26 | 8940.22 | 0.0588 | 38.98 | 3436.65 | 1.1342 | 10.44 | 7739.17 | 0.1349 | 92.27 | 11396.06 | 0.8097 | 116.20 | 8514.88 | 1.3647 | 16.63 | 8366.72 | 0.1988 | LA2 | 7.06 | 6163.58 | 0.1145 | 110.58 | 11359.90 | 0.9734 | 38.25 | 21707.93 | 0.1762 | 8.65 | 9105.55 | 0.0950 | 45.78 | 3419.43 | 1.3388 | 10.95 | 9140.90 | 0.1198 | 84.67 | 16077.78 | 0.5266 | 87.09 | 8669.05 | 1.0046 | 14.22 | 7375.81 | 0.1928 | LA3 | 49.51 | 6127.32 | 0.8080 | 189.37 | 10480.08 | 1.8070 | 47.31 | 23969.23 | 0.1974 | 23.46 | 8251.42 | 0.2843 | 73.17 | 3213.54 | 2.2769 | 30.13 | 8053.11 | 0.3741 | 190.71 | 18067.61 | 1.0555 | 206.67 | 10157.90 | 2.0346 | 118.69 | 11012.41 | 1.0778 | LA4 | 9.45 | 6231.43 | 0.1517 | 101.15 | 10764.28 | 0.9397 | 43.93 | 18445.78 | 0.2382 | 6.83 | 9106.47 | 0.0750 | 5.48 | 3968.13 | 0.1381 | 2.07 | 7183.48 | 0.0288 | 14.98 | 11095.78 | 0.1350 | 44.31 | 8400.33 | 0.5275 | 18.02 | 5093.33 | 0.3538 | LA5 | 8.21 | 6468.09 | 0.1269 | 101.70 | 10782.93 | 0.9432 | 49.41 | 17857.46 | 0.2767 | 4.67 | 9378.50 | 0.0498 | 27.88 | 4320.50 | 0.6453 | 7.67 | 8732.91 | 0.0878 | 245.22 | 11348.94 | 2.1607 | 101.42 | 9642.82 | 1.0518 | 59.10 | 7589.10 | 0.7787 | LA6 | 95.03 | 6441.94 | 1.4752 | 53.56 | 10969.89 | 0.4882 | 45.63 | 19113.36 | 0.2387 | 34.05 | 8826.04 | 0.3858 | 22.67 | 3432.16 | 0.6605 | 15.73 | 7873.91 | 0.1998 | 194.49 | 13395.53 | 1.4519 | 203.37 | 9453.82 | 2.1512 | 165.17 | 5220.68 | 3.1638 | LA7 | 43.57 | 6390.61 | 0.6818 | 136.48 | 9697.57 | 1.4074 | 44.59 | 17227.16 | 0.2588 | 26.85 | 10617.54 | 0.2529 | 53.25 | 3342.84 | 1.5930 | 8.20 | 8078.65 | 0.1015 | 99.41 | 13308.10 | 0.7470 | 156.91 | 8444.81 | 1.8581 | 124.79 | 6172.25 | 2.0218 | LA8 | 25.51 | 5969.99 | 0.4273 | 159.29 | 9551.72 | 1.6677 | 21.69 | 22493.72 | 0.0964 | 7.29 | 12500.69 | 0.0583 | 28.21 | 5068.31 | 0.5566 | 12.52 | 10500.36 | 0.1192 | 2.23 | 19936.15 | 0.0112 | 66.00 | 11282.00 | 0.5850 | 75.19 | 11732.39 | 0.6409 | LA9 | 3.26 | 6188.23 | 0.0527 | 19.10 | 14974.86 | 0.1275 | 71.65 | 23929.16 | 0.2994 | 0.84 | 12303.21 | 0.0068 | 3.65 | 4847.99 | 0.0753 | 0.36 | 10895.91 | 0.0033 | 2.47 | 21371.14 | 0.0116 | 18.43 | 10548.00 | 0.1747 | 7.33 | 7698.82 | 0.0952 | LA10 | 29.15 | 5884.38 | 0.4954 | 95.43 | 11229.43 | 0.8498 | 89.66 | 20489.06 | 0.4376 | 16.96 | 9051.65 | 0.1874 | 21.61 | 3412.09 | 0.6333 | 16.06 | 8721.17 | 0.1841 | 2.82 | 17303.92 | 0.0163 | 74.14 | 8057.43 | 0.9201 | 27.50 | 5058.68 | 0.5436 | LA11 | 10.88 | 6259.53 | 0.1738 | 40.56 | 13131.47 | 0.3089 | 121.99 | 22020.10 | 0.5540 | 2.48 | 10555.63 | 0.0235 | 5.92 | 4847.60 | 0.1221 | 0.48 | 9784.56 | 0.0049 | 7.09 | 16593.97 | 0.0427 | 26.86 | 7655.07 | 0.3509 | 7.73 | 7284.80 | 0.1061 | LA12 | 48.02 | 6403.75 | 0.7499 | 149.63 | 9735.88 | 1.5369 | 62.74 | 14671.39 | 0.4276 | 20.20 | 8380.51 | 0.2410 | 56.05 | 3384.94 | 1.6559 | 5.41 | 6896.77 | 0.0784 | 91.38 | 11321.11 | 0.8072 | 109.18 | 5802.35 | 1.8817 | 46.13 | 7209.85 | 0.6398 | LA13 | 22.08 | 5983.25 | 0.3690 | 77.34 | 12359.55 | 0.6258 | 49.89 | 24426.48 | 0.2042 | 13.64 | 10650.97 | 0.1281 | 31.43 | 4286.46 | 0.7332 | 3.68 | 8877.22 | 0.0415 | 184.36 | 14885.17 | 1.2385 | 77.19 | 10677.05 | 0.7230 | 23.24 | 10012.96 | 0.2321 | LA14 | 29.06 | 6197.60 | 0.4689 | 219.41 | 12097.18 | 1.8137 | 68.78 | 22967.64 | 0.2995 | 7.41 | 10651.10 | 0.0696 | 33.00 | 4079.19 | 0.8090 | 10.50 | 8376.22 | 0.1254 | 21.77 | 16404.09 | 0.1327 | 122.70 | 8502.69 | 1.4431 | 92.02 | 9152.03 | 1.0055 | LA15 | 28.90 | 6409.17 | 0.4509 | 11.61 | 12035.67 | 0.0965 | 43.15 | 25371.86 | 0.1701 | 5.48 | 11118.01 | 0.0493 | 35.81 | 3597.27 | 0.9955 | 6.72 | 6464.97 | 0.1039 | 159.51 | 12763.92 | 1.2497 | 120.12 | 7008.78 | 1.7139 | 55.67 | 5676.13 | 0.9808 | LA16 | 20.91 | 6243.38 | 0.3349 | 95.37 | 11719.51 | 0.8138 | 41.47 | 21759.15 | 0.1906 | 2.48 | 11669.90 | 0.0213 | 27.93 | 5249.47 | 0.5321 | 5.48 | 10752.39 | 0.0510 | 113.55 | 14828.06 | 0.7658 | 123.52 | 9586.25 | 1.2885 | 34.37 | 10915.62 | 0.3149 | LA17 | 33.89 | 6029.51 | 0.5621 | 12.57 | 12627.27 | 0.0995 | 65.10 | 23746.45 | 0.2741 | 13.69 | 10538.29 | 0.1299 | 34.97 | 4468.75 | 0.7825 | 7.61 | 9975.36 | 0.0763 | 117.69 | 13313.53 | 0.8840 | 122.84 | 9248.08 | 1.3283 | 36.44 | 8620.93 | 0.4227 | LA18 | 29.56 | 6046.27 | 0.4889 | 137.19 | 10245.05 | 1.3391 | 54.86 | 18325.38 | 0.2994 | 10.74 | 8928.25 | 0.1203 | 48.27 | 3846.06 | 1.2551 | 6.44 | 7467.00 | 0.0862 | 91.91 | 12882.36 | 0.7135 | 125.43 | 7366.73 | 1.7027 | 36.87 | 4820.33 | 0.7649 |
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| Sample | Val | Cit | GABA | Cys2 | Pro | Trp | Leu | Arg | Cys | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio |
| SP1 | 4.42 | 6012.65 | 0.0735 | 2.49 | 4673.88 | 0.0533 | 3.46 | 3353.11 | 0.1032 | — | 11525.08 | — | 4.15 | 6607.74 | 0.0628 | 0.24 | 3637.74 | 0.0066 | 1.37 | 12211.14 | 0.0112 | 34.88 | 9489.73 | 0.3676 | — | 5538.05 | — | SP2 | 15.20 | 10648.71 | 0.1427 | 6.07 | 3955.21 | 0.1535 | 21.27 | 4028.12 | 0.5280 | — | 13123.45 | — | 12.90 | 6341.28 | 0.2034 | 0.51 | 6868.79 | 0.0074 | 4.08 | 11230.44 | 0.0363 | 87.38 | 8979.88 | 0.9731 | — | 8675.28 | — | SP3 | 15.36 | 6327.29 | 0.2428 | 24.59 | 4218.39 | 0.5829 | 83.54 | 2906.04 | 2.8747 | 0.67 | 9520.68 | 0.0070 | 27.55 | 7911.24 | 0.3482 | 2.67 | 6256.52 | 0.0427 | 33.86 | 9531.17 | 0.3553 | 68.39 | 8667.37 | 0.7891 | — | 3752.42 | — | SP4 | 16.09 | 10136.97 | 0.1587 | 9.45 | 4525.17 | 0.2088 | 112.07 | 1860.38 | 6.0240 | 0.71 | 8713.26 | 0.0081 | 22.64 | 9816.87 | 0.2306 | 3.14 | 6886.81 | 0.0456 | 25.37 | 11900.95 | 0.2132 | 41.42 | 7830.13 | 0.5290 | — | 5020.00 | — | SP5 | 12.81 | 12270.45 | 0.1044 | 3.68 | 5960.38 | 0.0617 | 9.31 | 2163.00 | 0.4304 | — | 11194.54 | — | 5.92 | 8973.82 | 0.0660 | 0.39 | 6741.47 | 0.0058 | 3.03 | 17710.97 | 0.0171 | 75.96 | 11624.78 | 0.6534 | — | 8152.58 | — | SP6 | 18.63 | 6921.90 | 0.2691 | 54.08 | 6475.87 | 0.8351 | 110.08 | 2010.87 | 5.4742 | 0.26 | 9803.15 | 0.0027 | 28.19 | 7126.12 | 0.3956 | 4.73 | 3570.11 | 0.1325 | 26.75 | 15586.82 | 0.1716 | 43.86 | 5689.69 | 0.7709 | — | 3789.97 | — | SP7 | 17.07 | 9259.39 | 0.1844 | 29.75 | 4140.35 | 0.7185 | 103.95 | 2825.91 | 3.6785 | 2.41 | 9778.44 | 0.0246 | 24.62 | 8226.72 | 0.2993 | 3.95 | 4856.66 | 0.0813 | 27.66 | 10861.08 | 0.2547 | 34.40 | 4988.56 | 0.6896 | — | 3471.13 | — | SP8 | 15.86 | 7296.00 | 0.2174 | 3.13 | 4702.29 | 0.0666 | 20.48 | 1682.03 | 1.2176 | — | 6139.57 | — | 10.52 | 6680.26 | 0.1575 | 0.56 | 4883.67 | 0.0115 | 4.38 | 9640.58 | 0.0454 | 64.28 | 4886.46 | 1.3155 | — | 3120.50 | — | SP9 | 37.20 | 6514.46 | 0.5710 | 10.18 | 5254.55 | 0.1937 | 57.02 | 2501.97 | 2.2790 | 0.14 | 10056.41 | 0.0014 | 15.77 | 5340.61 | 0.2953 | 1.20 | 4253.18 | 0.0282 | 14.42 | 11713.99 | 0.1231 | 124.64 | 5090.33 | 2.4486 | — | 3897.56 | — | SP10 | 38.29 | 9908.44 | 0.3864 | 13.50 | 7105.23 | 0.1900 | 57.85 | 1953.05 | 2.9620 | 0.26 | 10687.68 | 0.0024 | 19.03 | 7381.05 | 0.2578 | 1.17 | 7036.56 | 0.0166 | 13.77 | 14235.69 | 0.0967 | 108.51 | 4268.65 | 2.5420 | — | 8653.16 | — | SP11 | 21.90 | 10089.65 | 0.2171 | 8.30 | 5747.51 | 0.1444 | 108.20 | 3155.71 | 3.4287 | 0.79 | 9550.72 | 0.0083 | 24.66 | 5804.81 | 0.4248 | 1.94 | 7077.68 | 0.0274 | 26.89 | 14118.06 | 0.1905 | 67.72 | 5222.67 | 1.2967 | — | 6165.20 | — | SP12 | 36.91 | 5104.20 | 0.7231 | 31.74 | 3267.50 | 0.9714 | 56.19 | 3092.80 | 1.8168 | 0.58 | 8821.94 | 0.0066 | 11.01 | 6511.44 | 0.1691 | 2.35 | 4185.92 | 0.0561 | 10.46 | 8633.77 | 0.1212 | 99.42 | 6433.17 | 1.5454 | — | 2940.84 | — | SP13 | 27.76 | 5423.78 | 0.5118 | 27.14 | 3816.49 | 0.7111 | 82.12 | 2484.15 | 3.3058 | 0.99 | 6828.14 | 0.0145 | 22.06 | 7524.55 | 0.2932 | 11.42 | 3149.92 | 0.3625 | 31.25 | 8945.92 | 0.3493 | 73.82 | 5010.51 | 1.4733 | — | 6503.52 | — | SP14 | 44.12 | 10896.32 | 0.4049 | 11.57 | 6328.11 | 0.1828 | 70.23 | 4220.23 | 1.6641 | 0.28 | 9165.62 | 0.0031 | 21.63 | 8005.88 | 0.2702 | 2.44 | 4732.57 | 0.0516 | 18.29 | 13035.53 | 0.1403 | 65.62 | 6826.41 | 0.9613 | — | 8677.59 | — | SP15 | 6.17 | 7444.35 | 0.0829 | 5.45 | 3756.96 | 0.1451 | 4.23 | 3324.82 | 0.1272 | — | 10198.26 | — | 14.42 | 5416.47 | 0.2662 | — | 5143.26 | — | 1.80 | 14814.40 | 0.0122 | 30.19 | 5059.02 | 0.5968 | — | 6694.08 | — | SP16 | 26.04 | 6396.60 | 0.4071 | 36.82 | 3762.26 | 0.9787 | 134.46 | 3870.97 | 3.4735 | 0.72 | 8704.16 | 0.0083 | 27.10 | 7353.81 | 0.3685 | 15.39 | 7545.48 | 0.2040 | 30.79 | 12588.03 | 0.2446 | 43.32 | 6483.46 | 0.6682 | — | 4369.57 | — | SP17 | 9.24 | 8969.61 | 0.1030 | 4.12 | 3703.39 | 0.1112 | 2.34 | 3148.92 | 0.0743 | — | 8001.88 | — | 14.78 | 8403.61 | 0.1759 | — | 4014.56 | — | 5.35 | 10274.36 | 0.0521 | 9.96 | 4876.50 | 0.2042 | — | 6360.07 | — | SP18 | 26.19 | 12386.71 | 0.2114 | 26.35 | 5209.87 | 0.5058 | 98.88 | 3534.87 | 2.7973 | 0.12 | 12402.18 | 0.0010 | 17.21 | 9211.57 | 0.1868 | 2.08 | 7798.78 | 0.0267 | 22.77 | 17831.20 | 0.1277 | 108.35 | 4662.91 | 2.3237 | — | 7665.04 | — | SP19 | 25.16 | 8312.52 | 0.3027 | 8.51 | 4849.89 | 0.1755 | 73.42 | 1868.93 | 3.9285 | 0.28 | 8968.53 | 0.0031 | 17.64 | 8754.89 | 0.2015 | 3.68 | 5290.70 | 0.0696 | 16.70 | 11607.35 | 0.1439 | 80.47 | 7406.94 | 1.0864 | — | 7063.71 | — | SP20 | 25.85 | 8395.03 | 0.3079 | 17.22 | 4586.93 | 0.3754 | 131.28 | 2873.62 | 4.5685 | 0.40 | 8894.24 | 0.0045 | 18.50 | 4472.47 | 0.4136 | 9.86 | 3888.62 | 0.2536 | 24.40 | 8829.37 | 0.2764 | 42.54 | 4662.51 | 0.9124 | — | 4657.46 | — | SP21 | 11.27 | 5982.04 | 0.1884 | 24.90 | 4366.50 | 0.5703 | 10.82 | 3551.90 | 0.3046 | 0.24 | 8933.72 | 0.0027 | 28.86 | 6002.68 | 0.4808 | 0.15 | 6460.55 | 0.0023 | 3.89 | 12300.36 | 0.0316 | 55.98 | 5963.67 | 0.9387 | — | 5955.22 | — | SP22 | 10.06 | 9469.47 | 0.1062 | 5.09 | 5545.62 | 0.0918 | 1.90 | 1902.37 | 0.0999 | — | 10023.81 | — | 18.22 | 5611.46 | 0.3247 | 0.14 | 3261.78 | 0.0043 | 9.76 | 12591.58 | 0.0775 | 18.52 | 8217.10 | 0.2254 | — | 6884.34 | — | SP23 | 19.80 | 6941.68 | 0.2852 | 35.46 | 4560.09 | 0.7776 | 10.96 | 2519.87 | 0.4349 | 0.31 | 11078.52 | 0.0028 | 25.31 | 7474.12 | 0.3386 | 0.55 | 4776.94 | 0.0115 | 5.34 | 9323.61 | 0.0573 | 75.70 | 8379.33 | 0.9034 | — | 4296.33 | — | SP24 | 24.68 | 7991.34 | 0.3088 | 29.19 | 6319.28 | 0.4619 | 4.94 | 3668.10 | 0.1347 | 0.09 | 10178.72 | 0.0009 | 23.29 | 5293.61 | 0.4400 | 0.60 | 4551.39 | 0.0132 | 3.83 | 14205.93 | 0.0270 | 58.04 | 6170.55 | 0.9406 | — | 5644.77 | — | SP25 | 28.45 | 7459.65 | 0.3814 | 46.15 | 5088.78 | 0.9069 | 163.48 | 3897.18 | 4.1948 | 1.16 | 11215.85 | 0.0103 | 24.67 | 7584.57 | 0.3253 | 7.63 | 7080.31 | 0.1078 | 35.40 | 14162.74 | 0.2500 | 74.34 | 9656.72 | 0.7698 | — | 6166.09 | — | LP1 | 21.36 | 7244.74 | 0.2948 | 5.16 | 4405.39 | 0.1171 | 58.37 | 2407.83 | 2.4242 | 0.13 | 13065.90 | 0.0010 | 11.76 | 8651.28 | 0.1359 | 3.62 | 5123.83 | 0.0707 | 13.93 | 10764.87 | 0.1294 | 30.24 | 8884.37 | 0.3404 | — | 4324.94 | — | LP2 | 14.46 | 7373.76 | 0.1961 | 16.36 | 4874.65 | 0.3356 | 40.10 | 2138.03 | 1.8756 | 0.77 | 7988.91 | 0.0096 | 14.86 | 8851.40 | 0.1679 | 14.60 | 3817.53 | 0.3824 | 15.17 | 13357.73 | 0.1136 | 26.71 | 9701.11 | 0.2753 | — | 7977.29 | — | LP3 | 9.83 | 8734.76 | 0.1125 | 60.38 | 3744.80 | 1.6124 | 14.14 | 2099.63 | 0.6735 | — | 9725.45 | — | 18.43 | 4540.45 | 0.4059 | 0.45 | 4728.65 | 0.0095 | 3.52 | 9822.04 | 0.0358 | 74.16 | 5810.06 | 1.2764 | — | 3530.69 | — | LP4 | 35.80 | 9919.45 | 0.3609 | 3.79 | 3526.80 | 0.1075 | 122.04 | 2438.49 | 5.0047 | 0.37 | 9387.49 | 0.0039 | 18.34 | 8296.58 | 0.2211 | 1.14 | 5349.26 | 0.0213 | 22.21 | 9157.07 | 0.2425 | 48.84 | 8460.67 | 0.5773 | — | 6861.56 | — | LP5 | 35.99 | 8871.65 | 0.4057 | 11.90 | 4587.62 | 0.2594 | 133.05 | 3159.85 | 4.2106 | 4.21 | 7298.47 | 0.0577 | 25.23 | 5061.04 | 0.4985 | 4.34 | 5510.02 | 0.0788 | 31.89 | 11224.14 | 0.2841 | 45.88 | 6939.12 | 0.6612 | — | 3854.06 | — | LP6 | 24.78 | 7215.09 | 0.3434 | 9.73 | 4416.05 | 0.2203 | 91.48 | 2092.89 | 4.3710 | 2.32 | 7641.78 | 0.0304 | 14.71 | 6655.83 | 0.2210 | 5.76 | 3078.31 | 0.1871 | 13.10 | 10225.91 | 0.1281 | 77.03 | 6842.51 | 1.1258 | — | 3272.62 | — | LP7 | 18.41 | 6396.21 | 0.2878 | 10.84 | 4275.51 | 0.2535 | 64.21 | 2197.40 | 2.9221 | 4.25 | 11232.05 | 0.0378 | 9.15 | 8097.10 | 0.1130 | 4.71 | 3289.73 | 0.1432 | 11.93 | 9991.64 | 0.1194 | 30.66 | 7921.66 | 0.3870 | 0.14 | 6607.63 | 0.0021 | LP8 | 23.88 | 7401.70 | 0.3226 | 16.38 | 4758.26 | 0.3442 | 69.10 | 3565.33 | 1.9381 | 0.55 | 8739.92 | 0.0063 | 14.73 | 8982.82 | 0.1640 | 2.82 | 4541.13 | 0.0621 | 24.29 | 16149.82 | 0.1504 | 31.42 | 6643.33 | 0.4730 | — | 5673.14 | — | LP9 | 22.74 | 8090.74 | 0.2811 | 32.17 | 6784.16 | 0.4742 | 95.67 | 3874.88 | 2.4690 | 0.34 | 11756.40 | 0.0029 | 25.48 | 9895.35 | 0.2575 | 3.59 | 4755.18 | 0.0755 | 30.55 | 11213.15 | 0.2724 | 118.53 | 7876.17 | 1.5049 | 0.22 | 4743.85 | 0.0046 | LP10 | 44.70 | 10435.87 | 0.4283 | 15.47 | 3862.27 | 0.4005 | 82.77 | 2085.51 | 3.9688 | 0.95 | 13573.29 | 0.0070 | 21.56 | 8888.77 | 0.2426 | 0.77 | 7378.31 | 0.0104 | 16.31 | 14411.77 | 0.1132 | 63.57 | 9539.07 | 0.6664 | 0.14 | 8866.38 | 0.0016 | LP11 | 30.18 | 7118.23 | 0.4240 | 10.12 | 3840.01 | 0.2635 | 38.62 | 2188.18 | 1.7649 | 0.39 | 9579.85 | 0.0041 | 14.31 | 6477.73 | 0.2209 | 0.56 | 4389.22 | 0.0128 | 9.34 | 10905.75 | 0.0856 | 74.49 | 5696.30 | 1.3077 | — | 5334.87 | — | LP12 | 10.67 | 9073.21 | 0.1176 | 9.45 | 4795.94 | 0.1970 | 6.74 | 2798.07 | 0.2409 | — | 9754.10 | — | 10.14 | 5687.18 | 0.1783 | 0.22 | 6220.07 | 0.0035 | 2.99 | 11120.12 | 0.0269 | 89.48 | 9822.46 | 0.9110 | — | 7787.85 | — | LP13 | 24.43 | 7986.97 | 0.3059 | 10.20 | 5208.39 | 0.1958 | 105.99 | 3587.82 | 2.9542 | 1.19 | 10899.43 | 0.0109 | 25.32 | 9578.40 | 0.2643 | 2.01 | 6255.14 | 0.0321 | 24.85 | 10572.72 | 0.2350 | 76.46 | 7230.87 | 1.0574 | — | 8350.79 | — | LP14 | 21.85 | 12895.61 | 0.1694 | 10.61 | 6247.35 | 0.1698 | 114.88 | 3385.86 | 3.3929 | 0.65 | 12941.50 | 0.0050 | 24.21 | 10165.28 | 0.2382 | 0.42 | 5801.66 | 0.0072 | 24.35 | 12767.46 | 0.1907 | 38.76 | 9267.96 | 0.4182 | 0.10 | 4749.52 | 0.0021 | LP15 | 30.04 | 10600.31 | 0.2834 | 8.02 | 6112.10 | 0.1312 | 39.61 | 2063.22 | 1.9198 | 0.26 | 10874.29 | 0.0024 | 14.42 | 6109.32 | 0.2360 | 0.63 | 7137.55 | 0.0088 | 7.68 | 12394.41 | 0.0620 | 71.29 | 6514.00 | 1.0944 | — | 4351.01 | — | LP16 | 26.39 | 5728.98 | 0.4606 | 10.83 | 4203.58 | 0.2576 | 96.25 | 3176.63 | 3.0299 | 3.59 | 6782.15 | 0.0529 | 16.36 | 8733.17 | 0.1873 | 4.94 | 6147.21 | 0.0804 | 18.97 | 9376.15 | 0.2023 | 51.19 | 8498.90 | 0.6023 | 0.14 | 5213.83 | 0.0027 | LA1 | 45.00 | 5702.67 | 0.7891 | 13.87 | 3437.80 | 0.4035 | 97.36 | 3259.71 | 2.9868 | 0.34 | 9934.14 | 0.0034 | 16.88 | 5375.18 | 0.3140 | 5.39 | 5649.12 | 0.0954 | 25.80 | 11813.05 | 0.2184 | 46.47 | 7148.37 | 0.6501 | — | 6609.48 | — | LA2 | 19.62 | 10334.80 | 0.1898 | 28.58 | 3747.09 | 0.7627 | 81.64 | 2390.45 | 3.4153 | 0.86 | 7845.80 | 0.0110 | 12.38 | 8095.98 | 0.1529 | 2.57 | 5265.52 | 0.0488 | 23.74 | 15177.45 | 0.1564 | 33.03 | 7150.11 | 0.4620 | — | 5064.86 | — | LA3 | 39.08 | 11531.59 | 0.3389 | 11.17 | 7658.73 | 0.1458 | 96.78 | 3420.33 | 2.8296 | 0.34 | 9648.03 | 0.0035 | 25.22 | 6740.71 | 0.3741 | 14.39 | 6990.99 | 0.2058 | 28.29 | 16947.54 | 0.1669 | 35.87 | 11157.91 | 0.3215 | 0.12 | 5317.49 | 0.0023 | LA4 | 30.49 | 9094.55 | 0.3353 | 5.75 | 3337.54 | 0.1723 | 59.10 | 1960.88 | 3.0140 | — | 7030.26 | — | 21.76 | 7834.00 | 0.2778 | 1.38 | 6225.95 | 0.0222 | 12.30 | 8279.16 | 0.1486 | 67.99 | 6933.19 | 0.9806 | — | 5458.32 | — | LA5 | 41.41 | 10636.04 | 0.3893 | 53.62 | 5018.49 | 1.0684 | 47.11 | 3686.56 | 1.2779 | 1.53 | 7468.47 | 0.0205 | 28.74 | 6068.81 | 0.4736 | 1.29 | 4893.15 | 0.0264 | 22.91 | 11517.82 | 0.1989 | 104.70 | 5679.74 | 1.8434 | — | 6326.99 | — | LA6 | 26.86 | 10152.01 | 0.2646 | 10.02 | 5879.06 | 0.1704 | 109.90 | 3477.43 | 3.1604 | 0.66 | 10000.06 | 0.0066 | 23.06 | 5135.21 | 0.4491 | 7.12 | 3736.03 | 0.1906 | 33.26 | 15229.07 | 0.2184 | 38.54 | 6481.81 | 0.5946 | 0.24 | 5289.57 | 0.0045 | LA7 | 37.39 | 5299.21 | 0.7056 | 7.21 | 4582.47 | 0.1573 | 137.64 | 3164.85 | 4.3490 | — | 6820.33 | — | 25.78 | 4508.55 | 0.5718 | 2.81 | 5062.03 | 0.0555 | 30.16 | 14035.50 | 0.2149 | 37.11 | 8557.89 | 0.4336 | — | 6719.24 | — | LA8 | 33.07 | 10470.63 | 0.3158 | 14.37 | 6157.76 | 0.2334 | 26.46 | 2514.35 | 1.0524 | — | 12359.55 | — | 27.27 | 8147.42 | 0.3347 | 3.27 | 7846.61 | 0.0417 | 18.76 | 12842.68 | 0.1461 | 88.93 | 8060.89 | 1.1032 | — | 4516.77 | — | LA9 | 3.40 | 12345.60 | 0.0275 | 9.98 | 5675.92 | 0.1758 | 2.04 | 4742.21 | 0.0430 | — | 15127.20 | — | 6.76 | 10585.00 | 0.0639 | 0.29 | 8961.94 | 0.0032 | 1.34 | 12900.12 | 0.0104 | 13.42 | 10716.38 | 0.1252 | — | 5820.67 | — | LA10 | 32.37 | 8506.23 | 0.3805 | 15.12 | 4869.46 | 0.3105 | 40.05 | 3515.47 | 1.1393 | 0.11 | 11225.08 | 0.0010 | 15.86 | 4962.73 | 0.3196 | 1.40 | 6261.69 | 0.0224 | 8.88 | 9143.75 | 0.0971 | 86.86 | 5400.65 | 1.6083 | — | 7815.34 | — | LA11 | 5.06 | 11187.35 | 0.0452 | 16.69 | 6130.94 | 0.2722 | 2.35 | 2533.92 | 0.0927 | 0.36 | 13012.18 | 0.0028 | 5.43 | 10083.36 | 0.0539 | 0.97 | 5607.42 | 0.0173 | 1.87 | 15543.78 | 0.0120 | 7.40 | 7751.63 | 0.0955 | — | 4413.68 | — | LA12 | 38.36 | 6567.71 | 0.5841 | 37.15 | 4331.21 | 0.8577 | 73.93 | 1638.83 | 4.5111 | 0.13 | 10001.78 | 0.0013 | 19.64 | 5219.17 | 0.3763 | 1.98 | 3334.61 | 0.0594 | 16.66 | 13924.60 | 0.1196 | 43.90 | 4477.46 | 0.9805 | — | 3708.31 | — | LA13 | 33.49 | 9334.49 | 0.3588 | 21.25 | 5427.96 | 0.3915 | 57.89 | 3900.56 | 1.4841 | 0.15 | 11927.09 | 0.0013 | 18.94 | 7570.98 | 0.2502 | 1.52 | 3832.52 | 0.0397 | 14.66 | 14801.24 | 0.0990 | 130.27 | 9104.06 | 1.4309 | — | 4437.40 | — | LA14 | 48.22 | 9862.78 | 0.4889 | 10.25 | 5078.48 | 0.2018 | 68.84 | 1820.89 | 3.7806 | 0.18 | 12167.89 | 0.0015 | 20.49 | 9331.57 | 0.2196 | 3.12 | 6487.16 | 0.0481 | 27.88 | 15343.15 | 0.1817 | 73.66 | 5754.34 | 1.2801 | — | 4845.05 | — | LA15 | 33.62 | 4870.39 | 0.6903 | 38.52 | 4318.57 | 0.8920 | 46.08 | 2538.52 | 1.8152 | — | 8893.47 | — | 18.06 | 5895.62 | 0.3063 | 0.58 | 3366.22 | 0.0172 | 18.67 | 7744.33 | 0.2411 | 97.99 | 6807.78 | 1.4394 | 0.19 | 6361.27 | 0.0030 | LA16 | 28.73 | 10676.60 | 0.2691 | 17.16 | 5956.75 | 0.2881 | 30.34 | 4234.41 | 0.7165 | 0.10 | 10936.85 | 0.0009 | 20.90 | 7579.89 | 0.2757 | 1.06 | 6621.76 | 0.0160 | 17.03 | 15351.32 | 0.1109 | 39.65 | 7199.84 | 0.5507 | 0.16 | 4666.63 | 0.0034 | LA17 | 25.33 | 11534.16 | 0.2196 | 8.43 | 5093.69 | 0.1655 | 57.74 | 3692.35 | 1.5638 | 0.41 | 10297.60 | 0.0040 | 12.50 | 7491.18 | 0.1669 | 4.43 | 3719.53 | 0.1191 | 16.02 | 17696.48 | 0.0905 | 32.56 | 9782.67 | 0.3328 | — | 8946.44 | — | LA18 | 24.44 | 9269.41 | 0.2637 | 7.67 | 3801.25 | 0.2018 | 56.82 | 3179.11 | 1.7873 | 0.60 | 9490.75 | 0.0063 | 15.74 | 6342.64 | 0.2482 | 2.92 | 3811.54 | 0.0766 | 15.43 | 11215.99 | 0.1376 | 37.22 | 8358.76 | 0.4453 | — | 3946.18 | — |
|
| Sample | Hpro | Met | Thr | Asn | Gln | Ser | Total free amino acids | Total proteins (%) | | | | | | | | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio | Free | Total | Ratio |
| SP1 | 0.34 | 12275.50 | 0.0028 | — | 2102.26 | — | 12.78 | 7963.72 | 0.1605 | 39.82 | 3834.80 | 1.0384 | 1.04 | 1971.45 | 0.0528 | 4.76 | 6466.09 | 0.0736 | 172.07 | 16.19 | | | | | | | | SP2 | 0.84 | 11585.53 | 0.0073 | — | 1927.32 | — | 38.01 | 7239.98 | 0.5250 | 215.37 | 4986.79 | 4.3188 | 3.20 | 2096.01 | 0.1527 | 22.43 | 5929.40 | 0.3783 | 646.85 | 18.88 | | | | | | | | SP3 | 10.37 | 9975.53 | 0.1040 | 4.20 | 1384.33 | 0.3034 | 157.92 | 4945.98 | 3.1929 | 133.70 | 3711.29 | 3.6025 | 68.98 | 1951.23 | 3.5352 | 144.02 | 5954.58 | 2.4186 | 1437.51 | 15.19 | | | | | | | | SP4 | 3.50 | 12741.33 | 0.0275 | — | 1958.62 | — | 168.24 | 8709.13 | 1.9318 | 139.13 | 4253.91 | 3.2706 | 143.70 | 2036.62 | 7.0558 | 163.42 | 5609.49 | 2.9133 | 1520.16 | 17.82 | | | | | | | | SP5 | 0.48 | 15829.31 | 0.0030 | — | 2151.19 | — | 34.91 | 8355.57 | 0.4178 | 258.84 | 4912.45 | 5.2691 | 3.06 | 2256.83 | 0.1356 | 16.69 | 10234.90 | 0.1631 | 546.01 | 20.46 | | | | | | | | SP6 | 6.53 | 12371.35 | 0.0528 | — | 1608.64 | — | 185.93 | 5726.31 | 3.2469 | 131.14 | 4602.59 | 2.8493 | 53.20 | 2164.53 | 2.4578 | 144.62 | 8041.81 | 1.7984 | 1568.88 | 17.51 | | | | | | | | SP7 | 3.37 | 12423.61 | 0.0271 | 0.10 | 1470.47 | 0.0068 | 168.48 | 4848.42 | 3.4749 | 137.82 | 3978.83 | 3.4638 | 115.64 | 2145.57 | 5.3897 | 153.92 | 8601.82 | 1.7894 | 1616.80 | 15.59 | | | | | | | | SP8 | 0.83 | 9760.19 | 0.0085 | — | 1320.98 | — | 36.00 | 5251.98 | 0.6855 | 243.18 | 3721.89 | 6.5338 | 4.33 | 2074.31 | 0.2087 | 23.02 | 7285.14 | 0.3160 | 601.76 | 14.41 | | | | | | | | SP9 | 2.33 | 10641.34 | 0.0219 | 0.10 | 1927.64 | 0.0052 | 101.08 | 6224.18 | 1.6240 | 287.73 | 3643.59 | 7.8969 | 22.11 | 2123.14 | 1.0414 | 80.72 | 7300.64 | 1.1057 | 1176.53 | 14.43 | | | | | | | | SP10 | 5.44 | 15070.02 | 0.0361 | 0.26 | 2233.47 | 0.0116 | 111.26 | 9030.91 | 1.2320 | 295.67 | 4158.01 | 7.1109 | 19.66 | 2820.23 | 0.6971 | 98.55 | 9877.31 | 0.9977 | 1162.05 | 19.14 | | | | | | | | SP11 | 11.23 | 13641.99 | 0.0823 | 0.28 | 1744.92 | 0.0160 | 176.59 | 7985.90 | 2.2113 | 140.18 | 4655.28 | 3.0112 | 144.55 | 2112.77 | 6.8417 | 179.12 | 6088.37 | 2.9420 | 1570.89 | 17.01 | | | | | | | | SP12 | 12.01 | 11162.90 | 0.1076 | 0.24 | 1881.32 | 0.0128 | 125.79 | 4403.32 | 2.8567 | 137.25 | 3369.96 | 4.0727 | 41.76 | 1600.68 | 2.6089 | 57.70 | 6605.01 | 0.8736 | 1145.82 | 14.13 | | | | | | | | SP13 | 2.39 | 10615.66 | 0.0225 | 3.51 | 1382.26 | 0.2539 | 228.15 | 6391.62 | 3.5695 | 165.25 | 4095.51 | 4.0349 | 269.51 | 1696.44 | 15.8868 | 168.80 | 6708.25 | 2.5163 | 1755.14 | 13.75 | | | | | | | | SP14 | 1.44 | 13205.06 | 0.0109 | — | 2393.23 | — | 132.66 | 8976.95 | 1.4778 | 149.56 | 4798.05 | 3.1171 | 125.79 | 2465.90 | 5.1012 | 129.14 | 7298.41 | 1.7694 | 1255.50 | 19.06 | | | | | | | | SP15 | 6.10 | 10366.51 | 0.0588 | — | 1814.22 | — | 15.94 | 7685.12 | 0.2074 | 22.02 | 4676.65 | 0.4708 | 6.45 | 2382.45 | 0.2707 | 7.22 | 5548.49 | 0.1301 | 194.11 | 15.85 | | | | | | | | SP16 | 7.67 | 12903.86 | 0.0594 | 0.23 | 2509.21 | 0.0092 | 85.06 | 5550.87 | 1.5324 | 142.06 | 4329.68 | 3.2811 | 176.62 | 3056.34 | 5.7788 | 145.74 | 5866.53 | 2.4843 | 1678.57 | 18.29 | | | | | | | | SP17 | 2.03 | 10626.57 | 0.0191 | — | 1794.68 | — | 10.28 | 5329.55 | 0.1929 | 3.24 | 3731.24 | 0.0868 | 2.10 | 2828.19 | 0.0743 | 6.37 | 4657.92 | 0.1368 | 166.05 | 15.26 | | | | | | | | SP18 | 3.88 | 12874.45 | 0.0301 | 0.25 | 2623.84 | 0.0095 | 124.83 | 7649.77 | 1.6318 | 148.44 | 4745.86 | 3.1278 | 123.11 | 3038.81 | 4.0513 | 102.24 | 8464.54 | 1.2079 | 1304.51 | 19.91 | | | | | | | | SP19 | 6.64 | 13923.42 | 0.0477 | 0.39 | 1611.21 | 0.0242 | 116.76 | 6748.38 | 1.7302 | 49.92 | 4539.22 | 1.0997 | 45.19 | 3232.29 | 1.3981 | 77.95 | 5525.06 | 1.4108 | 1063.99 | 17.50 | | | | | | | | SP20 | 1.26 | 8623.89 | 0.0146 | 0.17 | 1655.87 | 0.0103 | 184.54 | 4751.82 | 3.8836 | 152.52 | 3938.78 | 3.8723 | 120.92 | 2150.51 | 5.6229 | 176.26 | 7450.83 | 2.3656 | 1670.95 | 13.61 | | | | | | | | SP21 | 10.27 | 10862.57 | 0.0945 | — | 1789.85 | — | 19.55 | 7093.47 | 0.2756 | 38.03 | 4126.30 | 0.9216 | 7.72 | 2908.79 | 0.2654 | 11.94 | 6041.00 | 0.1976 | 460.11 | 16.55 | | | | | | | | SP22 | 3.58 | 11476.96 | 0.0312 | 0.36 | 1441.11 | 0.0250 | 11.15 | 5896.68 | 0.1891 | 3.63 | 3801.35 | 0.0955 | 8.88 | 2075.29 | 0.4279 | 6.66 | 7009.63 | 0.0950 | 192.55 | 15.30 | | | | | | | | SP23 | 6.80 | 11931.55 | 0.0570 | — | 1557.75 | — | 48.22 | 5634.77 | 0.8558 | 90.90 | 3869.18 | 2.3493 | 14.04 | 1927.16 | 0.7285 | 18.66 | 8290.65 | 0.2251 | 651.61 | 16.73 | | | | | | | | SP24 | 6.27 | 10593.16 | 0.0592 | 0.12 | 2127.69 | 0.0056 | 64.57 | 5101.21 | 1.2658 | 104.24 | 3837.96 | 2.7160 | 14.64 | 2823.06 | 0.5186 | 24.13 | 9012.82 | 0.2677 | 734.27 | 16.87 | | | | | | | | SP25 | 1.86 | 13824.44 | 0.0135 | 0.44 | 2716.54 | 0.0162 | 186.66 | 4842.06 | 3.8550 | 146.65 | 4187.28 | 3.5023 | 97.55 | 2771.87 | 3.5193 | 189.30 | 8595.86 | 2.2022 | 1899.50 | 19.76 | | | | | | | | LP1 | 0.47 | 14631.38 | 0.0032 | 1.18 | 1948.75 | 0.0606 | 65.83 | 6231.55 | 1.0564 | 95.95 | 4013.49 | 2.3907 | 86.11 | 3138.12 | 2.7440 | 85.73 | 5753.40 | 1.4901 | 814.99 | 18.47 | | | | | | | | LP2 | 0.64 | 12206.18 | 0.0052 | 1.85 | 2297.38 | 0.0805 | 78.50 | 5838.37 | 1.3446 | 145.43 | 4899.76 | 2.9681 | 52.18 | 2104.26 | 2.4797 | 73.92 | 6212.65 | 1.1898 | 1012.65 | 17.73 | | | | | | | | LP3 | 4.52 | 8885.71 | 0.0509 | 0.13 | 1858.23 | 0.0070 | 41.09 | 5789.60 | 0.7097 | 124.04 | 2882.55 | 4.3031 | 10.24 | 2456.95 | 0.4168 | 10.18 | 6286.97 | 0.1619 | 597.23 | 13.95 | | | | | | | | LP4 | 5.45 | 10112.04 | 0.0539 | — | 1630.58 | — | 163.52 | 7525.00 | 2.1730 | 143.69 | 3758.46 | 3.8231 | 51.80 | 1875.09 | 2.7625 | 160.80 | 7731.94 | 2.0797 | 1426.96 | 16.05 | | | | | | | | LP5 | 1.71 | 9028.04 | 0.0189 | — | 1621.37 | — | 152.81 | 4615.56 | 3.3108 | 134.30 | 3260.74 | 4.1187 | 112.30 | 1704.64 | 6.5879 | 122.16 | 4651.12 | 2.6265 | 1718.87 | 15.03 | | | | | | | | LP6 | 0.71 | 11053.96 | 0.0064 | — | 1379.86 | — | 85.21 | 6409.94 | 1.3293 | 270.66 | 3875.46 | 6.9839 | 136.75 | 1528.04 | 8.9494 | 72.78 | 6453.61 | 1.1277 | 1308.25 | 13.94 | | | | | | | | LP7 | 0.41 | 10437.44 | 0.0039 | 0.99 | 1616.03 | 0.0613 | 48.37 | 6713.60 | 0.7205 | 199.42 | 3616.48 | 5.5142 | 71.18 | 2426.57 | 2.9334 | 73.61 | 5273.31 | 1.3959 | 1113.74 | 16.11 | | | | | | | | LP8 | 0.60 | 12028.82 | 0.0050 | 2.77 | 2130.37 | 0.1300 | 64.52 | 8264.66 | 0.7807 | 93.71 | 4102.87 | 2.2840 | 128.62 | 3030.50 | 4.2442 | 77.21 | 8764.09 | 0.8810 | 1028.91 | 17.52 | | | | | | | | LP9 | 2.85 | 15395.17 | 0.0185 | 1.09 | 2611.93 | 0.0417 | 95.31 | 6079.19 | 1.5678 | 135.68 | 5800.10 | 2.3393 | 21.02 | 2847.50 | 0.7382 | 160.76 | 6714.80 | 2.3941 | 1620.64 | 20.09 | | | | | | | | LP10 | 3.15 | 12510.19 | 0.0252 | 0.19 | 2294.16 | 0.0083 | 139.99 | 5986.95 | 2.3383 | 316.13 | 4149.54 | 7.6184 | 20.34 | 2755.14 | 0.7383 | 126.41 | 9249.73 | 1.3666 | 1408.67 | 18.88 | | | | | | | | LP11 | 2.02 | 11304.83 | 0.0179 | 0.44 | 1616.02 | 0.0272 | 92.06 | 7087.95 | 1.2988 | 100.62 | 3134.85 | 3.2097 | 9.67 | 2255.64 | 0.4287 | 81.26 | 7479.28 | 1.0865 | 735.57 | 14.11 | | | | | | | | LP12 | 1.26 | 11500.95 | 0.0110 | 0.34 | 1721.63 | 0.0197 | 24.77 | 6419.44 | 0.3859 | 25.52 | 4463.29 | 0.5718 | 3.93 | 2645.29 | 0.1486 | 15.06 | 7598.99 | 0.1982 | 291.40 | 16.46 | | | | | | | | LP13 | 6.41 | 13163.18 | 0.0487 | 0.30 | 2716.29 | 0.0110 | 172.44 | 9432.07 | 1.8282 | 143.41 | 4225.29 | 3.3941 | 134.72 | 2932.22 | 4.5945 | 169.75 | 8497.59 | 1.9976 | 1667.79 | 19.79 | | | | | | | | LP14 | 3.64 | 16225.57 | 0.0224 | 0.17 | 2793.92 | 0.0061 | 175.47 | 6457.65 | 2.7172 | 140.65 | 5052.79 | 2.7836 | 118.28 | 3874.56 | 3.0527 | 171.21 | 9352.55 | 1.8306 | 1529.56 | 21.15 | | | | | | | | LP15 | 1.70 | 11614.17 | 0.0146 | 0.09 | 2501.01 | 0.0036 | 89.92 | 6615.18 | 1.3593 | 269.56 | 3725.94 | 7.2347 | 3.34 | 2877.91 | 0.1161 | 82.11 | 8616.92 | 0.9529 | 900.44 | 18.46 | | | | | | | | LP16 | 0.94 | 11631.20 | 0.0081 | 0.99 | 1651.61 | 0.0599 | 95.46 | 5189.08 | 1.8396 | 201.46 | 3964.71 | 5.0813 | 106.74 | 2083.97 | 5.1220 | 89.52 | 5649.83 | 1.5845 | 1381.04 | 15.81 | | | | | | | | LA1 | 0.75 | 10525.37 | 0.0071 | 0.33 | 1722.41 | 0.0192 | 119.80 | 5747.08 | 2.0845 | 146.08 | 4354.39 | 3.3548 | 117.79 | 2828.86 | 4.1639 | 99.93 | 8354.17 | 1.1962 | 1262.44 | 15.27 | | | | | | | | LA2 | 0.71 | 11050.46 | 0.0064 | 2.14 | 2075.76 | 0.1031 | 88.95 | 5755.14 | 1.5456 | 114.22 | 4714.20 | 2.4229 | 113.30 | 2590.48 | 4.3737 | 128.49 | 8446.54 | 1.5212 | 1057.50 | 16.42 | | | | | | | | LA3 | 1.58 | 14292.88 | 0.0111 | — | 2387.79 | — | 85.96 | 9803.09 | 0.8769 | 129.12 | 5651.48 | 2.2847 | 172.44 | 2107.17 | 8.1835 | 147.16 | 11408.14 | 1.2900 | 1716.54 | 20.72 | | | | | | | | LA4 | 0.78 | 11457.33 | 0.0068 | — | 2109.40 | — | 75.39 | 7598.12 | 0.9922 | 177.20 | 4225.71 | 4.1934 | 34.18 | 2341.13 | 1.4600 | 45.77 | 7073.90 | 0.6470 | 778.32 | 15.58 | | | | | | | | LA5 | 6.18 | 11098.92 | 0.0557 | 0.60 | 1527.50 | 0.0393 | 127.09 | 6426.35 | 1.9776 | 196.17 | 4798.09 | 4.0885 | 29.66 | 2500.29 | 1.1863 | 66.00 | 7750.15 | 0.8516 | 1332.28 | 16.58 | | | | | | | | LA6 | 1.69 | 11256.40 | 0.0150 | 0.14 | 1485.02 | 0.0094 | 92.57 | 6651.83 | 1.3916 | 129.99 | 4328.83 | 3.0029 | 86.79 | 1722.57 | 5.0384 | 157.13 | 8406.98 | 1.8690 | 1547.66 | 16.04 | | | | | | | | LA7 | 2.07 | 11307.16 | 0.0183 | — | 1577.93 | — | 92.43 | 4656.66 | 1.9849 | 145.34 | 4362.67 | 3.3314 | 135.71 | 1877.25 | 7.2292 | 170.21 | 8033.47 | 2.1188 | 1517.92 | 14.71 | | | | | | | | LA8 | 10.79 | 15918.39 | 0.0678 | 0.19 | 2259.56 | 0.0084 | 117.78 | 7883.83 | 1.4939 | 154.15 | 5792.38 | 2.6613 | 216.67 | 2621.75 | 8.2643 | 61.37 | 7941.33 | 0.7728 | 1171.00 | 21.30 | | | | | | | | LA9 | 0.76 | 14178.74 | 0.0054 | 0.14 | 2618.77 | 0.0053 | 6.51 | 6538.81 | 0.0996 | 7.87 | 4624.51 | 0.1702 | 2.68 | 2321.32 | 0.1155 | 6.76 | 10561.97 | 0.0640 | 189.02 | 21.46 | | | | | | | | LA10 | 1.44 | 11088.93 | 0.0130 | 0.26 | 1806.72 | 0.0144 | 62.25 | 6942.43 | 0.8967 | 53.97 | 4802.60 | 1.1238 | 47.46 | 2041.76 | 2.3245 | 36.17 | 5403.37 | 0.6694 | 775.54 | 16.41 | | | | | | | | LA11 | 0.84 | 15220.71 | 0.0055 | 1.65 | 2528.91 | 0.0652 | 8.60 | 7038.75 | 0.1222 | 1.31 | 5236.37 | 0.0250 | 4.91 | 2429.40 | 0.2021 | 7.80 | 6092.24 | 0.1280 | 289.21 | 19.05 | | | | | | | | LA12 | 2.55 | 9164.65 | 0.0278 | 0.18 | 1894.44 | 0.0095 | 174.89 | 4404.00 | 3.9712 | 138.27 | 3675.47 | 3.7620 | 72.48 | 1770.28 | 4.0943 | 85.28 | 5128.63 | 1.6628 | 1294.14 | 14.54 | | | | | | | | LA13 | 2.16 | 13906.13 | 0.0155 | — | 2514.70 | — | 116.52 | 7070.17 | 1.6481 | 294.15 | 3964.62 | 7.4194 | 42.77 | 2727.93 | 1.5679 | 65.75 | 7050.95 | 0.9325 | 1282.38 | 18.31 | | | | | | | | LA14 | 9.08 | 13760.74 | 0.0660 | 0.60 | 2297.56 | 0.0261 | 164.90 | 9014.10 | 1.8294 | 131.85 | 5045.39 | 2.6133 | 63.90 | 2704.59 | 2.3627 | 144.27 | 5601.90 | 2.5754 | 1371.90 | 17.81 | | | | | | | | LA15 | 3.69 | 8467.71 | 0.0436 | 0.30 | 1826.09 | 0.0164 | 135.18 | 5450.03 | 2.4804 | 62.94 | 3497.92 | 1.7994 | 46.02 | 1747.54 | 2.6334 | 51.56 | 4656.58 | 1.1073 | 1020.37 | 13.89 | | | | | | | | LA16 | 2.78 | 16217.53 | 0.0171 | 0.29 | 2603.75 | 0.0111 | 97.73 | 8455.20 | 1.1559 | 22.61 | 5055.17 | 0.4473 | 18.70 | 2206.25 | 0.8476 | 48.71 | 9026.29 | 0.5396 | 811.03 | 20.42 | | | | | | | | LA17 | 0.68 | 12202.21 | 0.0056 | 2.23 | 2011.22 | 0.1109 | 81.41 | 5966.49 | 1.3645 | 207.86 | 3770.32 | 5.5131 | 55.84 | 3327.23 | 1.6783 | 76.89 | 7660.33 | 1.0037 | 1027.14 | 18.44 | | | | | | | | LA18 | 0.55 | 9875.86 | 0.0056 | 2.42 | 1754.15 | 0.1380 | 76.82 | 5468.75 | 1.4047 | 143.75 | 3704.63 | 3.8803 | 52.67 | 1760.52 | 2.9917 | 90.61 | 6192.83 | 1.4631 | 1068.96 | 14.93 | | | | | | | |
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—, analytes were not detected.
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